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Thermal Methods of Analysis pp 63–122Cite as

Differential thermal analysis and differential scanning calorimetry

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Abstract

When an organic chemical is prepared, it is checked against known materials for purity and stability. One of the easiest ways of doing this is to determine its melting point! This cannot be done by TG, since it involves no mass change! This also applies to solid-solid phase transitions and to some solid-state reactions. We therefore need a technique that identifies these transitions. Such a technique will give us a simple way of identifying and assessing the quality of materials that may be applied across a large range of substances, from polymers to metals.

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References

  1. A.L. Lavoisier, P.S. de Laplace, Mem. R. Acad. Sci., Paris, 1784, 355.

    Google Scholar 

  2. J.B. Fourier, Theorie Analytique de la Chaleur, Paris, 1822.

    Google Scholar 

  3. J.P. Joule, Collected Works, The Physical Society, London, 1884, p. 474.

    Google Scholar 

  4. J.P. McCullogh, D.W. Scott, Experimental Thermodynamics, Vol. 1, Butterworth, London, 1968.

    Google Scholar 

  5. H. Le Chatelier, C.R. Acad. Sci., Paris, 1887, 104, 1443.

    Google Scholar 

  6. W.C. Roberts-Austen, Proc. R. Instn. Mech. Eng. London, 1899, p. 35.

    Google Scholar 

  7. E.S. Watson, M.J. O’Neill, J. Justin, N. Brenner, Anal. Chem., 1964, 36, 1233.

    Article  CAS  Google Scholar 

  8. J.O. Hill, For Better Thermal Analysis and Calorimetry (3rd edn), ICTAC, 1991.

    Google Scholar 

  9. R.C. Mackenzie, Anal. Proc, 1980, 217.

    Google Scholar 

  10. R.L. Blaine, A Generic Definition of Differential Scanning Calorimetry, Dupont Instruments, 1978.

    Google Scholar 

  11. F.E. Freeberg, T.G. Alleman, Anal. Chem., 1966, 38, 1806.

    Article  CAS  Google Scholar 

  12. I. Mita, I.Imai, H.Kambe, Thermochim. Acta, 1971, 2, 337.

    Article  CAS  Google Scholar 

  13. H.G. Wiedemann, G. Bayer, Thermochim. Acta, 1985, 83, 153.

    Article  CAS  Google Scholar 

  14. P.J. Haines, G.A. Skinner, Thermochim. Acta, 1982, 59, 343.

    Article  CAS  Google Scholar 

  15. H.G. Wiedemann, A. Boller, Int. Lab., 1992, 22, 14.

    Google Scholar 

  16. Dupont Application Brief, No. 900B32, 1970.

    Google Scholar 

  17. P.J. Haines, Educ. in Chem., 1969, 6, 171.

    CAS  Google Scholar 

  18. R.N. Rogers, E.D. Morris, Anal. Chem., 1966, 38, 410.

    Article  CAS  Google Scholar 

  19. M.E. Brown, Introduction To Thermal Analysis, Springer Science+Business Media Dordrecht, London, 1988.

    Book  Google Scholar 

  20. C.J. Keattch, D. Dollimore, Introduction to Thermogravimetry (2nd edn), Heyden, London, 1975.

    Google Scholar 

  21. F.W. Wilburn, J.R. Hesford, J.R. Flower, Anal. Chem., 1968, 40, 777.

    Article  CAS  Google Scholar 

  22. R. Melling, F.W. Wilburn, R.M. Mcintosh, Anal. Chem., 1969, 41, 1275.

    Article  CAS  Google Scholar 

