Abstract
The freezing of water and the melting of ice, phenomena that are extraordinarily familiar from the world around, are only poorly understood at a molecular level. Like all liquids, water can be undercooled without freezing; like most solids, ice cannot be superheated to a significant extent. The dynamics of these phase transitions, and what they tell about the molecular level structure of interfaces and critical nuclei, is revealed by experiment, computer simulation, and theory. In some regards, water resembles simpler liquids in the kinetics of its changes of state, but in others it is quite different. This chapter explores the microscopic dynamics of freezing and melting, with particular emphasis on the water-ice system.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
D. W. Oxtoby, J. Phys. Cond Matter 4, 7627 (1992).
J. L. Katz and F. Spaepen, Phil Mag. B 37, 137 (1978).
D. Turnbull and J. C. Fisher, J. Chem. Phys. 17, 71 (1949).
D. W. Oxtoby and P. R. Harrowell, J. Chem. Phys. 96, 3834 (1992).
G. R. Wood and A. G. Walton, J. Appl. Phys. 41, 3027 (1970).
G. T. Butorin and V. P. Skripov, Sov. Phys.-Crystallogr. 17, 322 (1972).
J. Huang and L. S. Bartell, J. Phys. Chem. 99, 3924 (1995).
S. C. Hardy, Phil. Mag. 35, 471 (1977).
D. R. MacFarlane, R. K. Kadiyala, and C. A. Angell, J. Chem. Phys. 79, 3921 (1983).
P. R. Harrowell and D. W. Oxtoby, J. Chem. Phys. 80, 1639 (1984).
Y. C. Shen and D. W. Oxtoby, J. Chem. Phys. 105, 6517 (1996).
L. A. Baez and P. Clancy, J. Chem. Phys. 102, 8138 (1995).
P. R. ten Wolde, M. J. Ruiz-Montero, and D. Frenkel, J. Chem. Phys. 104, 9932(1996).
K. Ding, D. Chandler, S. J. Smithline, and A. D. J. Haymet, Phys. Rev. Lett. 59, 1698(1987)
O. A. Karim, P. A. Kay, and A. D. J. Haymet, J. Chem. Phys. 92, 4634 (1990).
I. M. Svishchev and P. G. Kusalik, Phys. Rev. Lett. 73, 975 (1994).
Y. C. Shen and D. W. Oxtoby, Phys. Rev. Lett. 77, 3585 (1996).
R. J. Speedy and C. A. Angell, J. Chem. Phys. 65, 851 (1976).
H. R. Pruppacher, J. Atmos. Sci. 52, 1924 (1995).
P. H. Poole, F. Sciortino, U. Essmann, and H. E. Stanley, Nature 360, 324 (1992).
H Tanaka, Nature 380, 328 (1996).
O. Mishima, Nature 384, 546 (1996).
D. W. Oxtoby, in Inhomogeneous Liquids, ed. by Douglas Henderson (Marcel Dekker, New York, 1992), Chapter 10
W. Barlow and A. D. J. Haymet, Rev. Sci. Inst. 66, 2996 (1995).
J. Rosinski and A. Lecinski, J. Phys. Chem. 85, 2993 (1981).
M. Gavish, R. Popovitz-Biro, M. Lahav, and L. Leiserowitz, Science 250, 973 (1990).
K. B. Storey and J. M. Storey, Sci. Am. (December, 1990), p. 92.
C. A. Knight and N. C. Knight, Science (Nov. 10, 1972).
R. Lipowsky, Phys. Rev. Lett. 49, 1575 (1982).
R. Ohnesorge, H. Lowen, and H. Wagner, Phys. Rev. E 50, 4801 (1994).
J. Z. Larese and Q. M. Zhang, Phys. Rev. Lett. 64, 922 (1990).
D. Zhu and J. G. Dash, Phys. Rev. Lett. 60, 432 (1988).
J. W. M. Frenken and J. F. van der Veen, Phys. Rev. Lett. 54, 134 (1985).
B. Pluis, A. W. Denier van der Gon, J. W. M. Frenken, and J. F. van der Veen, Phys. Rev. Lett. 59, 2678 (1987)
J. J. Metois and J. C. Heyraud, J. Phys. France 50, 3175 (1989)
J. G. Dash, H. Fu and J. S. Wettlaufer, Rep. Prog. Phys. 58, 115 (1995)
M. Elbaum andM. Schick, Phys. Rev. Lett. 66, 1713 (1991)
M Elbaum, S. G. Lipson, and J. G. Dash, J. Cryst. Growth 129, 491 (1993)
P. Buffat and J.-P. Borel, Phys. Rev. A 13, 2287 (1976)
T. L. Beck, J. Jellinek, and R. S. Berry, J. Chem. Phys. 87, 545 (1987)
F. Ercolessi, W. Andreoni, and E. Tosatti, Phys. Rev. Lett. 66, 911 (1991)
M. B. Baker and J. G. Dash, J. Cryst. Growth 97, 770 (1989); J. Geophys. Res. 99, 10621 (1994).
D. Beaglehole, J. Cryst. Growth 112, 663 (1991)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Oxtoby, D.W. (1999). Nucleation and Surface Melting of Ice. In: Wettlaufer, J.S., Dash, J.G., Untersteiner, N. (eds) Ice Physics and the Natural Environment. NATO ASI Series, vol 56. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-60030-2_3
Download citation
DOI: https://doi.org/10.1007/978-3-642-60030-2_3
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-64226-5
Online ISBN: 978-3-642-60030-2
eBook Packages: Springer Book Archive