Abstract
The field of photochemical conversion of solar energy has become an exciting and rapidly growing area of research over the last few years. Light-driven redox reactions coupled with redox catalysts are being investigated as a possible route for the generation of fuels by visible light [5.1–4]. With the limitations imposed by the near diffusion-controlled rates for the back reactions that follow endergonic (uphill) photoredox reactions with organic and inorganic dye-based systems, attention is being directed towards semiconductor particulate and colloidal systems as light harvesting units. Heterogeneous photocatalysis with semiconductor particulate systems offer several advantages. Colloidal semiconductors combine a number of desirable properties such as high extinction coefficients, fast carrier diffusion to the interface and suitable positioning of valence and conduction bands to achieve high efficiencies in light-energy conversion processes. The transparent nature of these sols allows ready detection of short-lived intermediates by fast kinetic spectroscopy. Particularly attractive is the added possibility of modifying the surface of the semiconductor particles by chemisorption, chemical derivatization and/or catalyst deposition assisting the light-induced charge separation and subsequent fuel-generating dark reaction.
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Kalyanasundaram, K., Grätzel, M. (1984). Heterogeneous Photocatalysis with Semiconductor Particulate Systems. In: Vanselow, R., Howe, R. (eds) Chemistry and Physics of Solid Surfaces V. Springer Series in Chemical Physics, vol 35. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82253-7_5
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