  23. F.W. Wilburn, D. Dollimore, J.S. Crighton, Thermochim. Acta, 1991, 181, 173.

    Article  CAS  Google Scholar 

  24. F.W. Wilburn, D. Dollimore, J.S. Crighton, Thermochim. Acta, 1991, 181, 191.

    Article  CAS  Google Scholar 

  25. H.J. Borchardt, F. Daniels, J. Amer. Chem. Soc., 1957, 79, 41.

    Article  CAS  Google Scholar 

  26. A.W. Coats, J.P. Redfern, Nature, 1964, 201, 68.

    Article  CAS  Google Scholar 

  27. M.J. Vold, Anal. Chem., 1949, 21, 683.

    Article  CAS  Google Scholar 

  28. F.W. Wilburn, R.M. Mcintosh, A. Turnock, Trans. Brit. Ceram. Soc., 1974, 73, 117.

    Google Scholar 

  29. S.L. Boersma, J. Amer. Ceram. Soc., 1955, 38, 281.

    Article  CAS  Google Scholar 

  30. E.L. Charsley et al., J. Thermal Anal., 1993, 40, 1415.

    Article  Google Scholar 

  31. R.W. Carling, Thermochim. Acta, 1983, 60, 265.

    Article  CAS  Google Scholar 

  32. A.P. Gray, Perkin-Elmer Thermal Analysis Study, #1, Perkin-Elmer Ltd, 1972.

    Google Scholar 

  33. J. Pöyhönen, T. Sivonen, M. Hilpela, Proc 1st ICTA, Aberdeen, Macmillan, London, 1965, p. 148.

    Google Scholar 

  34. Z.G. Szabo, I.K. Thege, E.E. Zapp, Proc. 1st ESTA, Salford, Heyden, London, 1976, p. 272.

    Google Scholar 

  35. W. Engel, Explosivstoffe, 1973, 21, 9.

    CAS  Google Scholar 

  36. D. Chapman, Chem. Rev., 1966, 62, 433.

    Article  Google Scholar 

  37. J.S. Aronhime, Thermochim. Acta, 1988, 134, 1.

    Article  CAS  Google Scholar 

  38. N.V. Lovegren, M.S. Gray, R.O. Feuge, J. Amer. Oil Chem. Soc., 1976, 53, 83.

    Article  CAS  Google Scholar 

  39. E. Kaiserberger, Thermochim. Acta, 1989, 151, 83.

    Article  Google Scholar 

  40. J.L. Ford, P. Timmins, Pharmaceutical Thermal Analysis, Ellis Horwood, Chichester, 1989.

    Google Scholar 

  41. M.J. Hardy, Proc 7th ICTA, Canada, Wiley, Chichester, 1982, p. 876.

    Google Scholar 

  42. B. Sustar, N. Bukovec, P. Bukovec, J. Thermal Anal., 1993, 40, 475.

    Article  CAS  Google Scholar 

  43. G.S. Attard, G. Williams, Chem. in Brit., 1986, 22, 919.

    CAS  Google Scholar 

  44. G.W. Gray, Molecular Structure and Properties of Liquid Crystals, Academic Press, London, 1962.

    Google Scholar 

  45. H.G. Wiedemann, Mettler Application, No. 805, 1987.

    Google Scholar 

  46. F.D. Ferguson, T.K. Jones, The Phase Rule, Butterworth, London, 1966, p.

    Google Scholar 

  47. P. Atkins, Physical Chemistry, OUP, Oxford, 1978, Ch. 10.

    Google Scholar 

  48. E.A. Franceschi, G.A. Costa, J. Thermal Anal., 1988, 34, 451.

    Article  CAS  Google Scholar 

  49. P.-Y. Chevalier, Thermochim. Acta., 1989, 155, 211.

    Article  CAS  Google Scholar 

  50. A.V. Galanti, R.S. Porter, J. Phys. Chem., 1972, 76, 3089.

    Article  CAS  Google Scholar 

  51. H. Jacobson, G. Reier, J. Pharm. Sci., 1969, 58, 631.

    Article  CAS  Google Scholar 

  52. D.J.W. Grant, I.K.A. Abougela, G.G. Liversidge, J.M. Padfield, Anal. Proc., 1982, 545 and 549. @@

    Google Scholar 

  53. F. Giordano, G.P. Bettinetti, A. La Manna, A. Marini, V. Berbenni, J. Thermal Anal., 1988, 34, 531.

