Skip to main content
Log in

Comonomer sequence distribution in ethylene/1-hexene copolymers

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The13C NMR spectral assignments for ethylene/1-hexene copolymers are reexamined. Revised assignments are obtained for the 34–36 ppm region. A computational scheme is devised to extract information on composition and sequence distribution from the spectral intensities. A computerized analytical approach that fits the observed intensities to statistical models is also available.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. B. Florin-Michel, M.-F. Llauro, R. Spitz, and Q. T. Pham,Eur. Polym. J., 15, 277 (1979).

    Article  CAS  Google Scholar 

  2. E. T. Hsieh and J. C. Randall,Macromolecules, 15, 1402 (1982).

    Article  CAS  Google Scholar 

  3. K. Soga, T. Uozumi, and J. R. Park,Macromol. Chem., 191, 100 (1990).

    Article  Google Scholar 

  4. M. De Pooter, et al.,J. Appl. Polym. Sci., 42, 399 (1991).

    Article  CAS  Google Scholar 

  5. C. J. Carman, R. A. Harrington, and C. E. Wilkes,Macromolecules, 10, 773 (1977).

    Article  Google Scholar 

  6. D. M. Grant and E. G. Paul,J. Am. Chem. Soc., 86, 2984 (1964).

    Article  CAS  Google Scholar 

  7. L. P. Lindeman and J. Q. Adams,Anal. Chem., 43, 1245 (1971).

    Article  CAS  Google Scholar 

  8. C. J. Carman, A. R. Tarpley, and J. H. Goldstein,Macromolecules, 6, 719 (1973).

    Article  CAS  Google Scholar 

  9. H. N. Cheng and M. A. Bennett,Anal. Chim. Acta, 242, 43 (1991), and references cited therein.

    Article  CAS  Google Scholar 

  10. G. J. Ray, P. E. Johnson, and J. R. Knox,Macromolecules, 10, 773 (1977).

    Article  CAS  Google Scholar 

  11. J. C. Randall,Macromolecules, 11, 33 (1978).

    Article  CAS  Google Scholar 

  12. H. N. Cheng,Anal. Chem. 54, 1828 (1982).

    Article  CAS  Google Scholar 

  13. G. J. Ray, J. Spanswick, J. R. Knox, and C. Serres,Macromolecules, 14, 1323 (1981).

    Article  CAS  Google Scholar 

  14. E. T. Hsieh and J. C. Randall,Macromolecules, 15, 353 (1982).

    Article  CAS  Google Scholar 

  15. H. N. Cheng,Macromolecules, submitted for publication.

  16. H. N. Cheng,Polym. Comm., 25, 99 (1984).

    CAS  Google Scholar 

  17. K. Kimura, S. Yuasa, and Y. Maru,Polymer, 25, 441 (1984).

    Article  CAS  Google Scholar 

  18. H. N. Cheng,J. Chem. Inf. Computer Sci., 17, 8 (1987).

    Article  Google Scholar 

  19. H. N. Cheng,J. Appl. Polym. Sci.: Appl. Polym. Symp., 43, 129 (1989).

    CAS  Google Scholar 

  20. H. N. Cheng,J. Appl. Polym. Sci., 35, 1639 (1988).

    Article  CAS  Google Scholar 

  21. H. N. Cheng,Am. Chem. Soc. Symp. Ser., 404, 174 (1989).

    CAS  Google Scholar 

  22. H. N. Cheng,Polym. Bull., 23, 589 (1990).

    Article  CAS  Google Scholar 

  23. H. N. Cheng and M. Kakugo,Macromolecules, in press.

  24. H. N. Cheng, manuscript in preparation.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cheng, H.N. Comonomer sequence distribution in ethylene/1-hexene copolymers. Polymer Bulletin 26, 325–332 (1991). https://doi.org/10.1007/BF00587977

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00587977

Keywords

Navigation