Yield processes in glassy polymers

Crist, B.

doi:10.1007/978-94-011-5850-3_4

B. Crist

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Abstract

Virtually all solid polymers — amorphous polymers below the glass transition temperature T _g or crystalline polymers below the melting temperature T _m — undergo a permanent shape change when subjected to a stress of sufficient magnitude. This chapter focuses on the onset of irreversible deformations in glassy polymers, i.e. the transition from elastic to plastic behaviour. Reversible elastic and linear viscoelastic deformations, which result from small stresses with corresponding strains ε < 0.01, were treated in Chapter 3. Chapter 5 addresses large irreversible strains and associated phenomena that develop after the transition.

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References

Aboulfaraj, M, G’Sell, C, Mangelinck, D. and McKenna, G.B. (1994) J. Non-Cryst. Solids, 172-174, 615–621.
Article CAS Google Scholar
Argon, A.S. (1973) Phil. Mag., 28, 839–865.
Article CAS Google Scholar
Argon, A.S. (1993) in Materials Science and Technology, Vol. 6 (ed. H. Mughrabi), VCH, New York, pp. 461–508.
Google Scholar
Argon, A.S. and Bessonov, M.I. (1977a) Polym. Eng. Sci., 17, 174–182.
Article CAS Google Scholar
Argon, A.S. and Bessonov, M.I. (1977b) Phil. Mag., 35, 917–933.
Article CAS Google Scholar
Argon, A.S., Bulatov, V.V, Mott, P.H. and Suter, U.W. (1995) J. Rheol., 39, 377–399.
Article CAS Google Scholar
Bauwens-Crowet, C, Bauwens, J.C. and Homès, G.A. (1972) J. Mater. Sci., 7, 176–183.
Article CAS Google Scholar
Bowden, P.B. (1973) in The Physics of Glassy Polymers (ed. R.N. Haward), John Wiley, New York, Ch. 5.
Google Scholar
Bowden, P.B. and Jukes, J.A. (1972) J. Mater. Sci., 7, 52–63.
Article CAS Google Scholar
Bowden, P.B. and Raha, S. (1970) Phil. Mag., 22, 463–482.
Article CAS Google Scholar
Bowden, P.B. and Raha, S. (1974) Phil. Mag., 29, 149–166.
Article CAS Google Scholar
Boyce, M.C., Arruda, E.M. and Jayachandran, R. (1994) Polym. Eng. Sci., 34, 716–725.
Article CAS Google Scholar
Brady, T.E. and Yeh, G.S.Y. (1971) J. Appl. Phys., 42, 4622–4630.
Article CAS Google Scholar
Brown, D. and Clarke, J.H.R. (1991) Macromolecules, 24, 2075–2082.
Article CAS Google Scholar
Brown, N. (1983) J. Mater. Sci., 18, 2241–2254.
Article CAS Google Scholar
Brown, N. (1986) in Failure of Plastics (eds W. Brostow and R.D. Corneliussen), Hanser, New York, Ch. 6.
Google Scholar
Buchdahl, R. (1958) J. Polym. Sci., 28, 239–242.
Article Google Scholar
Bulatov, V.V. and Argon, A.S. (1994) Modelling Simul. Mater. Sci. Eng., 2, 203–222.
Article Google Scholar
Crist, B. (1993) in Materials Science and Technology, Vol. 12 (ed. E.L. Thomas), VCH, New York, Ch. 10.
Google Scholar
Dettenmaier, M., Maconnachie, A., Higgins, J.S. et al. (1986) Macromolecules, 19, 773–778.
Article CAS Google Scholar
Diaz-Calleja, R., Ribes-Greus, A. and Gomez-Ribelles, J.L. (1989) Polymer, 30, 1433–1438.
Article CAS Google Scholar
Escaig, B. (1984) Polym. Sci Eng., 24, 737–749.
Article CAS Google Scholar
Fan, CF. (1995) Macromolecules, 28, 5215–5224.
Article CAS Google Scholar
Gilmour, I.W., Trainor, A. and Haward, R.N. (1979) J. Appl. Polym. Sci., 23, 3129–3138.
Article CAS Google Scholar