    Article  CAS  Google Scholar 

  54. F. Rodriguez, Principles of Polymer Systems, McGraw-Hill, Singapore, 1983.

    Google Scholar 

  55. M. Dole, J. Polym. Sci. (C), 1967, 18, 57.

    Google Scholar 

  56. E.M. Barrali et al, J. Appl. Polym. Sci., 1965, 9, 3061.

    Article  Google Scholar 

  57. M.E. Brown, Introduction to Thermal Analysis Springer Science+Business Media Dordrecht, London, 1988, p. 46.

    Book  Google Scholar 

  58. M.J. O’Neill, Anal. Chem., 1966, 38, 1331.

    Article  Google Scholar 

  59. B. Wunderlich, M. Dole, J. Polym. Scl., 1957, 24, 201.

    Article  CAS  Google Scholar 

  60. B. Wunderlich, J. Phys. Chem., 1965, 69, 2078.

    Article  CAS  Google Scholar 

  61. S.Z.D. Cheng, B. Wunderlich, Thermochim. Acta, 1988, 134, 161.

    Article  CAS  Google Scholar 

  62. A. Everett, Materials, Mitchells, London, 1986.

    Google Scholar 

  63. Mettler DSC 20 System Reference, Mettler-Toledo.

    Google Scholar 

  64. A.R. Ubbelohde, Quart. Rev., 1957, XI, 246.

    Article  Google Scholar 

  65. B. Wunderlich, M. Bodily, J. Polym. Sci. (C), 1963, 6, 132.

    Google Scholar 

  66. W.P. Brennan, Perkin-Elmer Thermal Analysis Application Study, 8 & 11, W.P. Brennan, Perkin-Elmer Ltd, 1973.

    Google Scholar 

  67. M.E. Brown, J. Chem. Ed., 1979, 56, 310.

    Article  CAS  Google Scholar 

  68. P.W. Atkins, Physical Chemistry, OUP, Oxford, 1978, p. 219.

    Google Scholar 

  69. G. Widmann, O. Scherrer, J. Thermal Anal., 1991, 37, 1957.

    Article  CAS  Google Scholar 

  70. S.T. Glasstone, Textbook of Physical Chemistry Macmillan, London, 1951, p. 650.

    Google Scholar 

  71. C. Plato, A.R. Glasgow, Anal. Chem., 1969, 41, 330.

    Article  CAS  Google Scholar 

  72. P.D. Garn, B. Kawalec, J.J. Houser, T.F. Habash, Proc. 7th ICTA, Wiley, Chichester, 1982, p. 899.

    Google Scholar 

  73. K.E.J. Barrett, J. Appl. Polym. Sci., 1967, 11, 1617.

    Article  CAS  Google Scholar 

  74. J.R. Knox, Analytical Calorimetry (ed. R.S. Porter, J.F. Johnson), Plenum, New York, 1968, p. 45.

    Chapter  Google Scholar 

  75. A. Wlochowicz, M. Eder, Thermochim. Acta, 1988, 134, 133.

    Article  CAS  Google Scholar 

  76. ASTM E698-79: Arrhenius Kinetic Constants for Thermally Unstable Materials, ASTM, Philadelphia, 1979.

    Google Scholar 

  77. T. Ozawa, J. Thermal Anal., 1970, 2, 301; 1975, 7, 601.

    Article  CAS  Google Scholar 

  78. M.I. Pope, M.D. Judd, Differential Thermal Analysis, Heyden, London, 1977.

    Google Scholar 

  79. W. Wendlandt, J.P. Smith, J. Inorg. Nucl. Chem., 1963, 25, 843, 1267.

    Article  CAS  Google Scholar 

  80. J.E. House, K. Farran, J. Inorg. Nucl. Chem., 1972, 34, 1466.

    Article  CAS  Google Scholar 

  81. G. Beech, C.T. Mortimer, E.G. Tyler, J. Chem. Soc, 1967, 925, 929.

    Google Scholar 

  82. R.C. Mackenzie, Differential Thermal Analysis, 2 Vols, Academic Press, London, 1970 and 1972.

    Google Scholar 

  83. Recommendations for Testing High Alumina Cement Concrete Samples by Thermo-analytical Techniques, Thermal Methods Group, RSC, London, 1975.

