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Grafting of styrene onto carbon fiber having perester groups

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Summary

The oxidized carbon fiber having t-butyl perester groups was prepared by the esterification of acid chloride groups on the carbon fiber with t-butyl hydroperoxide. Then, graft polymerization of styrene onto the carbon fiber having t-butyl perester group was carried out. The concentration of monomer affected grafting efficiency. The grafting efficiency increases with the polymerization time and reachs a constant value above 70°C. Addition of Fe2+ and Cu2+ to the polymerization system at a concentration of 0.5–1.0×10-5 mol/l gave the maximum grafting efficiency.

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Authors and Affiliations

  1. Department of Industrial Chemistry, Chiba Institute of Technology, 2-17-1, Tsudanuma, Narashino-shi, 275, Chiba, Japan

    Ryutoku Yosomiya & Takao Fujisawa

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  1. Ryutoku Yosomiya
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  2. Takao Fujisawa
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Yosomiya, R., Fujisawa, T. Grafting of styrene onto carbon fiber having perester groups. Polymer Bulletin 13, 7–14 (1985). https://doi.org/10.1007/BF00264234

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