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Kinetics and mechanism of oxidation of cyclohexanol by 1-Chlorobenzotriazole (CBT) in acid medium

Kinetik und Mechanismus der Oxidation von Cyclohexanol mit 1-Chlorbenzotriazol (CBT) in saurem Medium

  • Anorganische Und Physikalische Chemie
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Abstract

The kinetics of oxidation of cyclohexanol by 1-Chlorobenzotriazole (CBT) has been studied at 40°C in 50% aqueous acetic acid. The reaction is first order with respect to oxidant and first order with respect to substrate. The rate is found to increase with increase in acid concentration and percentage ofAcOH in the mixture. The kinetic parameters have been calculated. A suitable mechanism is proposed.

Zusammenfassung

Die Kinetik der Oxidation von Cyclohexanol mitCBT wurde bei 40°C in 50% wäßriger Essigsäure untersucht. Die Reaktion war sowohl bezüglich Oxidationsmittel als auch Substrat von erster Ordnung. Die Reaktionsgeschwindigkeit wird mit zunehmender Säurekonzentration (AcOH) erhöht. Die kinetischen Parameter wurden bestimmt und ein passender Mechanismus wird vorgeschlagen.

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References

  1. Ganapathy K, Karunakaran C (1982) Monatsh Chem 113: 1239

    Google Scholar 

  2. Ganapathy K, Vijayan B (1978) Proc Ind Acad 87A: 215

    Google Scholar 

  3. Richler JC, Hoa NTT (1969) Can J Chem 47: 2479

    Google Scholar 

  4. Radhakrishnamurthy PS, Behera J (1970) Ind Chem Soc 47: 429

    Google Scholar 

  5. Radhakrishnamurthy PS, Mahandhi K (1973) Ind J Chem 11: 762

    Google Scholar 

  6. Srinivasan VS, Venkatasubramanian N (1979) Ind J Chem 18A: 259

    Google Scholar 

  7. Mushran SP et al (1978) Acta Ciencia Indica 4(3): 219

    Google Scholar 

  8. Vijayalakshmi, Sundaram EV (1978) J Ind Chem Soc: 567

  9. Rees CW, Storr RC (1969) J Chem Soc Org C 11: 1474

    Google Scholar 

  10. Vogel AI (1959) Practical organic chemistry, 3rd edn. p 346

  11. Rangadurai A et al (1982) Ind J Chem 1: 42

    Google Scholar 

  12. Kuselan P, Venkatasubramanian N (1983) Ind J Chem 4: 292

    Google Scholar 

  13. Jeyaraman PS et al (1982) Proc Ind Acad Sci 91(5): 421

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Annamalai University, 608002, Annamalainagar, India

    K. Ganapathy, R. Gurumurthy, N. Mohan & G. Sivagnanam

Authors
  1. K. Ganapathy
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  2. R. Gurumurthy
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  3. N. Mohan
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  4. G. Sivagnanam
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Ganapathy, K., Gurumurthy, R., Mohan, N. et al. Kinetics and mechanism of oxidation of cyclohexanol by 1-Chlorobenzotriazole (CBT) in acid medium. Monatsh Chem 118, 583–587 (1987). https://doi.org/10.1007/BF00809668

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  • DOI: https://doi.org/10.1007/BF00809668

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