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Optical recording using hydrogen phthalocyanine thin films

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Abstract

Vacuum sublimed thin films of the blue dye hydrogen phthalocyanine (H2Pc) were incorporated into various optical recording structures. The dye was shown to be thermally, hydrolytically, and oxidatively stable. In all cases, the writing mechanisms are dependent on the sublimation of H2Pc. Several recording structures which take advantage of the sublimation property of H2Pc are demonstrated, including pit forming and bubble forming media. These H2Pc-based optical recording structures show very high optical contrast and low writing threshold energies. In addition, very thin films (50–75Å) of H2Pc were incorporated into a tellurium-based medium, which significantly enhanced the writing contrast observed in that medium.

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References

  1. R.C. Miller, R.H. Willens, H.A. Watson, L.A. D'Asaro, M. Feldman: Bell. Syst. Tech. J.58, 1909–1998 (1979)

    Google Scholar 

  2. P. Kivits, R. de Bont, B. Jacobs, P. Zalm: Thin Solid Films87, 215–231 (1982)

    Google Scholar 

  3. R.A. Bartolini: Proc. IEEE70, 589 (1982)

    Google Scholar 

  4. S.Y. Suh: Topical Meeting on Optical Data Storage, Incline Village, Nevada (1983)

  5. G.A.N. Connell, R.I. Johnson, D. Kowalski, C. DePuy: Optical Disk Technology, Proc. SPIE329, 166 (1982)

    Google Scholar 

  6. A.E. Bell: J. Appl. Phys.53, 3430 (1982)

    Google Scholar 

  7. A. Bloom, W.J. Burke: U.S. Patent 4,241,355 (Dec. 23, 1980) Assignee: RCA

  8. J. van der Veen, P.J. Kivits, M.R.J. de Bont: U.S. Patent 4,298,975 (Nov. 3, 1981) Assignee: U.S. Philips Corp

  9. Jpn. Kokai Tokkyo Koho JP 56, 130, 742, Assignee: Asahi Chemical Ind., October 13, 1981

  10. P. Kivits, R. de Bont, J. van der Veen: Appl. Phys. A26, 101 (1981)

    Google Scholar 

  11. K. Ogawa, Y. Goto, N. Koshino, S. Ogawa: Technical Digest, Conf. on Lasers and Electro-optics (Optical Society of America), Phoenix, AZ (1982) p. 140

    Google Scholar 

  12. Kirk-Othmer Encyclopedia of Chemical Technology, Vol. 17, ed. by M. Grayson, D. Eckroth (Wiley, New York 1982) p. 777

    Google Scholar 

  13. T.W. Smith, G.E., Johnson, A.T. Ward, D.J. Luca: Optical Disk Technology, Proc. SPIE329, 228 (1982)

    Google Scholar 

  14. F. Gutman, L.E. Lyons: Organic Semiconductors, P. A (Robert E. Krieger Publishers, Malibar, FL 1981) p. 149

    Google Scholar 

  15. B.H. Shectman: Ph.D. Dissertation, Photoemission and Optical Studies of Organic Solids; Phthalocyanines and Porphyrins, Stanford University (1968)

  16. O.S. Heavens:Optical Properties of Thin Solid Films (Dover, New York 1955)

    Google Scholar 

  17. A.E. Bell, F.W. Spong: IEEE J. QE-14, 487 (1978)

    Google Scholar 

  18. H.G. Craighhead, R.E. Howard, R.W. Smith, D.A. Snyder: Optical Disk Technology, Proc. SPIE329, 202–205 (1982)

    Google Scholar 

  19. R.A. Bartolini, A.E. Bell, F.W. Spong: IEEE J. QE-17, 69 (1981)

    Google Scholar 

  20. R.P. Freese, R.F. Wilson, L.D. Wald, W.B. Robbins, T.C. Smith: Optical Disk Technology, Proc. SPIE329, 174 (1982)

    Google Scholar 

  21. J. Cornet, J.C. Lehureau, F. LeCarvennec: Technical Digest, Conf. on Lasers and Electro-optics (Optical Society of America). Washington (1981) p. 122

    Google Scholar 

  22. D.J. Broer, L. Vriens: Appl. Phys.A32, 107–123 (1983)

    Google Scholar 

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Dautartas, M.F., Suh, S.Y., Forrest, S.R. et al. Optical recording using hydrogen phthalocyanine thin films. Appl. Phys. A 36, 71–79 (1985). https://doi.org/10.1007/BF00620612

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