Abstract
Methanol is an important industrial chemical, ranked 22d (Chang and Tikkamen 1988) in the top 50 products in the United States. It is also an alternate automotive fuel that, if adopted even partially, will require a multifold increase in production to meet the higher demand.
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References
Anderson, A.B., and J.J. Maloney. 1987. Activation of methane on iron, nickel and platinum surfaces. A molecular orbital study. American Chemical Society Preprints, Div. Fuel Chem. 194th National Meeting New Orleans, Aug. 31–Sept. 4, 1987 Vol. 32 /3, p. 291.
Anshits, A.G., A.N. Shigapov, S.N. Vereshchagin, and V.N. Shevin. 1990. C2 hydrocarbon formation from methane on silver membrane. Catal. Today, 6: 593.
Ausloos, P., R.E. Rebbert, and S.G. Lias. 1965. Direct and Inert-Gas-Sensitized Radiolysis and Photolysis of Methane in the Solid Phase. J. Chem. Phys. 42:540.
Baerns, M., K. van der Wiele, and J.R.H. Ross. 1989. Methane Activation—A Bibliography Catal. Today 4: 471.
Bauerle, G.L. 1964. Surface and catalytic effects in high pressure oxidation of methane. Ph.D. Dissertation, University of Oklahoma, Norman, OK.
Bauerle, G.L., J.L. Lott, and C.M. Sliepcevich. 1974a. Oxidation of methane at elevated pressures I. Ignition delay. J. Fire & Flammability 5: 136.
Bauerle, G.L., J.L. Lott, and C.M. Sliepcevich. 1974b. Oxidation of methane at elevated pressures II. A reaction mechanism. J. Fire & Flammability 5: 190.
Baughcum, S.L., R.C. Oldenborg, W.C. Danen, G.E. Streit, and C. Rofer. 1986. Laser-initiated chain reactions in the partial oxidation of methane. In SPIE Proceedings, Vol. 669, Laser Appl. Chem, June.
Bell, K.M., and C.A. McDowell. 1961. The mercury photosensitized oxidation of hydrocarbons. Can. J. Chem. 39: 1419.
Bergman, R.G. 1984. Selective oxidative of methane. Science 223: 902.
Boni, A.A., and R.C. Penner. 1977. Sensitivity analysis of a mechanism for methane oxidation kinetics. Combust. Sci. Technol. 15: 99.
Boomer, E.H., and V. Thomas. 1937. The oxidation of methane at high pressures. III. Experiments using pure methane and principally copper catalysts. Can. J. Res. Sect. B. 15: 414.
Borrell, P., C.J. Cobos, A.E. Croce de Cobos, H. Hippler, K. Luther, A.R. Ravishankara, and J. Troe, 1985. Radical association reactions in gases at high pressures. Ber. Bunsenges. Phys. Chem. 89: 337.
Burch, R., G.D. Squire, and S.C. Tsang. 1989. Direct conversion of methane to methanol. J. Chem. Soc., Faraday Trans. 1 85: 3561.
Calvert, J.G., and J.N. Pitts., Jr. 1966. Photochemistry. New York: J. Wiley & Sons.
Chan, Y.W., and R.B. Wilson, Jr. 1987. Partial oxidation of methane using supported porphyrin and phthalocyanine complexes. American Chemical Society Preprints, Div. Fuel. Chem. 194th National Meeting, New Orleans, Aug. 31-Sept. 4, 1987, Vol. 33 /3, p. 453.
Chang, R., and W. Tikkanen. 1988. Kinetics of the photochemical reaction of gas mixtures of methane and water and the effects of added oxygen. In The Top Fifty Industrial Chemicals. New York: Random House.
Corder, R.E., E.R. Johnson, J.L. Vega, E.C. Clausen, and J.L. Gaddy. 1987. Biological production of methanol from methane. American Chemical Society Preprints, Div. Fuel Chem. 194th National Meeting, New Orleans, Aug. 31-Sept. 4, 1987, Vol. 33 /3, p. 469.
Cran, J. 1988. Alta Plan, Calgary, Private communication.
Crocco, J. 1990. Methanol yesterday, today and tommorrow. Chem. Ind. (London) 97.
Dowdy, D. 1988. Private communication.
Durante, V.A., J.E. Lyons, and D.W. Walker. 1989. Vapor phase catalytic hydroxylation of methane. Preprints, Methane Activation Symposium, Pacifichem 89, Honolulu, Hawaii, Dec. 17–20, 1989, p. 23.
