Abstract
Efforts to minimize pollution and alleviate chronic water shortages in many parts of the world have resulted in the increased use of treated sewage effluent in irrigated agriculture. One of the problems associated with this practice is the potential for enhanced transport of agrochemicals such as pesticides as a result of complexation with relatively mobile effluent-borne macromolecules and colloids. Interaction of macromolecules and colloids with soil organic carbon may also change the nature of soil sorption sites and reduce the surface area available for pesticide sorption. Enhanced transport of nearly water insoluble pesticides at dissolved organic carbon (DOC) concentrations as low as 5 mg L-1 has been demonstrated in laboratory studies (Dunnivant et al., 1992a). The use of effluents in irrigated agriculture with relatively higher levels of organic carbon (15–150 mg DOC L-1) therefore may result in deep soil and groundwater contamination by pesticides due to enhanced downward transport.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Ballard T M 1971 Role of humic carrier substances in DDT movement through forest soils. Soil Sci. Soc. Am. Proc. 35, 145–147.
Chin Y P, Weber W J and Chiou C T 1991 A thermodynamic partition model for binding of nonpolar organic compounds by organic colloids and implications for their sorption to soils and sediments. In Organic Substances and Sediments in Water, Volume I. Humics and Soils. Ed. R A Baker. pp 251–273. Lewis Publishers, MI, USA.
Chiou C T 1989 Theoretical considerations of the partition uptake of nonionic organic compounds by soil organic matter. In Reaction and Movement of Organic Chemicals in Soils, SSSA Special Publication Number 22. Ed. B L Sawhney and K Brown, pp 1–30. Soil Science Soc. of America, Madison, WI, USA.
Conroy L E, Maier W J and Young-Tzung S 1981 Determination of carbohydrates and primary amines in river water. In Chemistry in Water Reuse. Ed. W J Cooper, pp 65–84. Ann Arbor Science, MI, USA.
Dunnivant F M, Jardine P M, Taylor D J and McCarthy J F 1992a Cotransport of cadmium and hexachlorobiphenyl by dissolved organic carbon through columns containing aquifer material. Environ. Sci. Technol. 26, 360–367.
Dunnivant F M, Jardine P M, Taylor D J and McCarthy J F 1992b Transport of naturally occurring dissolved organic carbon in laboratory columns containing aquifer material. Soil Sci. Soc. Am. Proc. 56, 437–444.
Graber E R, Gerstl Z, Fischer E and Mingelgrin U 1995 Enhanced transport of atrazine under irrigation with effluent. Soil Sci. Soc. Am. J. 59, 1513–1519.
Jury W A, Focht D D and Farmer W J 1987 Evaluation of pesticide groundwater pollution potential from standard indices of soil-chemical adsorption and degradation. J. Environ. Qual. 16, 422–428.
Karickhoff S W 1981 Semi-empirical estimation of sorption of hydrophobic pollutants on natural sediments and soils. Chemosphere 10, 833–846.
Magee B R, Lion L W and Lemley A T 1991 Transport of dissolved organic molecules and their effect on the transport of phenanthrene in porous media. Environ. Sci. Technol. 25, 323–331.
Manka J, Rebhun M, Mandelbaum A and Bortinger A 1974 Characterization of organics in secondary effluents. Environ. Sci. Technol. 8, 1017–1020.
Muszkat L, Lahav L, Ronen D and Magaritz M 1993 Penetration of pesticides and industrial organics deep into soil and into groundwater. Arch. Insect. Biochem. Physiol. 22, 487–499.
Ogner G and Schnitzer M 1970 Humic substances: Fulvic acid-dialkyl phthalate complexes and their role in pollution. Science 170, 317–318.
Rebhun M and Manka J 1971 Classification of organics in secondary effluents. Environ. Sci. Technol. 5, 606–609.
Stevenson F J 1985 Geochemistry of soil humic substances. In Humic Substances in Soils, Sediments, and Water. Ed. G R Aiken, D M McKnight, and R L Wershaw. pp 13–52. Wiley-Interscience, New York, USA.
Vinten A J A, Yaron B and Nye P H 1983 Vertical transport of pesticides into soil when adsorbed on suspended particles. J. Agric. Food Chem. 31, 662–664.
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1997 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Graber, E.R. (1997). Effect of irrigation with secondary sewage effluent on the transport of soil-borne pesticides. In: Rosen, D., Tel-Or, E., Hadar, Y., Chen, Y. (eds) Modern Agriculture and the Environment. Developments in Plant and Soil Sciences, vol 71. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5418-5_25
Download citation
DOI: https://doi.org/10.1007/978-94-011-5418-5_25
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6279-4
Online ISBN: 978-94-011-5418-5
eBook Packages: Springer Book Archive