Abstract
Attention has been given to the development of new higher strength steel grades by employing duplex microstructures of bainitic or martensitic ferrite with retained austenite. Such microstructures rely first upon appropriate alloying to stabilise austenite against thermal decomposition, either isothermally to bainite or athermally to martensite. The alloying, typically by involving Si additions, promotes chemical stabilisation indirectly through suppression of carbide precipitation and hence increase of austenite carbon concentration. The most recent novel concept, aimed at higher strength martensitic grades, combines enhanced Si alloying with an interrupted quench, followed by an anneal to allow carbon migration from supersaturated martensite regions to untransformed austenite, a process which has become known as quenching and partitioning, or Q&P. Recent progress in understanding the detailed evolution of microstructure during the Q&P heat treatment, and the potential for exploration of the resulting microstructures in various steel grades, will be described.
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References
J.H. Woodhead, S.R. Keown, Am. Soc. Metals 15 (1986)
T. Gladman, The Physical Metallurgy of Microalloyed Steels (Institute of Materials, London, 1997)
G.E. Totten, L. Xie, K. Funatani (eds.), Handbook of Mechanical Alloy Design (Marcel Dekker, New York, 2004)
A.R. Marder, J.I. Goldstein (eds.), Phase Transformations in Ferrous Alloys (AIME, 1984)
H.K.D.H. Bhadeshia, D.V. Edmonds, Metall. Trans. 10A, 895 (1979)
S. Matas, R.F. Hehemann, Trans. AIME 221, 176 (1961)
J.P. Oblak, R.F. Hehemann, Transformations and Hardenability in Steels (Climax Molybdenum Co., 1967)
R.F. Hehemann, Phase Transformations (American Society for Metals, OH, USA, 1970)
R.F. Hehemann, K.R. Kinsman, H.I. Aaronson, Metall. Trans. 3, 1077 (1972)
H.K.D.H. Bhadeshia, D.V. Edmonds, Acta Metall. 28, 1265 (1980)
J.G. Speer, D.V. Edmonds, F.C. Rizzo, D.K. Matlock, Curr. Opin. Solid-State Mater. Sci. 8, 219 (2004)
A.A. Honarbakhsh-Raouf, Dissertation, University of Leeds, UK (1997)
H.K.D.H. Bhadeshia, D.V. Edmonds, Metal Sci. J. 17, 411 (1983)
V.T.T. Miihkinen, D.V. Edmonds, Mater. Sci. Technol. 3, 422 (1987)
J.A. Charles, G.W. Greenwood, G.C. Smith (eds.), Future Developments of Metals and Ceramics (London, 1992)
J.K. Yates, Sci. Parliam. 53, 2 (1996)
J.K. Yates, (1996) British Steel Track Products, Innovation in Rail Steel. http://www.msm.cam.ac.uk/Phase-Trans/Parliament.html
V.F. Zackay, E.R. Parker, Steel 161, 73 (1967)
V.F. Zackay, E.R. Parker, D. Fahr, B. Bush, ASM Trans. Q 60, 252 (1967)
I. Tamura, Metal Sci. 16, 245 (1982)
O. Matsumura, Y. Sakuma, H. Takechi, Scripta Metall. 21, 1301 (1987)
O. Matsumura, Y. Sakuma, H. Takechi, Trans. ISIJ 27, 570 (1987)
P. Jacques, Y. Carnot, P. Harlet, J. Ladriere, F. Delannay, Metall. Trans. 29A, 2383 (1998)
E. Girault, P. Jacques, P. Ratchev, J. Van Humbeeck, B. Verlinden, E. Aernoudt, Mater. Sci. Eng. A273, 471 (1999)
B.C. De Cooman, Curr. Opin. Solid State Mater. Sci. 8, 285 (2004)
F.G. Caballero, H.K.D.H. Bhadeshia, J.A. Mawella, D.G. Jones, P. Brown, Mater. Sci. Technol. 18, 279 (2002)
C. Garcia-Mateo, F.G. Caballero, H.K.D.H. Bhadeshia, J. De Phys. Colloque 112, 285 (2003)
C. Garcia-Mateo, F.G. Caballero, H.K.D.H. Bhadeshia, ISIJ 43, 1238 (2003)
F.G. Caballero, H.K.D.H. Bhadeshia, J.A. Mawella, D.G. Jones, P. Brown, Mater. Sci. Technol. 17, 512 (2001)
