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Speciation analysis — why and how?

  • Lectures, Part I
  • Spectrometric Methods In Environmental Analysis
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Summary

The different aspects of speciation analysis are reviewed. Species-specific instrumental techniques as well as various speciation schemes are considered for the determination of species of metals and metalloids, including organometallic compounds. The application of the methods are discussed in some detail for the analysis of natural waters, air, soil, sediment and biological samples. The relationship between metal species and bioavailability is also briefly dealt with.

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References

  1. Bernhard M, Brinckman FE, Sadler PJ (eds) (1986) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York

    Google Scholar 

  2. Leppard GG (ed) (1983) Trace element speciation in surface waters and its ecological implications. Plenum, New York

    Google Scholar 

  3. Kramer JR, Allen HE (eds) (1988) Metal speciation. Theory, analysis and application. Lewis Pub, Chelsea (Michigan)

    Google Scholar 

  4. Gardiner PHE (1987) Topics Current Chem 141:145

    Google Scholar 

  5. Hunt DTE, Wilson AL (1986) The chemical analysis of water. General principles and techniques, 2. edn. Royal Soc Chem, London, chap 11.5

    Google Scholar 

  6. Natusch DFS, Hopke PK (eds) (1983) Analytical aspects of environmental chemistry. Wiley, New York

    Google Scholar 

  7. Salomons W, Förstner U (1984) Metals in the hydrocycle. Springer, Berlin Heidelberg New York

    Google Scholar 

  8. Craig PJ (ed) (1986) Organometallic compounds in the environment. Principles and reactions. Longman, Harlow

    Google Scholar 

  9. Sunda WG, Lewis JAM (1978) Limnol Oceanogr 23:870

    Google Scholar 

  10. Sunda WG, Klaveness D, Palumbo V (1984) In: Kramer CJM, Duinker JC (eds) Complexation of trace metals in natural waters. Nijhoff/Junk, The Hague, p 393

    Google Scholar 

  11. Baker JP, Schofield CL (1982) Water Air Soil Poll 18:289

    Google Scholar 

  12. Lægreid M, Alstad J, Klaveness D, Seip HM (1983) Environ Sci Technol 17:357

    Google Scholar 

  13. Winner RW (1984) Aquatic Toxicol 5:267

    Google Scholar 

  14. Florence TM, Lumsden BG, Fardy JJ (1984) In: Kramer CJM, Duinker JC (eds) Complexation of trace metals in natural waters. Nijhoff/Junk, The Hague, p 411

    Google Scholar 

  15. Kamp-Nielsen L (1972) Deep-Sea Res 19:899

    Google Scholar 

  16. Hodge VF, Seidel SL, Goldberg ED (1979) Anal Chem 51:1256

    Google Scholar 

  17. Jacobsen A, Lund W, Jacobsen E (1987) Anal Chim Acta 200:269

    Google Scholar 

  18. Beyer ME, Bond AM, McLaughlin RJW (1975) Anal Chem 47:479

    Google Scholar 

  19. Davison W (1976) J Electroanal Chem 72:229

    Google Scholar 

  20. Davison W (1977) Limnol Oceanogr 22:746

    Google Scholar 

  21. Davison W, Gabbutt CD (1979) J Electroanal Chem 99:311

    Google Scholar 

  22. Wang J (1985) Stripping analysis. Principles, instrumentation and applications. VCH Pub, Deerfield Beach

    Google Scholar 

  23. Krull IS (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 579

    Google Scholar 

  24. Krull IS (1984) In: Lawrence JF (ed) Liquid chromatography in environmental analysis. Humana Press, Clifton, p 169

    Google Scholar 

  25. Bertsch PM, Layton WJ, Barnhisel RI (1986) Soil Sci Soc Am J 50:1449

    Google Scholar 

  26. Bertsch PM, Barnhisel RI, Thomas GW, Layton WJ, Smith SL (1986) Anal Chem 58:2583

    Google Scholar 

  27. Bertsch PM, Thomas GW, Barnhisel RI (1986) Soil Sci Soc Am J 50:825

    Google Scholar 

  28. Bertsch PM (1987) Soil Sci Soc Am J 51:825

    Google Scholar 

  29. Sadler PJ (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 563

    Google Scholar 

  30. Date AR, Gray AJ (eds) (1989) Applications of inductively coupled plasma mass spectrometry. Blackie, Glasgow

    Google Scholar 

  31. Novakov T, Chang SG, Dod RL, Gundel L (1983) In: Natusch DFS, Hopke PK (eds) Analytical aspects of environmental chemistry. Wiley, New York, p 191

