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Synthesis and conversions of metallocycles. XII.13C NMR spectra of tri- and tetracyclic organoaluminum compounds with a bridge structure

  • Physical Chemistry
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Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

The13C NMR spectra of a new class of tri- and tetracyclic organoaluminum and organosulfur bridge-type compounds, containing five-membered heterocycles with anexo-orientation, are discussed. The assignment of the signals and determination of the isomerism of the compounds studied were performed using the spectra of their hydrocarbon analogs, additive calculations, and an analysis of the spectra of products of deuteration and hydrolysis of organoaluminum compounds.

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References

  1. U. M. Dzhemilev, A. G. Ibragimov, A. P. Zolotarev, L. M. Khalikov, and R. R. Muslukhov,Izv. Akad. Nauk SSSR, Ser. Khim., No. 2, 386 (1992).

  2. U. M. Dzhemilev, A. G. Ibragimov, A. P. Zolotarev, R. R. Muslukhov, and G. A. Tolstikov,Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 207 (1989).

  3. U. M. Dzhemilev, A. G. Ibragimov, A. B. Morozov, R. R. Muslukhov, and G. A. Tolstikov,Izv. Akad. Nauk SSSR, Ser. Khim., No. 7, 1607 (1991).

  4. U. M. Dzhemilev, A. G. Ibragimov, A. P. Zolotarev, R. R. Muslukhov, and G. A. Tolstikov,Izv. Akad. Nauk SSSR, Ser. Khim., No. 12, 2831 (1990).

  5. K. Nakagawa, S. Iwase, G. Ishu, S. Hamanaka, and M. Ogawa,Bull. Chem. Soc. Jpn.,50, No. 9, 2391 (1977).

    Google Scholar 

  6. A. P. Marchand,Stereochemical Applications of NMR Studies in Rigid Bicyclic Systems, Verlag Chemie International, Deerfield Beach, Florida (1982), p. 230.

    Google Scholar 

  7. J. K. Whitesell and M. A. Minton,Stereochemical Analysis of Alicyclic Compounds by C-13 NMR Spectroscopy, Chapman and Hall, London (1987), p. 55.

    Google Scholar 

  8. A. A. Petrov,Stereochemistry of Saturated Hydrocarbons [in Russian], Nauka, Moscow (1981), p. 186.

    Google Scholar 

  9. G. A. Olan, G. K. S. Prakash, G. Liang, K. L. Henold, and G. B. Haigh, Progr. Natl. Acad. Sci. USA,74, No. 12, 5217 (1977).

    Google Scholar 

  10. O. Yamamoto and M. Yanagisawa,Bull. Chem. Soc. Jpn.,51, No. 4, 1231 (1978).

    Google Scholar 

  11. L. M. Khalilov, O. V. Shitikova, A. A. Gimaev, L. M. Khusnutdinov, U. M. Dzhemilev, A. A. Panasenko, and G. A. Tolstikov,Izv. Akad. Nauk SSSR, No. 9, 1973 (1990).

  12. L. M. Khalilov, A. A. Gimaev, and O. V. Shitikova, Summaries of Reports at the 8th All-Union Conference: The Use of Computers in Molecular Spectroscopy and Chemical Investigations [in Russian], Novosibirsk (1989).

  13. A. A. Panasenko and L. M. Khalilov,Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2652 (1989).

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Authors
  1. R. R. Muslukhov
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  2. L. M. Khalilov
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  3. A. G. Ibragimov
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  4. A. P. Zolotarev
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  5. U. M. Dzhemilev
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Additional information

For previous communication, see [1].

Institute of Organic Chemistry, Urals Branch, Russian Academy of Sciences, 450054 Ufa, Bashkortostan, Russia. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 12, pp. 2742–2750, December, 1992.

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Muslukhov, R.R., Khalilov, L.M., Ibragimov, A.G. et al. Synthesis and conversions of metallocycles. XII.13C NMR spectra of tri- and tetracyclic organoaluminum compounds with a bridge structure. Russ Chem Bull 41, 2172–2179 (1992). https://doi.org/10.1007/BF01150741

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  • DOI: https://doi.org/10.1007/BF01150741

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