H.K.D.H. Bhadeshia, in Proceedings Conference New Developments on Metallurgy and Applications of High Strength Steels, Buenos Aires, 3 (2008)
P.M. Brown, D.P. Baxter, in Proceedings Conference Materials Science and Technology, Physical Metallurgy and Property Development 433 (2004)
J.G. Speer, D.K. Matlock, B.C. De Cooman, J.G. Schroth, Acta Mater. 51, 2611 (2003)
J.G. Speer, A.M. Streicher, D.K. Matlock, F.C. Rizzo, G. Krauss, Austenite Formation and Decomposition, 505 (2003)
D.K. Matlock, V.E. Brautigam, J.G. Speer, in Proceedings Conference Thermec’03. Trans Tech Publications, 1089 (2003)
D.V. Edmonds, K. He, F.C. Rizzo, B.C. De Cooman, D.K. Matlock, J.G. Speer, Mater. Sci. Eng. A438–440, 25 (2006)
T.D. Bigg, D.V. Edmonds, in Proceedings 7th Pacific Rim conference Advanced Materials and Processing. Mater Sci Forum, vol. 33 (2010) pp. 654–656
T.D. Bigg, D.K. Matlock, J.G. Speer, D.V. Edmonds, in Proceedings conference Solid-Solid Phase Transformations in Inorganic Materials (2010)
D. Kalish, E.M. Roberts, Metall. Trans. 2, 2783 (1971)
A.J. Clarke, Dissertation, Colorado School of Mines, CO, USA (2006)
D.V. Edmonds, K. He, M.K. Miller, F.C. Rizzo, A. Clarke, D.K. Matlock, J.G. Speer, in Proceedings conference Thermec’06, Mater. Sci. Forum 4819, 539–543 (2007)
A.J. Clarke, J.G. Speer, M.K. Miller, R.E. Hackenberg, D.V. Edmonds, D.K. Matlock, F.C. Rizzo, K.D. Clarke, E. De Moor, Acta Mater. 56, 16 (2008)
A.J. Clarke, J.G. Speer, D.K. Matlock, F.C. Rizzo, D.V. Edmonds, M.J. Santofimia, Scripta Mater. 61, 149 (2009)
M.J. Santofimia, T. Nguyen-Minh, L. Zhao, D.N. Hanlon, T.A. Kop, J. Sietsma, in Proceedings conference New Developments in Advanced High-Strength Sheet Steels, vol. 191 (2008)
M.J. Santofimia, L. Zhao, J. Sietsma, Metall. Trans. 40A, 46 (2009)
H.Y. Li, X.W. Lu, X.C. Wu, Y.A. Min, X.J. Jin, Mater. Sci. Eng. A527, 6255 (2010)
F.L.H. Gerdemann, J.G. Speer, D.K. Matlock, in Proceedings Conference Materials Science and Technology, (2004)
D.V. Edmonds, K. He, F.C. Rizzo, A. Clarke, D.K. Matlock, J.G. Speer, in Proceedings 1st conference Super-High Strength Steels (2005)
K. He, D.V. Edmonds, J.G. Speer, D.K. Matlock, A. Clarke, F.C. Rizzo, in Proceedings 16th. Microscopy Congress, vol. 3, (2006) 1702
M. Hillert, J. Agren, Scripta Mater. 50, 697 (2004)
J.G. Speer, D.K. Matlock, B.C. De Cooman, J.G. Schroth, Scripta Mater. 52, 83 (2005)
M. Hillert, J. Agren, Scripta Mater. 52, 87 (2005)
N. Zhong, X. Wang, Y. Rong, L. Wang, J. Mater. Sci. Technol. 22, 751 (2006)
J.G. Speer, R.E. Hackenberg, B.C. De Cooman, D.K. Matlock, Phil. Mag. Lett. 87, 379 (2007)
M.J. Santofimia, L. Zhao, J. Sietsma, Scripta Mater. 59, 159 (2008)
M.J. Santofimia, L. Zhao, R. Petrov, J. Mater. Character 59, 1758 (2008)
S.J Kim, H.S. Kim, B.C. De Cooman, in Proceedings conference Materials Science and Technology, MS&T’07, Steel Properties and Applications, 73 (2007)
S.J. Kim, J.G. Speer, H.S. Kim, B.C. De Cooman, in Proceedings conference New Developments in Advanced High-Strength Sheet Steels, 179 (2008)
D.H. Kim, J.G. Speer, H.S. Kim, B.C. De Cooman, Metall. Trans. 40A, 2048 (2009)
H.Y. Li, X.J. Jin, in Proceedings 7th Pacific Rim conference Advanced Materials and Processing. Mater. Sci. Forum 86, 654–656 (2010)
H. Li, X. Jin, Chin. J. Mech. Eng. 22, 645 (2009)
E. De Moor, J. Penning, C. Fojer, A. Clarke, J.G. Speer, in Proceedings Conference New Developments in Advanced High-Strength Sheet Steels, 199 (2008)