Edwards, J.H., and N.R. Foster. 1988. The potential for methanol production from natural gas by direct catalytic partial oxidation. Fuel Sci. Technol. Intl. 48: 365.
Edwards, J.H., and R.J. Tyler. 1989. The oxidative coupling of methane in a fluidized-bed-reactor. Catal. Today 4: 365.
Eng, D., and M. Stoukides. 1988. Partial oxidation of methane in a solid electrolyte cell. In Proceedings of the 9th International Congress on Catalysis, Calgary, 1988, Vol. 2, p. 975.
Foster, N.R. 1985. Direct Catalytic oxidation of methane to methanol-A review. Appl. Catal. 19: 1.
Fox, J.M., III, T.P. Chen, and B.D. Degen. 1990. An evaluation of direct methane conversion processes. Chem. Eng. Prog. Apr.: 43.
Fukuoka, N., K. Omata, and K. Fujimoto. 1989. Effect of additives on partial oxidation of methane. Preprints, Methane Activation Symposium, Pacifichem 89, Honolulu, Hawaii, Dec. 17–20, 1989, p. 106.
Garcia, E.Y., and D.A. Loftier. 1984. Partial oxidation of methane. Lat. Am. J. Chem. Eng. Appl. Chem. 14: 267.
Geerts, J.W.M.H., J.H.B.J. Hoebind, and K. van der Wiele. 1990. Methanol from natural gas. Proven and new technologies. Catal. Today 6: 613.
Gerasimov, S.P. 1988. Mechanism of methane photoxidation on V/SiO2 catalyst. Kinet. Catal. Lett. 32: 57.
Gesser, H.D. 1989. Unpublished results.
Gesser, H.D., and N.R. Foster. 1986. Unpublished results.
Gesser, H.D., N.R. Hunter, and L.A. Morton. 1990. Unpublished results.
Gesser, H.D., N.R. Hunter, and C.B. Prakash. 1985. The direct conversion of methane to methanol by controlled oxidation. Chem. Rev. 85: 235.
Glockler, G., and S.C. Lind. 1939. The Electrochemistry of Gasses and Other Dielectrics. New York: J. Wiley & Sons.
Gould, R.F. (ed.). 1959. Chemical Reactions in Electrical Discharges. Adv. Chem. Series 80 Washington, DC: American Chemical Society.
Gratzel, M., K.R. Thampi, and J. Kiwi. 1989. Methane oxidation at room temperature and atmospheric pressure activated by light via polytungstate dispersion on titania. J. Phys. Chem. 93: 4128.
Hamilton, T.P., and H.F. Schaefer III. 1989. The reaction of methanol with molecular oxygen: A semiquantitative estimate of the activation energy. J. Chem. Phys. 90: 6391.
Hardwicke, N.L. 1966. The mechanism of partial oxidation of methane at high pressures. Ph.D. Dissertation, University of Oklahoma, Norman, OK
Hardwicke N.L., J.L. Lott, and C.M. Sliepcevich. 1969. Oxidation of methane at high pressures. Ind. Eng. Chem., Proc. Des. Derr. 8: 133.
Helton, T.E., and R.G. Anthony. 1989. Methanol and formaldehyde production from natural gas. Preprints, Methane Activation Symposium, Pacifichem 89, Honolulu, Hawaii, Dec. 17–20, p. 143.
Hill, C.L. (ed.). 1989a. Activation and Functionalization of Alkanes. New York: J. Wiley & Sons.
Hill, C.L. (guest ed.). 1989b. Alkane activation and functionalization. New J. Chem. 10/11:645–750.
Hill, W., B.N. Shelimov, and V.B. Karansky. 1987. Photoinduced reactions of methane with molybdena supported on silica. J. Chem. Soc., Faraday Trans. 1 83: 2381.
Holloban, J.R., and A.T. Bell (eds.). 1974. Techniques and Applications of Plasma Chemistry. New York: Wiley.
Hunter, N.R., H.D. Gesser, L.A. Morton, and D.P.C. Fung. 1985. The direct conversion of natural gas to methanol by controlled oxidation at high pressures. In Proceedings of the 35th Canadian Chemical Engineering Conference, Calgary, Oct. 6–9, Vol. 2, p. 486.
Hunter, N.R., H.D. Gesser, L.A. Morton, and P.S. Yarlagadda. 1990. Methanol formation at high pressure by the catalyzed oxidation of natural gas and by the sensitized oxidation of methane. Appl. Catal. 57: 45.
