Abstract
Let us consider a polymer which is in its molten state. What may happen when it cools down? The two possibilities are shown in Fig.5.1. The polymer may either crystallize (route a) or cool down to its glassy, amorphous state (route b). The temperature at which the slope in the specific volume—temperature graph (route b) changes is referred to as the glass transition temperature, T g . Rigid-rod polymers, i.e. polymers with very inflexible groups in the backbone chain or in side chains, may form liquid-crystalline states, an issue dealt with in Chapters 6.
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References
Bair, H. E. (1970) Polym. Eng. Sci.10, 247.
Beaman, R. G. (1953) J. Polym. Sci.9, 472.
Boyd, R. H. and Breitling, S. M. (1974) Macromolecules 7, 855.
Boyer, R. F. (1954) J. Appl. Phys.25, 825.
Boyer, R. F. (1963) Rubber Chem. And Technol.36, 1303.
Davies, R. O. and Jones, G. O. (1953) Advances in Physics, Philosophical Magazine Supplement 2, 370.
DiMarzio, E. A. (1981) Equilibrium theory of glasses, in Structure and Mobility in Molecular and Atomic Glasses (J. M. O’Reilly and M. Goldstein, eds), Annals of the New York Academy of Sciences 371). New York Academy of Sciences, New York.
Doolittle, A. K. (195I) J. Appl. Phys.22, 1471.
Eisenberger, A. (1984). The glassy state, in Physical Properties of Polymers, Am. Chem. Soc., Washington, DC.
Fox, T. G. (1956) Bull. Am. Phys. Soc.1, 123.
Gibbs, J. H. and DiMarzio, E. A. (1958) J. Chem. Phys.28, 373.
Goldbach, G. and Rehage, G. (1967) Rheol. Acta 6, 30.
Heijboer, J. (1965) Physics of Noncrystalline Solids. North-Holland, Amsterdam.
Kovacs. A. J. (1963) Fortschr. Hochpolym. Forsch.3, 394.
Kovacs, A. J., Aklonis, J. J., Hutchinson, J. M. and Ramos, A. R. (1979) J. Polym. Sci., Polym. Phys. Ed.17, 1097.
Lethersich, W. (1950) Brit. J. Appl. Phys.1, 294.
Lovell, R., Mitchell, G. R. and Windle, A. H. (1979) Faraday Discuss. Chem. Soc.68, 46.
McCammon, R. D., Saba, R. G. and Work, R. N. (1969) J. Polym. Sci., Part A2 7, 1271.
Pechold, W. (1968) Kolloid Z. Z. Polym.228, 1.
Rietsch, F., Daveloose, D. and Froelich, D. (1976) Polymer 17, 859.
Rogers, S. S. and Mandelkem, L. (1957) J. Phys. Chem.61, 985.
Rogers, S. S. and Mandelkem, L. (1957) J. Phys. Chem.61, 985.
Schatzki, T. F. (1966) J. Polym. Sci., Polym. Symp.14, 139.
Schmieder, K. and Wolf, D. (1953) Kolloid Z.134, 149.
Schmieder, K. and Wolf, D. (1953) Kolloid Z.134, 149.
Stein, R. S. and Hong, S. D. (1976) J. Macromol. Sci., Part B 12, 125.
Struik, L. C. E. (1978) Physical Ageing of Amorphous Polymers and Other Materials. Elsevier, Amsterdam.
Tool, A. Q. (1946) J. Am. Chem. Soc.29, 240.
Wolf, D. (1951) Kunststoffe 41, 89.
Yano, O. and Wada, Y. (1971)]. Polym. Sci. Part A29, 669.
Suggested Further Reading
Eisenberger, A. (1993) The glassy state and the glass transition, in Physical Properties of Polymers, 2nd edn. American Chemical Society, Washington, DC.
Ferry, J. D. (1980) Viscoelastic Properties of Polymers. Wiley, New York.
Keinath, S. E., Miller, R. L. and Rieke, J. K. (eds) (1987) Order in the Amorphous State of Polymers. Plenum, New York and London.
McCrum, N. G., Read, B. E. and Williams, G. (1967) Anelastic and Dielectric Effects in Polymeric Solids. Wiley, New York.
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Gedde, U.W. (1999). The Glassy Amorphous State. In: Polymer Physics. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0543-9_5
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DOI: https://doi.org/10.1007/978-94-011-0543-9_5
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