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Synthesis by metallocene/MAO catalyst and functionalization of poly(ethene-co-4-vinylcyclohexene)

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Summary

New functional copolymers consisting of ethene and 4-vinylcyclohexene (4-VCH) were synthesized by a stereorigid metallocene/methylalumoxane catalyst. The content of 4-VCH depends on the polymerization temperature, thus influencing the polymeric properties. Investigations of the microstructure were made using 13C NMR spectroscopy, thus revealing that 4-VCH is inserted regioselectively into the growing polymer chain. Hydroboration of selected copolymers followed by an oxidative workup yielded polyacohols which display different polymeric properties than the precursor

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Authors and Affiliations

  1. Institute for Technical and Macromolecular Chemistry, Bundesstrasse 45, D-20146, Hamburg, Germany

    W. Kaminsky, D. Arrowsmith & H. R. Winkelbach

Authors
  1. W. Kaminsky
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  2. D. Arrowsmith
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  3. H. R. Winkelbach
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Kaminsky, W., Arrowsmith, D. & Winkelbach, H.R. Synthesis by metallocene/MAO catalyst and functionalization of poly(ethene-co-4-vinylcyclohexene). Polymer Bulletin 36, 577–584 (1996). https://doi.org/10.1007/BF00342449

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  • DOI: https://doi.org/10.1007/BF00342449

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