Hutchings, G.J., M.S. Scurrell, and J.R. Woodhouse. 1989. Oxidative coupling of methane using oxide catalysts. Chem. Soc. Rev. 18: 251.
Il’chenko, N.I., A.I. Bostan, L.Yu. Dulgikhnd, and G.I. Golodets. 1987. A partial oxidation and oxidative condensation of methane with participation of nitrous oxide on a vanaduim pentoxide/silica catalyst. Theoret. Experim. Chem. USSR 23: 641.
Il’chenko, N.I., A.I. Bostan, and G.I. Golodets. 1988. Effect of the Chemical nature of Supported Metal Ions on/heir Catalyst Properties in Methane Oxidation by Nitrous Oxide. Theoret. Experim. Chem. USSR 24: 455.
Il’chenko, N.I., and G.I. Golodets. 1988. Causes of the higher selectivity of methane partial oxidation catalysts using nitrous oxide as an oxidizing agent. Theoret. Experim. Chem. 24: 727.
Il’chenko, N.I., L.N. Raevskaya, A.I. Bostan, and G.I. Golodets. 1988. Oxidative condensation of methane on metal-like compounds. Theoret. Experim. Chem. USSR 24: 638.
Il’chenko, N.I., V.G. Ilyine, L.N. Raevskaya, N.V. Turtutina, A.D. Onishchenko, and A.I. Bostan. 1989. Oxidative condensation of methane on modified natural mordenites. React. Kinet. Catal. Lett. 38: 141.
Jeong, G., and K.J. Klabunde. 1986. Metal atom reactions with methane. Boron, aluminum, gallium and indium atoms and dimers. J. Am. Chem. Soc. 108: 7103.
Karmilova, L.A., N.S. Enikolopyan, and A.B. Nalbandyan. 1960. The kinetics and mechanism of the oxidation of methane. Zh. Fiz. Khim. 34: 550, 990, 1176.
Karmilova, L.A., N.S. Enikolopyan, and A.B. Nalbandyan. 1961. The kinetics and mechanism of methane oxidation. Zh. Fiz. Khim. 35: 1046, 1435, 1458.
Kastanas, G.N., G.A. Tsigdinos, and J. Schwank. 1988a. Effect of small amounts of ethane on the selective oxidation of methane over silicic acid and quartz glass surfaces. J. Chem. Soc., Chem. Commun. 1298.
Kastanas, G.N., G.A. Tsigdinos, and J. Schwank. 1988b. Selective oxidation of methane over Vycor glass, quartz glass, and various silica, magnesium and alumina surfaces. Appl Catal. 44: 33.
Khenkin, A.M., and A.E. Shilov. 1987. Electrochemical model of alkane oxidation by cytochrome P-450. React. Kinet. Catal. Lett. 33: 125.
Khenkin, A.M., and A.E. Shilov. 1989. Biomimetic alkane oxidation in the presence of iron complexes. New J. Chem. 13: 659.
Klabunde, K.J., and Y. Tanaka. 1983. Activation of methane with metal atoms at 10K without photolysis. J. Am. Chem. Soc. 105: 3544.
Kondrat’ev, V.N. 1971. Rate Constants of Gas Phase Reactions. Nauka: Moscow.
Kuo, J.C.W. 1987. Evaluation of direct methane conversion to higher hydrocarbons and oxygenates. Final Report Contract No. DE-AC22–86PC90009, US Department of Energy.
Lott, J.L. 1965. The selective oxidation of methane at high pressures. Ph.D. Dissertation, University of Oklahoma, Norman, OK.
Lott, J.L., and C.M. Sliepcevich. 1967. Partial oxidation of methane at high pressures. Ind. Eng. Chem., Proc. Des. Dey. 6: 67.
MacGiolla Coda, E., M. Kennedy, J.B. McMonagle, and B.K. Hodnett. 1990. Oxidation of methane to formaldehyde over supported molybdena catalysts at ambient pressure. Isolation of the selective oxidation product. Catal. Today 6: 559.
Mallinson, R.G., C.M. Sliepcevich, and S. Rusek. 1987. Methane partial oxidation in alternating electric fields. American Chemical Society Preprints, Div. Fuel Chem. 194th National Meeting, New Orleans, Aug. 31-Sept. 4, 1987, Vol. 32 /3, p. 266.
McConkey, B.H., and P.R. Wilkinson. 1967. Oxidation of methane to formaldehyde in a fluidized bed reactor. Ind. Eng. Chem. Proc. Des. Dee., 6: 436.
