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The Intramolecular Diels-Alder Reaction: Variations and Scope

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Intramolecular Diels-Alder and Alder Ene Reactions

Part of the book series: Reactivity and Structure Concepts in Organic Chemistry ((REACTIVITY,volume 18))

Abstract

The Diels-Alder reaction has long been a useful tool in organic synthesis. Although the concept of covalently linking the diene and the dienophile was originated by Alder (1), it has only been in the last ten years that the intramolecular Diels-Alder reaction has been widely used. Partly this has been because efficient routes to the requisite trienes have only recently been available, and partly it has been because there has not been enough data in the literature to allow one to predict with confidence the stereochemical outcome of a prospective cyclization.

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  1. Department of Chemistry, University of Delaware, Newark, Delaware, 19711, USA

    Douglass F. Taber

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Taber, D.F. (1984). The Intramolecular Diels-Alder Reaction: Variations and Scope. In: Intramolecular Diels-Alder and Alder Ene Reactions. Reactivity and Structure Concepts in Organic Chemistry, vol 18. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-69233-8_1

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  • DOI: https://doi.org/10.1007/978-3-642-69233-8_1

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