Abstract
The Microstructure of quenched and annealed iPP films was investigated by means of differential scanning calorimetry (DSC), density measurements, wide-angle X-ray diffraction (WAXD) and dynamic mechanical spectrometry (DMS). It was found that quenched iPP can be described as a biphasic material constituted of an amorphous phase strongly cross-linked by many crystalline entities exhibiting both small size and very low degree of perfection. Such microcrystallites act as true physical ties of the amorphous phase. On increasing the annealing temperature from 20 °C (quenched film) to 160 °C, the crystallinity ratio first remained constant for annealing temperatures between 20 and 93 °C and then it increased. Subsequently, both size and degree of perfection of crystalline entities progressively increased and tended towards the characteristics of the monoclinic phase. This resulted in a progressive decrease in the physical cross-linking degree of the amorphous phase, even for the samples exhibiting the highest crystallinity ratio.
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References
D. R. Morrow, J. Macromol. Sci. Phys. B3 (1) (1969) 53.
J. Varga, J. Mater. Sci. 27 (1992) 2557.
Z. Mencik, J. Macromol. Sci. B(6) (1972) 101.
G. Natta, P. Corradini and M. Cesari, Atti. Acad. Naz. Lincei Rend. 21 (1956) 65.
R. J. Samuels and R. Y. Yee, J. Polym. Sci. A(2) 10 (1972) 385.
A. Turner Jones, J. M. Aizlewood and D. R. Beckett, Makromol. Chem. 75 (1964) 134.
Hiskosaka, Jpn J. Appl. Phys. 12 (1973) 1293.
B. Lotz, S. Graff and J. C. Wittman, J. Polym. Sci. Polym. Phys. Ed. 24 (1986) 2017.
R. L. Miller, Polymer 1 (1960) 135.
R. Zannetti, G. Celotti, A. Fichera and R. Francesconi, Makromol. Chem. 128 (1969) 137.
G. Bodor, M. Grell and A. Kello, Faserforsch. Textil. Technol. 15 (1964) 527.
D. M. Gezowich and P. H. Geil, Polym. Eng. Sci. 8 (1968) 202.
P. B. McAllister, T. J. Carter and R. M. Hinde, J. Polym. Sci. Polym. Phys. Ed. 16 (1978) 49.
C. C. Hsu, P. H. Geil, H. Miyaji and K. Asai, ibid. 24 (1986) 2379.
G. Natta, SPE J. (1979) 377.
J. Grebowicz, I. F. Lau and B. Wunderlich, Polym. Sci. Polym. Symp. 71 (1984) 19.
M. Glotin, R. R. Rahalkar, P. J. Hendra, M. E. A. Cudby and H. A. Willis, Polymer 22 (1981) 731.
P. J. Hendra, J. Vile, H. A. Willis, V. Zichy and M. E. A. Cubdy, ibid. 25 (1984) 785.
R. Saraf and R. S. Porter, Molec. Cryst. Liq. Cryst. Lett. 2 (1985) 85.
P. Corradini, V. Petracccone, C. De Rosa and G. Guerra, Macromolecules 19 (1986) 2699.
A. Fichera and R. Zannetti, Mackromol. Chem. 128 (1975) 137.
D. T. Grubb and D. Y. Yoon, Polym. Commun. 27 (1986) 84.
V. Vittoria, J. Macromol. Sci. Phys. B28 (1989) 489.
Idem J. Polym. Sci. Polym. Phys. Ed. 24 (1986) 451.
Idem J. Mater. Sci. 27 (1992) 4350.
V. Vittoria and A. Perullo, J. Macromol. Sci. B25 (1986) 2671.
N. Alberola, M. Fugier, D. Petit and B. Fillon, J. Mater. Sci. 30 (1995) in press.
J. A. Gailey and R. H. Ralston, SPE Trans. 4 (1964) 29.
A. Fichera and R. Zannetti, Makromol. Chem. 176 (1975) 1885.
D. J. Blundell, Polymer 28 (1987) 2248.
P. Cebe and S. D. Hong, ibid. 27 (1986) 1183.
N. Alberola, J. Mater. Sci. 26 (1991) 1856.
B. Wunderlich, “Macromolecular Physics”, Vol. 1 (Academic Press, New York, 1973) p. 549.
S. Z. D. Cheng, H. S. Bu and B. Wunderlich, Polymer 29 (1988) 579.
S. H. Ryu, C. G. Gogos and M. Xanthos, ibid. 32 (1991) 2449.
C. Passingham, P. J. Hendra, M. E. A. Cudby, V. Zichy and M. Weller, Eur. Polym. J. 26 (1990) 631.
Y. Lee, R. S. Porter and J. S. Lin, Macromolecules 22 (1989) 1756.
S. S. Chang, Polym. Commun. 29 (1988) 138.
R. Alamo and L. Mandelkern, J. Polym. Sci. B Polym. Phys. Ed. 24 (1986) 2087.
M. E. Nichols and R. E. Robertson, ibid. 30 (1992) 305.
M. P. Lattimer, J. K. Hobbs, M. J. Hill and P. J. Barham, Polymer 33 (1992) 3971.
G. Natta, P. Corradini and M. Cesari, Atti. Accad. Nazl. Lincei. Rend. Sci. Fis. Mat. et Nat. 22 (1957) 11.
F. De Candia, P. Iannelli, G. Staulo and V. Vittoria, Coll. Polym. Sci. 266 (1988) 608.
A. Cecere, R. Greco and A. Taglialatela, Polymer 33 (1992) 1411.
N. Alberola, J. Y. Cavaille and J. Perez, Eur. Polym. J. 28 (1992) 935.
R. F. Boyer, Rubber Chem. Technol. 36 (1963) 1303.
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Alberola, N., Fugier, M., Petit, D. et al. Microstructure of quenched and annealed films of isotactic polypropylene. JOURNAL OF MATERIALS SCIENCE 30, 1187–1195 (1995). https://doi.org/10.1007/BF00356118
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DOI: https://doi.org/10.1007/BF00356118