Meltser, L.Z., T.A. Garibyan, R.R. Grigoryan, A.A. Muradyan, and L.N. Kurina. 1989. Effect of Homogeneous Initiator on Heterogeneous Homogeneous oxidation of Methane. React. Kinet. Catal. Lett. 38: 229.
Meubus, P., and G. Jean. 1987. Methane polymerization usings hollow cathode. American Chemical Society Preprints, Div. Fuel Chem. 194th National Meeting, New Orleans, Aug. 31-Sept. 4, 1987, Vol. 32 /3, p. 260.
Morton, L.A., N.R. Hunter, and H.D. Gesser. 1984. The production of methanol by the controlled oxidation of methane at high pressure. Final Report, CAN-MET, Ottawa, June 1984. CANM-87:000414, EDB-88–025858, Report No. MU/C-8406; Microlog-87–02229.
Morton, L., N. Hunter and H. Gesser. 1990. Methanol: A fuel for today and tomorrow. Chem. Ind. (London) 457.
Ogura, K., and M. Kataoka. 1988. Photochemical conversion of methane. J. Mol. Catal. 43: 371.
Ogura, K., C.T. Migita, and M. Fujita. 1988. Conversion of methane to oxygen-containing compounds by the photochemical reactions. Ind. Eng. Chem. Res. 27: 1387.
Ogura, K., C.T. Migita, and Y. Ito. 1990. Combined photochemical and electrochemical oxidation of methane. J. Electrochem. Soc. 137: 500.
Ogura, K., C.T. Migita, and T. Yamada. 1990. Kinetics of the photochemical reaction of gas mixtures of methane and water and the effects of added oxygen. J. Photochem., Photobiol. A, Chem. 52: 241.
Olah, G.A. 1987a. Electrophilic methane conversion. Acc. Chem. Res. 20:422. Olah, G.A. 1987b. Electrophilic methane conversion. Makromol. Chem., Macro-mol. Symp. 13 /14: 1.
Omata, K., S. Hashimoto, H. Tominaga, and K. Fujimoto. 1989. Oxidative coupling of methane using a membrane reactor. Appl. Catal. 52: L1.
Onsager, O.T. 1990. Private communication.
Onsager, O.T., P. Soraker, and R. Lodeng. 1989. Experimental investigation and computer simulation of homogeneous gas phase oxidation of methane to methanol. Preprints, Methane Activation Symposium, Pacifichem 89, Honolulu, Hawaii, Dec. 17–20, 1989, p. 113.
Oshima, Y., M. Saito, S. Koda, and H. Tominaga. 1988. Partial oxidation of methane by laser-initiated chain reaction. Chem. Lett. 203.
Otsuka, K., S. Yokoyama, and A. Morikawa. 1985. Catalytic activity and selectivity control for oxidative coupling of methane by oxygen-pumping through yttriastabilized zirconia. Chem. Lett. 319.
Patras, L.E., and A. Tang. 1987. Bioconversion of methane to methanol by Methylobacterium organophilum. American Chemical Society Preprints, Div. Fuel Chem. 194th National Meeting, New Orleans, Aug. 31-Sept. 4, 1987, Vol. 33 /3, p. 462.
Perkins, W.G. 1973. Permeation and outgassing of vacuum materials. J. Vac. Sci. Technol. 10: 543.
Pitchai, R., and K. Klier. 1986. Partial oxidation of methane. Catal. Rev.-Sci. Eng. 28: 13.
Ryabov, A.D. 1990. Mechanism of intermolecular activation of C-H bonds in transition-metal complexes. Chem. Rev. 90: 403.
Sayyed, B.A., and P.C. Stair. 1990. Laser-induced activation of methane at oxide surfaces: A probe of radical-surface interactions. J. Phys. Chem. 94: 409.
Schwartz, J. 1985. Alkane activation by oxide-bound organorhodium complexes. Acc. Chem. Res. 18: 302.
Schwartz, J. 1987. Alkane activation by oxide-bound organorhodium complexes. American Chemical Society Preprints, Div. Fuel Chem. 194th National Meeting, New Orleans, Aug. 31-Sept. 4, 1987, Vol. 32 /3, p. 286.
Seimonides, S. and M. Stoukides. 1986. Electrochemical modification of Ag-MgO catalyst electrodes during methane oxidation. J. Electrochem. Soc. 133: 1535.
Shelnutt, J.A., F.V. Stohl, and B. Granoff. 1987. Computer-aided molecular design of alkane-activation catalysts. American Chemical Society Preprints, Div. Fuel Chem., 194th National Meeting, New Orleans, Aug. 31-Sept. 4, 1987, Vol. 33 /3, p. 479.