Gloaguen, J.M, Escaig, B. and Lefebvre, J.M. (1995) J. Mater. Sci., 30, 1111–1116.
Article CAS Google Scholar
Grenet, J. and G’Sell, C. (1990) Polymer, 31, 205–265.
Article Google Scholar
G’Sell, C. (1986) in Strength of Metals and Alloys, Vol. 3 (eds H.J. McQueen, J.P. Bailon, J.L Dickson et al.), Pergamon Press, New York, pp. 1943–1982.
Google Scholar
G’Sell, C. and Gopez, A.J. (1985) J. Mater. Sci., 20, 3462–3478.
Article Google Scholar
G’Sell, C. and Jonas, JJ. (1979) J. Mater. Sci., 16, 1956–1974.
Article Google Scholar
G’Sell, C. and Jonas, J.J. (1981) J. Mater. Sci., 14, 583–591.
Google Scholar
G’Sell, C, Boni, S. and Shrivastava, S. (1983) J. Mater. Sci., 18, 903–918.
Article Google Scholar
G’Sell, C, Hiver, J.M, Dahoun, A. and Souahi, A. (1992) J. Mater. Sci., 27, 5031–5039.
Article Google Scholar
G’Sell, C, El Bari, H., Perez, J. et al. (1989) Mater. Sci. Eng., AHO, 223–229.
Google Scholar
Hasan, O.A. and Boyce, M.C. (1993) Polymer, 34, 5085–5092.
Article CAS Google Scholar
Hasan, O.A. and Boyce, M.C. (1995) Polym. Sci. Eng., 35, 331–344.
Article CAS Google Scholar
Hasan, O.A., Boyce, M.C, Li, X.S. and Berko, S. (1993) J. Polym. Sci. B: Polym. Phys., 31, 185–197.
Article CAS Google Scholar
Haussy, J., Cavrot, J.P., Escaig, B. and Lefebvre, J.M. (1980) J. Polym. Sci. B: Polym. Phys. Edn., 18, 311–325.
Article CAS Google Scholar
Haward, R.N. (1973) in Physics of Glassy Polymers (ed. R.N. Haward), John Wiley, New York, Ch. 1.
Chapter Google Scholar
Haward, R.N. (1974) in Molecular Behaviour and the Development of Polymeric Materials (eds A. Ledwith and A.M. North), Chapman & Hall, London, London, p. 444.
Google Scholar
Haward, R.N. (1994) Thermochim. Acta, 247, 87–109.
Article CAS Google Scholar
Hutnik, M., Argon, A.S. and Suter, U.W. (1993) Macromolecules, 26, 1097–1108.
Article CAS Google Scholar
Imai, Y. and Brown, N. (1976) J. Polym. Sci., Polym. Phys. Edn., 14, 723–739.
Article CAS Google Scholar
Kelly, A. and Macmillen, N.H. (1986) Strong Solids, 3rd edn, Oxford University Press, New York, 423 pp.
Google Scholar
Knauss, W.A. and Emri, I. (1987) Polym. Eng. Sci., 27, 86–100.
Article CAS Google Scholar
Kozey, V.V. and Kumar, S. (1994) J. Mater. Res., 9, 2717–2726.
Article CAS Google Scholar
Krausz, A.S. and Eyring, H. (1975) Deformation Kinetics, Wiley-Interscience, New York, 398 pp.
Google Scholar
Lefebvre, J.M., Escaig, B., Coulon, G. and Picot, C. (1985) Polymer, 26, 1807–1813.
Article CAS Google Scholar
Lohse, F, Schmid, R., Batzer, H. and Fisch, W. (1969) Br. Polym. J., 1, 110–114.
Article CAS Google Scholar
Magonov, S.N., Vainilovitch, I.S. and Sheiko, S.S. (1991) Polym. Bull., 25, 491–498, 499-506.
Article CAS Google Scholar
Matsuoka, S. (1986) in Failure of Plastics (eds W. Brostow and R.D. Corneliussen), Hanser, New York, Ch. 3.
Google Scholar
Matsuoka, S. (1992) Relaxation Phenomena in Polymers, Hanser, New York, Ch. 3.
Google Scholar
Matsushige, K, Radcliffe, S.V. and Baer, E. (1976) J. Polym. Sci., Polym. Phys. Edn, 14, 703–721.
Article CAS Google Scholar
Mott, P.H., Argon, A.S. and Suter, U.W. (1993) Phil. Mag. A, 67, 931–978.
Article CAS Google Scholar
Nanzai, Y. (1993) Prog. Polym. Sci., 18, 437–479.
Article CAS Google Scholar
Oleinik, E.F. (1986) Adv. Polym. Sci., 80, 49–99.
Article CAS Google Scholar
