Summary
The different aspects of speciation analysis are reviewed. Species-specific instrumental techniques as well as various speciation schemes are considered for the determination of species of metals and metalloids, including organometallic compounds. The application of the methods are discussed in some detail for the analysis of natural waters, air, soil, sediment and biological samples. The relationship between metal species and bioavailability is also briefly dealt with.
Similar content being viewed by others
References
Bernhard M, Brinckman FE, Sadler PJ (eds) (1986) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York
Leppard GG (ed) (1983) Trace element speciation in surface waters and its ecological implications. Plenum, New York
Kramer JR, Allen HE (eds) (1988) Metal speciation. Theory, analysis and application. Lewis Pub, Chelsea (Michigan)
Gardiner PHE (1987) Topics Current Chem 141:145
Hunt DTE, Wilson AL (1986) The chemical analysis of water. General principles and techniques, 2. edn. Royal Soc Chem, London, chap 11.5
Natusch DFS, Hopke PK (eds) (1983) Analytical aspects of environmental chemistry. Wiley, New York
Salomons W, Förstner U (1984) Metals in the hydrocycle. Springer, Berlin Heidelberg New York
Craig PJ (ed) (1986) Organometallic compounds in the environment. Principles and reactions. Longman, Harlow
Sunda WG, Lewis JAM (1978) Limnol Oceanogr 23:870
Sunda WG, Klaveness D, Palumbo V (1984) In: Kramer CJM, Duinker JC (eds) Complexation of trace metals in natural waters. Nijhoff/Junk, The Hague, p 393
Baker JP, Schofield CL (1982) Water Air Soil Poll 18:289
Lægreid M, Alstad J, Klaveness D, Seip HM (1983) Environ Sci Technol 17:357
Winner RW (1984) Aquatic Toxicol 5:267
Florence TM, Lumsden BG, Fardy JJ (1984) In: Kramer CJM, Duinker JC (eds) Complexation of trace metals in natural waters. Nijhoff/Junk, The Hague, p 411
Kamp-Nielsen L (1972) Deep-Sea Res 19:899
Hodge VF, Seidel SL, Goldberg ED (1979) Anal Chem 51:1256
Jacobsen A, Lund W, Jacobsen E (1987) Anal Chim Acta 200:269
Beyer ME, Bond AM, McLaughlin RJW (1975) Anal Chem 47:479
Davison W (1976) J Electroanal Chem 72:229
Davison W (1977) Limnol Oceanogr 22:746
Davison W, Gabbutt CD (1979) J Electroanal Chem 99:311
Wang J (1985) Stripping analysis. Principles, instrumentation and applications. VCH Pub, Deerfield Beach
Krull IS (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 579
Krull IS (1984) In: Lawrence JF (ed) Liquid chromatography in environmental analysis. Humana Press, Clifton, p 169
Bertsch PM, Layton WJ, Barnhisel RI (1986) Soil Sci Soc Am J 50:1449
Bertsch PM, Barnhisel RI, Thomas GW, Layton WJ, Smith SL (1986) Anal Chem 58:2583
Bertsch PM, Thomas GW, Barnhisel RI (1986) Soil Sci Soc Am J 50:825
Bertsch PM (1987) Soil Sci Soc Am J 51:825
Sadler PJ (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 563
Date AR, Gray AJ (eds) (1989) Applications of inductively coupled plasma mass spectrometry. Blackie, Glasgow
Novakov T, Chang SG, Dod RL, Gundel L (1983) In: Natusch DFS, Hopke PK (eds) Analytical aspects of environmental chemistry. Wiley, New York, p 191
Kane PF (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 643
Kester DR (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 337
Batley GE, Florence TM (1976) Anal Lett 9:379
Florence TM (1982) Anal Chim Acta 141:73
Figura P, McDuffie B (1979) Anal Chem 51:120
Laxen DP, Harrison RM (1981) Sci Total Environ 19:59
Hoffman MR, Yost EC, Eisenreich SJ, Maier WJ (1981) Environ Sci Technol 15:655
Hart BT, Davies SH (1977) Aust J Mar Freshwater Res 28:105
Buffle J, Zali O, Zumstein J, Haerdi W (1986) In: Hulanicki A (ed) Euroanalysis V, reviews on analytical chemistry. Akademiai Kiado, Budapest, p 83
Koenings JP (1976) Limnol Oceanogr 21:674
Sedlacek J, Gjessing E, Rambæk JP (1987) Sci Total Environ 62:275
Driscoll CT (1984) Intern J Environ Anal Chem 16:267
Seip HM, Müller L, Naas A (1984) Water Air Soil Poll 23:81
Sullivan TJ, Seip HM, Muniz IP (1986) Intern J Environ Anal Chem 26:61
Westøø G (1967) Acta Chem Scand 20:1790
Westøø G (1968) Acta Chem Scand 22:2277
Chiba K, Yoshida K, Tanabe K, Haraguchi H, Fawa K (1983) Anal Chem 55:450
Yamamoto J, Kaneda Y, Hikasa Y (1983) Intern J Environ Anal Chem 16:1
Minagawa K, Takisawa Y, Kifune I (1979) Anal Chim Acta 115:103