    Google Scholar 

  32. Kane PF (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 643

    Google Scholar 

  33. Kester DR (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 337

    Google Scholar 

  34. Batley GE, Florence TM (1976) Anal Lett 9:379

    Google Scholar 

  35. Florence TM (1982) Anal Chim Acta 141:73

    Google Scholar 

  36. Figura P, McDuffie B (1979) Anal Chem 51:120

    Google Scholar 

  37. Laxen DP, Harrison RM (1981) Sci Total Environ 19:59

    Google Scholar 

  38. Hoffman MR, Yost EC, Eisenreich SJ, Maier WJ (1981) Environ Sci Technol 15:655

    Google Scholar 

  39. Hart BT, Davies SH (1977) Aust J Mar Freshwater Res 28:105

    Google Scholar 

  40. Buffle J, Zali O, Zumstein J, Haerdi W (1986) In: Hulanicki A (ed) Euroanalysis V, reviews on analytical chemistry. Akademiai Kiado, Budapest, p 83

    Google Scholar 

  41. Koenings JP (1976) Limnol Oceanogr 21:674

    Google Scholar 

  42. Sedlacek J, Gjessing E, Rambæk JP (1987) Sci Total Environ 62:275

    Google Scholar 

  43. Driscoll CT (1984) Intern J Environ Anal Chem 16:267

    Google Scholar 

  44. Seip HM, Müller L, Naas A (1984) Water Air Soil Poll 23:81

    Google Scholar 

  45. Sullivan TJ, Seip HM, Muniz IP (1986) Intern J Environ Anal Chem 26:61

    Google Scholar 

  46. Westøø G (1967) Acta Chem Scand 20:1790

    Google Scholar 

  47. Westøø G (1968) Acta Chem Scand 22:2277

    Google Scholar 

  48. Chiba K, Yoshida K, Tanabe K, Haraguchi H, Fawa K (1983) Anal Chem 55:450

    Google Scholar 

  49. Yamamoto J, Kaneda Y, Hikasa Y (1983) Intern J Environ Anal Chem 16:1

    Google Scholar 

  50. Minagawa K, Takisawa Y, Kifune I (1979) Anal Chim Acta 115:103

    Google Scholar 

  51. Fujita M, Iwasahima K (1981) Environ Sci Technol 15:929

    Google Scholar 

  52. Hill S, Ebdon L, Jones P (1986) Anal Proceed 23:6

    Google Scholar 

  53. Braman RS, Tompkins MA (1979) Anal Chem 51:12

    Google Scholar 

  54. Andreae MO; Byrd JT (1984) Anal Chim Acta 156:147

    Google Scholar 

  55. Jewett KL, Brinckman FE (1981) J Chromatogr Sci 19:583

    Google Scholar 

  56. Förster U (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 465

    Google Scholar 

  57. Davison RL, Natusch DFS, Wallace JR, Evans CA (1974) Environ Sci Technol 8:1107

    Google Scholar 

  58. Smith RD, Campbell JA, Nielson KK (1979) Environ Sci Technol 13:553

    Google Scholar 

  59. Karstensen KH, Lund W (1989) Sci Total Environ 79:179

    Google Scholar 

  60. Harris WR, Silberman D (1988) Environ Sci Technol 22:109

    Google Scholar 

  61. Tessier A, Campbell PGC, Bisson M (1979) Anal Chem 51:844

    Google Scholar 

  62. Lum KR, Betteridge JS, Macdonald RR (1982) Environ Technol Lett 3:57

    Google Scholar 

  63. Naranjit D, Thomassen Y, Van Loon JC (1979) Anal Chim Acta 110:307

    Google Scholar 

  64. Braman RS (1983) In: Natusch DFS, Hopke PK (eds) Analytical aspects of environmental chemistry. Wiley, New York, p 1

    Google Scholar 

  65. Braman RS, Johnson DL (1974) Environ Sci Technol 8:996

    Google Scholar 

  66. Johnson DC, Braman RS (1974) Environ Sci Technol 8:1003

    Google Scholar 

  67. Bzezinska A, Van Loon JC, Williams D, Oguma K, Fuwa K, Haraguchi IH (1983) Spectrochim Acta 38B:1339

    Google Scholar 

  68. Zimmerli B, Zimmerman H (1980) Fresenius Z Anal Chem 304:23

    Google Scholar 

  69. Braman RS, Johnson DL, Foreback CC, Ammons JM, Bricker JL (1977) Anal Chem 49:621

    Google Scholar 

  70. Hewitt CN (1986) In: Craig PJ (ed) Organometallic compounds in the environmental. Principles and reactions. Longman, Harlow, p 160