Shilov, A.E. 1989. In Activation and Furjctionalization of Alkanes, ed. C.L. Hill, P. I. New York: Wiley.
Sokolovskii, V.D. 1987. Some principles of choosing catalysts for selective conversions of organic compounds at C-H bonds. React. Kinet. Catal. Lett. 35: 337.
Stoutland, P.O., R.G. Bergman, S.P. Nolan, and C.D. Hoff. 1988. The thermodynamic driving force for C-H activation at iridium. Polyhedron 7: 1429.
Tsang, W., and R.F. Hampson. 1986. Chemical kinetic data base for combustion chemistry. Phys. Chem. Ref. Data 15: 1087.
Urban, J., V. Klimo, and J. Tino. 1984. Quantum chemical modelling of reactions in hydrocarbon combination. Study of the CH, + 02 reactions. Collect. Czech. Chem. Commun. 49: 1440.
Vardanyan, I.A., S. Yan, and A.B. Nalbandyan. 1981. Mechanism of the thermal oxidation of methane. Kinet. Katal. 22: 845.
Vedeneev, V.I. 1990. Private communication.
Vedeneev, V.I., M.Y. Gol’denberg, N.I. Gorban, and M.A. Teitel’boim. 1987. Mechanism of the initial stage of the oxidation of methane at high pressures. Chem. Phys. USSR 6: 626.
Vedeneev, V.I., M.Y. Gol’denberg, N.I. Gorban, and M.A. Teitel’boim. 1988. Quantitative model of oxidation of methane at high pressures. Parts I, II, III, and IV. Kinet. Katal. 29:7, 14, 1291, and 1297.
Venugopolon, M. (ed.). 1971. Reactions under Plasma Conditions. New York: Wiley-Interscience.
Volodin, A.M., and A.E. Cherkashin. 1981. ESR spectrum of methyl radicals on ZnO surface. React. Kinet. Catal. Lett. 18: 243.
Westbrook, C.K., and F.L. Dryer. 1984. Chemical kinetic modeling of hydrocarbon combustion. Prog. Energy Combust. Sci. 10: 1.
Wiezevich, P.K., and P.K. Frolich. 1934. Direct oxidation of saturated hydrocarbons at high pressures. Ind. Eng. Chem. 26: 267.
Yamazaki, H., and R.J. Cvetanovic. 1964. Collisional deactivation of the excited singlet oxygen atoms and their insertion into the C— H bonds of programs. J. Chem. Phys. 41: 3703.
Yarlagadda, P.S., L.A. Morton, N.R. Hunter, and H.D. Gesser. 1986. Product optimization of the direct conversion process of natural gas to methanol by controlled oxidation. Final Report, Sept. 1986, CANMET, Ottawa. CANM87:000386, EDB-86:025860 Report No. MU/C-8609; Microlog-87–02221.
Yarlagadda, P.S., L.A. Morton, N.R. Hunter, and H.D. Gesser. 1987. Direct catalytic conversion of methane to higher hydrocarbons. Fuel Sci. Technol. Intl. 5: 169.
Yarlagadda, P.S., L.A. Morton, N.R. Hunter, and H.D. Gesser. 1988. Direct conversion of methane to methanol in a flow reactor. Ind. Eng. Chem. Res. 27: 252.
Yarlagadda, P.S., L.A. Morton, N.R. Hunter, and H.D. Gesser. 1990. Temperature oscillations during the high pressure partial oxidation of methane in a tubular flow reactor. Combust. & Flame 79: 216.
Yun, C., M. Anpo, Y. Mizokoshi, and Y. Kubokawa. 1980. Oxidation of alkanes and alkenes by N20 over UV irradiated MgO. Chem. Lett. 799.
Zanthoff, H., and M. Baerns. 1990. Ind. Eng. Chem. Res. 29: 2.
Zhu, Q., M. Zhang, Y. Xiao, and X. Zhao. 1989. Studies of the controlled oxidation of methane to formaldehyde and methanol. Preprints, Methane Activation Symposium, Pacifichem 89, Honolulu, Hawaii, Dec. 17–20, p. 117.
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Gesser, H.D., Hunter, N.R. (1992). The Direct Conversion of Methane to Methanol (DMTM). In: Wolf, E.E. (eds) Methane Conversion by Oxidative Processes. Van Nostrand Reinhold Catalysis Series. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-7449-5_12
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