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Electrical properties of polyaniline films formed in acid with and without Cs+ ions in the electrolyte

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Abstract

The effect of Cs+ ions added to the electrolyte for polyaniline films electrosynthesized in 0.1 m aniline/0.5m H2SO4 was investigated. Some properties of PANI films, such as the capacitance, the ohmic resistance and the charge-transfer resistance were obtained using electrochemical impedance spectroscopy. It was found that Cs+ ions used during PANI synthesis change its morphology, with a consequent increase in capacitance and conductivity, and a decrease in charge-transfer resistance.

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Authors and Affiliations

  1. Departamento de Química, Universidade Federal de Sao Carlos, Caixa Postal 676, 13560, Sao Carlos, SP, Brasil

    S. R. Biaggio & C. L. F. Oliveira

  2. Departamento de Química, Facultad de Ciencia, Universidad de Santiago de Chile, Casilla 307, Santiago 2, Chile

    M. J. Aguirre & J. H. Zagal

Authors
  1. S. R. Biaggio
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  2. C. L. F. Oliveira
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  3. M. J. Aguirre
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  4. J. H. Zagal
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Biaggio, S.R., Oliveira, C.L.F., Aguirre, M.J. et al. Electrical properties of polyaniline films formed in acid with and without Cs+ ions in the electrolyte. J Appl Electrochem 24, 1059–1065 (1994). https://doi.org/10.1007/BF00241199

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  • DOI: https://doi.org/10.1007/BF00241199

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