    Google Scholar 

  71. Pickering WF (1981) CRC Critical Rev Anal Chem Nov:233

  72. Salomons W, Förstner U (1980) Environ Technol Lett 1:506

    Google Scholar 

  73. Brümmer GW (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 169

    Google Scholar 

  74. Köster W, Merkel D (1983) Landwirtsch Forsch Sonderh 39:245

    Google Scholar 

  75. Förstner U, Calmano W, Conradt K, Jaksch H, Schimkus C, Schoer J (1981) Proc Int Conf, Heavy metals in the environment, Amsterdam, p 698

  76. Förstner U, Calmano W (1982) Vom Wasser 59:83

    Google Scholar 

  77. Luoma SN, Bryan GW (1978) J Mar Biol Ass UK 58:793

    Google Scholar 

  78. Luoma SN, Bryan GW (1979) In: Jenne EA (ed) Chemical modelling in aqueous systems. Am Chem Soc Symp Ser 93:577

    Google Scholar 

  79. Luoma SN, Bryan GW (1981) Sci Total Environ 17:165

    Google Scholar 

  80. Longbottom JE, Dressman RC, Lichtenberg JC (1973) J Assoc Off Anal Chem 56:1297

    Google Scholar 

  81. Brinckman FE, Jewett KL, Iverson EP, Irgolic KJ, Ehrhardt KC, Stockton RA (1980) J Chromatogr 191:311

    Google Scholar 

  82. Cruz RB, Lorouso C, George S, Thomassen Y, Kinrade JP, Butler LRP, Lye J, Van Loon JC (1980) Spectrochim Acta 35B:775

    Google Scholar 

  83. Crews HM, Burrell JA, McWeeny DJ (1983) J Sci Food Agric 34:997

    Google Scholar 

  84. Gardiner PE, Ottaway JM, Fell GS, Burns RR (1981) Anal Chim Acta 124:281

    Google Scholar 

  85. Falchuk KH (1977) N Engl J Med 296:1129

    Google Scholar 

  86. Selden C, Peters TJ (1979) Clin Chim Acta 98:47

    Google Scholar 

  87. Hansson L, Pettersson J, Eriksson L, Olin Å (1990) Clin Chem (in press)

  88. Van Loon JC (1985) Selected methods of trace metal analysis: Biological and environmental samples. Wiley, New York

    Google Scholar 

  89. Andreae MO (1986) In: Craig PJ (ed) Organometallic compounds in the environmental. Principles and reactions. Longman, Harlow, p 198

    Google Scholar 

  90. Holak W (1982) Analyst 107:1457

    Google Scholar 

  91. Langseth W (1986) Anal Chim Acta 185:249

    Google Scholar 

  92. Yu TH, Arakawa Y (1983) J Chromatogr 258:189

    Google Scholar 

  93. Shiomi K, Shinagawa A, Azuma M, Yamanaka H, Kikuchi T (1983) Comp Biochem Physiol 74:393

    Google Scholar 

  94. Kneip TJ, Kleineman MT (1982) In: Cantle JE (ed) Atomic absorption spectrometry. Elsevier, Amsterdam

    Google Scholar 

  95. Bridle TR, Cote PL, Constable TW, Fraser JL (1987) Wat Sci Tech 19:1029

    Google Scholar 

  96. Sawell SE, Bridle TR, Constable TW (1988) Waste Management Res 6:227

    Google Scholar 

  97. Jackson DR, Garrett BC, Bishop TA (1984) Environ Sci Technol 18:668

    Google Scholar 

  98. Melcher RG, Peters TL, Emmel HW (1986) Topics Current Chem 134:59

    Google Scholar 

  99. Wang J (1990) Fresenius J Anal Chem 337:508–511

    Google Scholar 

  100. Griepink B (1989) Community Bureau of Reference (BCR) Brussels, personal communication

  101. Apte SC, Howard AG (1986) J Anal At Spec 1:221

    Google Scholar 

  102. Maguire RJ, Chau YK, Bengert GA, Hale EJ, Wong PTS, Kramer O (1982) Environ Sci Technol 16:698

    Google Scholar 

  103. Ebdon L, Hill S, Ward RW (1986) Analyst 111:1113

    Google Scholar 

  104. Ebdon L, Hill S, Ward RW (1987) Analyst 112:1

    Google Scholar 

  105. Irgolic KJ, Brinckman FE (1986) In: Bernhard M, Brinckman FE, Sadler PJ (eds) The importance of chemical “speciation” in environmental processes. Springer, Berlin Heidelberg New York, p 667

    Google Scholar 

  106. Gardiner PE, Braetter P, Negretti VE, Schulze G (1983) Spectrochim Acta 38B:427

    Google Scholar 

  107. Krull IS, Panaro KW (1985) Appl Spectrosc 39:960

    Google Scholar 

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Lund, W. Speciation analysis — why and how?. Fresenius J Anal Chem 337, 557–564 (1990). https://doi.org/10.1007/BF00322862

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  • DOI: https://doi.org/10.1007/BF00322862

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