Oleynik, E. (1989) Prog. Coll. Polym. Sci., 80, 140–150.
Article Google Scholar
Oleynik, E.F. (1991) in High Performance Polymers (eds E. Baer and A. Moet), Hanser, New York, pp. 79–102.
Google Scholar
Pae, K.D. and Bhateja, S.K. (1975) J. Macromol. Sci., Rev. Macromol. Chem., C13, 1–75.
Google Scholar
Powers, J.M. and Caddell, R.M. (1972) Polym. Eng. Sci., 12, 432–436.
Article CAS Google Scholar
Raghava, R., Caddell, R.M. and Yeh, G.S.Y. (1973) J. Mater. Sci., 8, 225–232.
Article CAS Google Scholar
Rendell, R.W., Ngai, K.L., Fong, G.R. and Bankert, R.J. (1987) Polym. Eng. Sci., 27, 2–15.
Article CAS Google Scholar
Robertson, R.E. (1966) J. Chem. Phys., 44, 3950–3956.
Article Google Scholar
Ruan, M.Y., Moaddel, H., Jamieson, A.M. et al. (1992) Macromolecules, 25, 2407–2411.
Article CAS Google Scholar
Spitzig, W.A. and Richmond, O. (1979) Polym. Eng. Sci., 19, 1129–1138.
Article CAS Google Scholar
Stokes, V.K. and Bushko, W.C. (1995) Polym. Eng. Sci., 35, 291–303.
Article CAS Google Scholar
Struik, L.C.E. (1991) J. Non-Cryst. Solids, 131-133, 395–407.
Article CAS Google Scholar
Tant, J.M. and Wilkes, G.L. (1981) Polym. Eng. Sci., 21, 874–895.
Article CAS Google Scholar
Theodorou, D.N. and Suter, U.W. (1986) Macromolecules, 19, 139–154.
Article CAS Google Scholar
Theodorou, M., Jasse, B. and Monnerie, L. (1985) J. Polym. Sci., Polym. Phys. Edn, 23, 445–450.
Article CAS Google Scholar
Walker, N. (1980) Polymer, 21, 857–859.
Article CAS Google Scholar
Ward, I.M. and Hadley, D.W. (1993) An Introduction to the Mechanical Properties of Solid Polymers, John Wiley, New York, Ch. 11.
Google Scholar
Weertman, J. and Weertman, J.R. (1992) Introduction to Dislocations, 2nd edn, Oxford University Press, New York, 213 pp.
Google Scholar
Wignall, G.D. (1987) in Encyclopedia of Polymer Science and Engineering, Vol. 10 (eds. H.F. Mark et al.), John Wiley, New York, pp. 112–184.
Google Scholar
Williams, M.L., Landel, R.F and Ferry, J.D. (1955) J. Am. Chem. Soc., 11, 3701–3707.
Article Google Scholar
Wu, J.B.C. and Li, J.C.M. (1976) J. Mater. Sci., 11, 434–444.
Article CAS Google Scholar
Wu, W. and Turner, P.L. (1975) J. Polym. Sci., Polym. Phys. Edn, 13, 19–34.
Article CAS Google Scholar
Xie, L., Gidley, D.W., Hristov, H.A. and Yee, A.F. (1995) J. Polym. Sci. B: Polym. Phys., 33, 77–84.
Article CAS Google Scholar
Yamini, S. and Young, R.J. (1980) J. Mater. Sci., 15, 1814–1822.
Article CAS Google Scholar

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B. Crist
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Editors and Affiliations

Department of Chemistry, UMIST, UK
R. N. Haward (Visiting Professor) (Visiting Professor)
Manchester Materials Science Centre, University of Manchester/UMIST, UK
R. J. Young (Royal Society Wolfson Research Professor of Materials Science) (Royal Society Wolfson Research Professor of Materials Science)

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Crist, B. (1997). Yield processes in glassy polymers. In: Haward, R.N., Young, R.J. (eds) The Physics of Glassy Polymers. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5850-3_4

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DOI: https://doi.org/10.1007/978-94-011-5850-3_4
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