    Google Scholar 

  84. H.G. Midgley, Trans. Brit. Ceram. Soc., 1967, 66, 161

    CAS  Google Scholar 

  85. J.W. Dodd, K.H. Tonge, Thermal Methods, ACOL, Wiley, 1987, Ch. 6.

    Google Scholar 

  86. R.C. Mackenzie (ed.), The Differential Thermal Analysis of Clays, Mineralogical Soc., London, 1957.

    Google Scholar 

  87. D.N. Todor, Thermal Analysis of Minerals, Abacus Press, Tunbridge Wells, 1976.

    Google Scholar 

  88. C.M. Earnest, Thermal Analysis of Clays, Minerals and Coal, Perkin-Elmer, Norwalk, 1984.

    Google Scholar 

  89. J.G. Dunn, Stanton Redcroft Information Sheet, No. 130, 1978.

    Google Scholar 

  90. J.W. Rue, W.R. Ott, J. Thermal Anal., 1974, 6, 513.

    Article  CAS  Google Scholar 

  91. J.B. Farmer, A.J.D. Gilbert, P.J. Haines, Proc. 7th ICTA, Wiley-Heyden, Chichester, 1982, 650.

    Google Scholar 

  92. A.G. Sadler, W.D. Westwood, D.C. Lewis, J. Can. Ceram. Soc, 1971, 21, 127.

    Google Scholar 

  93. S.T. Henderson, P.W. Ranby, J. Electrochem. Soc., 1951, 98, 479.

    Article  CAS  Google Scholar 

  94. M.E. Brown, R.A. Rugunanan, Thermochim. Acta, 1988, 134, 413.

    Article  CAS  Google Scholar 

  95. P.G. Laye, E.L. Charsley, Thermochim. Acta, 1987, 120, 325.

    Article  CAS  Google Scholar 

  96. T. Ozawa, Thermochim. Acta, 1988, 133, 11.

    Article  CAS  Google Scholar 

  97. H.-J. Chen, J.H. Sharp, J. Thermal Anal., 1993, 40, 379.

    Article  CAS  Google Scholar 

  98. ASTM D 3350-84 and ASTM D 3895-80, ASTM, Philadelphia.

    Google Scholar 

  99. J.B. Howard, Polym. Eng. Sci., 1973, 13, 429.

    Article  CAS  Google Scholar 

  100. J.M. Barton, Advances in Polymer Science, 1985, 72, 111.

    Article  CAS  Google Scholar 

  101. R.B. Cassel, Perkin-Elmer Thermal Analysis Application Study, 5, Perkin-Elmer, 1973.

    Google Scholar 

  102. Setaram File 10: Micro-DSC. Setaram.

    Google Scholar 

  103. C.F. Cullis, M.M. Hirschler, The Combustion of Organic Polymers, Clarendon Press, Oxford, 1981.

    Google Scholar 

  104. G.P. Morie, T.A. Powers, C.A. Glover, Thermochim. Acta. 1972, 3, 259.

    Article  CAS  Google Scholar 

  105. R.J. Seyler, Thermochim. Acta, 1976, 17, 129.

    Article  CAS  Google Scholar 

  106. B. Cassel, M.P. DiVito, Int. Lab., 1994, 24, 19.

    Article  Google Scholar 

  107. H.G. Wiedemann, A. Boller, Int. Lab., 1992, 22, 14.

    Google Scholar 

  108. L.C. Thomas, Int. Lab., 1987, 17, 30.

    Google Scholar 

  109. DuPont Thermal Analysis Application Briefs, Nos 900B31 and 900B32, 1970.

    Google Scholar 

  110. F.R. Wright, G.W. Hicks, Polym. Eng. Sci., 1978, 18, 378.

    Article  Google Scholar 

  111. G.R. Tryson, A.R. Schultz, J. Polym. Sci., Polym. Phys. Ed., 1979, 17, 2059.

    Article  CAS  Google Scholar 

  112. T.R. Manley, G. Scurr, Proc. 2nd ESTA, Aberdeen, Heyden, London, 1981.

    Google Scholar 

  113. K.A. Hodd, N. Menon, Proc. 2nd ESTA, Aberdeen, Heyden, London, 1981.

    Google Scholar 

  114. P.S. Gill, S.R. Sauerbrunn, M. Reading, J. Thermal Anal., 1993, 40, 931.

    Article  CAS  Google Scholar 

  115. M. Reading, D. Elliott, V.L. Hill, J. Thermal Anal., 1993, 40, 949.

    Article  CAS  Google Scholar 

  116. A.F. Barnes, M.J. Hardy, T.J. Lever, J. Thermal Anal., 1993, 40, 499.

    Article  CAS  Google Scholar 

  117. TA Instruments Ltd Application Brief, MDSC-1, 1993.

    Google Scholar 

Bibliography

  • R.C. Mackenzie, Differential Thermal Analysis (2 Vols), Academic Press, London, 1970 and 1972.

    Google Scholar 

  • W.J. Smothers, J. Chiang, Differential Thermal Analysis, Chemical Publishing Co, New York, 1958.

    Google Scholar 

  • M.I. Pope, M.D. Judd, Differential Thermal Analysis, Heyden, London, 1977.

    Google Scholar 

  • J.L. McNaughton, C.T. Mortimer, Differential Scanning Calorimetry, Perkin-Elmer, 1975, Butterworth (Vol. 10 of 1RS Physical Chemistry Series 2).

    Google Scholar 

  • E. Kaisersberger, H. Mönier, DSC on Polymeric Materials, Netzsch Annual for Science and Industry, Vol. 1, 1991.

    Google Scholar 

  • E. Kaisersberger, S. Knappe, H. Möhler, TA for Polymer Engineering: DSC TG DMA, Netzsch Annual, Vol. 2, 1993, Netzsch, Selb.

    Google Scholar 

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  1. P. J. Haines
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Haines, P.J., Wilburn, F.W. (1995). Differential thermal analysis and differential scanning calorimetry. In: Thermal Methods of Analysis. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1324-3_3

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  • DOI: https://doi.org/10.1007/978-94-011-1324-3_3

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