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Impedance analysis of electrodes modified with a reversible redox polymer film

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Abstract

The study of the kinetics of an electrode coated with a redox polymer film has been carried out using an impedance technique. A theoretical model is proposed which takes into account the diffusion of the active centres. Experimental results are presented for a glassy carbon electrode coated with a [Ru(bpy)2 poly(4′-vinylpyridine)Cl]Cl film. There is good agreement between these results and the model.

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Authors and Affiliations

  1. LP 15 du CNRS, ‘Physique des Liquides et Electrochimie’, Université Pierre et Marie Curie, Tour 22, 4 place Jussieu, 75252, Paris Cedex 05, France

    C. Gabrielli & H. Takenouti

  2. Swiss Federal Institute for Reactor Research, CH-5303, Würenlingen, Switzerland

    O. Haas

Authors
  1. C. Gabrielli
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  2. O. Haas
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  3. H. Takenouti
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Gabrielli, C., Haas, O. & Takenouti, H. Impedance analysis of electrodes modified with a reversible redox polymer film. J Appl Electrochem 17, 82–90 (1987). https://doi.org/10.1007/BF01009134

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  • DOI: https://doi.org/10.1007/BF01009134

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