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Preparation of aromatic hydrocarbons from methane in the presence of O2

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Abstract

It has been revealed that methane conversion on ZSM zeolites in the presence of O2 can yield hydrocarbons having molecules with more than one carbon atom. A dependence of the selectivity of this process on the chemical composition and structure of the zeolites and the pressure of the reaction mixture has been studied and a reaction mechanism for this process is suggested.

Abstract

Показано, что в результате превращения метана на цеолитах типа ZSM в присутствии кислорода могут быть получены углеводороды, содержащие более одного углеродного атома в молекуле. Исследована зависимость селективности этого процесса от химического состава и структуры цеолитов, а также от давления реакционной смеси. Предложена схема протекания процесса.

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Shepelev, S.S., Ione, K.G. Preparation of aromatic hydrocarbons from methane in the presence of O2 . React Kinet Catal Lett 23, 323–325 (1983). https://doi.org/10.1007/BF02065583

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  • DOI: https://doi.org/10.1007/BF02065583

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