Fujita M, Iwasahima K (1981) Environ Sci Technol 15:929
Hill S, Ebdon L, Jones P (1986) Anal Proceed 23:6
Braman RS, Tompkins MA (1979) Anal Chem 51:12
Andreae MO; Byrd JT (1984) Anal Chim Acta 156:147
Jewett KL, Brinckman FE (1981) J Chromatogr Sci 19:583
Förster U (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 465
Davison RL, Natusch DFS, Wallace JR, Evans CA (1974) Environ Sci Technol 8:1107
Smith RD, Campbell JA, Nielson KK (1979) Environ Sci Technol 13:553
Karstensen KH, Lund W (1989) Sci Total Environ 79:179
Harris WR, Silberman D (1988) Environ Sci Technol 22:109
Tessier A, Campbell PGC, Bisson M (1979) Anal Chem 51:844
Lum KR, Betteridge JS, Macdonald RR (1982) Environ Technol Lett 3:57
Naranjit D, Thomassen Y, Van Loon JC (1979) Anal Chim Acta 110:307
Braman RS (1983) In: Natusch DFS, Hopke PK (eds) Analytical aspects of environmental chemistry. Wiley, New York, p 1
Braman RS, Johnson DL (1974) Environ Sci Technol 8:996
Johnson DC, Braman RS (1974) Environ Sci Technol 8:1003
Bzezinska A, Van Loon JC, Williams D, Oguma K, Fuwa K, Haraguchi IH (1983) Spectrochim Acta 38B:1339
Zimmerli B, Zimmerman H (1980) Fresenius Z Anal Chem 304:23
Braman RS, Johnson DL, Foreback CC, Ammons JM, Bricker JL (1977) Anal Chem 49:621
Hewitt CN (1986) In: Craig PJ (ed) Organometallic compounds in the environmental. Principles and reactions. Longman, Harlow, p 160
Pickering WF (1981) CRC Critical Rev Anal Chem Nov:233
Salomons W, Förstner U (1980) Environ Technol Lett 1:506
Brümmer GW (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 169
Köster W, Merkel D (1983) Landwirtsch Forsch Sonderh 39:245
Förstner U, Calmano W, Conradt K, Jaksch H, Schimkus C, Schoer J (1981) Proc Int Conf, Heavy metals in the environment, Amsterdam, p 698
Förstner U, Calmano W (1982) Vom Wasser 59:83
Luoma SN, Bryan GW (1978) J Mar Biol Ass UK 58:793
Luoma SN, Bryan GW (1979) In: Jenne EA (ed) Chemical modelling in aqueous systems. Am Chem Soc Symp Ser 93:577
Luoma SN, Bryan GW (1981) Sci Total Environ 17:165
Longbottom JE, Dressman RC, Lichtenberg JC (1973) J Assoc Off Anal Chem 56:1297
Brinckman FE, Jewett KL, Iverson EP, Irgolic KJ, Ehrhardt KC, Stockton RA (1980) J Chromatogr 191:311
Cruz RB, Lorouso C, George S, Thomassen Y, Kinrade JP, Butler LRP, Lye J, Van Loon JC (1980) Spectrochim Acta 35B:775
Crews HM, Burrell JA, McWeeny DJ (1983) J Sci Food Agric 34:997
Gardiner PE, Ottaway JM, Fell GS, Burns RR (1981) Anal Chim Acta 124:281
Falchuk KH (1977) N Engl J Med 296:1129
Selden C, Peters TJ (1979) Clin Chim Acta 98:47
Hansson L, Pettersson J, Eriksson L, Olin Å (1990) Clin Chem (in press)
Van Loon JC (1985) Selected methods of trace metal analysis: Biological and environmental samples. Wiley, New York
Andreae MO (1986) In: Craig PJ (ed) Organometallic compounds in the environmental. Principles and reactions. Longman, Harlow, p 198
Holak W (1982) Analyst 107:1457
Langseth W (1986) Anal Chim Acta 185:249
Yu TH, Arakawa Y (1983) J Chromatogr 258:189
Shiomi K, Shinagawa A, Azuma M, Yamanaka H, Kikuchi T (1983) Comp Biochem Physiol 74:393
Kneip TJ, Kleineman MT (1982) In: Cantle JE (ed) Atomic absorption spectrometry. Elsevier, Amsterdam
Bridle TR, Cote PL, Constable TW, Fraser JL (1987) Wat Sci Tech 19:1029
Sawell SE, Bridle TR, Constable TW (1988) Waste Management Res 6:227
Jackson DR, Garrett BC, Bishop TA (1984) Environ Sci Technol 18:668
Melcher RG, Peters TL, Emmel HW (1986) Topics Current Chem 134:59
Wang J (1990) Fresenius J Anal Chem 337:508–511
Griepink B (1989) Community Bureau of Reference (BCR) Brussels, personal communication
Apte SC, Howard AG (1986) J Anal At Spec 1:221
Maguire RJ, Chau YK, Bengert GA, Hale EJ, Wong PTS, Kramer O (1982) Environ Sci Technol 16:698
Ebdon L, Hill S, Ward RW (1986) Analyst 111:1113
Ebdon L, Hill S, Ward RW (1987) Analyst 112:1
Irgolic KJ, Brinckman FE (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 667
Gardiner PE, Braetter P, Negretti VE, Schulze G (1983) Spectrochim Acta 38B:427
Krull IS, Panaro KW (1985) Appl Spectrosc 39:960
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lund, W. Speciation analysis — why and how?. Fresenius J Anal Chem 337, 557–564 (1990). https://doi.org/10.1007/BF00322862
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00322862