W.S. Owen, Trans. ASM 46, 812 (1954)
J. Gordine, I. Codd, J. Iron Steel Inst. 207, 461 (1969)
W.C. Leslie, G.C. Rauch, Metall. Trans. 9A, 343 (1978)
S.J. Barnard, G.D.W. Smith, A.J. Garratt-Reed, Sande J. Vander, in Proceedings Conference Advances in the Physical Metallurgy and Applications of Steels, 33 (1981)
D.V. Edmonds, in Proceedings 6th conference Processing and Manufacturing of Advanced Materials, Thermec’09, Mater. Sci. Forum 110, 638–642 (2010)
H.Y. Li, X.W. Lu, W.J. Li, X.J. Jin, Metall. Trans. 41A, 1284 (2010)
T.Y. Hsu, Z.Y. Xu, Mater. Sci. Forum 561–565, 2283 (2007)
X.D. Wang, N. Zhong, Y.H. Rong, T.Y. Hsu, L. Wang, J. Mater. Res. 24, 260 (2009)
N. Zhong, X.D. Wang, L. Wang, Y.H. Rong, Mater. Sci. Eng. A506, 111 (2009)
X.D. Wang, W.Z. Xu, Z.H. Guo, L. Wang, Y.H. Rong, Mater. Sci. Eng. A527, 3373 (2010)
Y. Wang, S. Zhou, Z. Guo, Y. Rong, in Proceedings 7th Pacific Rim conference Advanced Materials and Processing, Mater. Sci. Forum 37, 654–656 (2010)
Y. Cao, F. Ernst, G.M. Michal, Acta Mater. 51, 4171 (2003)
D.V. Edmonds, K. He, F.C. Rizzo, J.G. Speer, D.K. Matlock, in Proceedings conference New Developments on Metallurgy and Applications of High Strength Steels, 829 (2008)
K. He, D.V. Edmonds, J.G. Speer, D.K. Matlock, F.C. Rizzo, in Proceedings 14th European Microscopy Congress, EMC’08. vol. 2, Materials Science, 429 (2008)
F.L.H. Gerdemann, Dissertation, Aachen University of Technology, Germany (2004)
G. Krauss, Colorado School of Mines, CO, USA. Private communication (2009)
J.G Speer, A.J. Shutts, D.K. Matlock, D.V. Edmonds, F. Rizzo, E.B. Damm, in Proceedings conference New Developments in Long and Forged Products: Metallurgy and Applications, 191 (2006)
S.C. Hong, J.C. Ahn, S.Y. Nam, S.J. Kim, H.C. Yang, J.G. Speer, D.K. Matlock, Metals Mater. Int. 13, 439 (2007)
F. Rizzo, A.R. Martins, J.G. Speer, D. Matlock, A. Streicher, B. De Cooman, in Proceedings 5th conference Processing and Manufacturing of Advanced Materials, Mater. Sci. Forum 4476, 539–543 (2007)
A.R. Martins, F. Rizzo, D. Coelho, J.G. Speer, D.K. Matlock, K. He, D. Edmonds, in Proceedings Conference Materials Science and Technology, MS&T’09, 825 (2009)
C. Wang, J. Shi, S. Liu, S. Du, H. Dong, Chin. J. Mater. Res. 23, 305 (2009)
B. Masek, H. Jirkova, D. Klauberova, L. Kucerova, D. Hauserova, in Proceedings 7th Pacific Rim conference Advanced Materials and Processing, Mater. Sci. Forum 94, 654–656 (2010)
D.K. Matlock, J.G. Speer, Structural Steels, 774 (2006)
O. Yakubovsky, N. Fonstein, D. Bhattacharya, in Proceedings conference Trip-Aided High Strength Ferrous Alloys, 263 (2002)
W.Q. Cao, C.Y. Wang, J. Shi, H. Dong, in Proceedings 7th Pacific Rim conference Advanced Materials and Processing, Mater. Sci. Forum 29, 654–656 (2010)
H.J. Jun, N. Fonstein, in Proceedings Conference New Developments in Advanced High-Strength Sheet Steels, 155 (2008)
J-W. Jin, S.H. Byun, S.B. Lee, S.I. Kim, C.S. Oh, N. Kang, K-M. Cho, in Proceedings Conference New Developments in Advanced High-Strength Sheet Steels, 169 (2008)
X. Wang, Z. Guo, Y. Rong, in Proceedings 7th Pacific Rim conference Advanced Materials and Processing, Mater. Sci. Forum 90, 654–656 (2010)
B.C. De Cooman, J.G. Speer, Steel Res. Inst. 77, 634 (2006)
E. De Moor, Dissertation, Universiteit Gent, Belgium (2009)
G.A. Thomas, J.G. Speer, DK Matlock, in Proceedings conference New Developments in Advanced High-Strength Sheet Steels, 227 (2008)
Acknowledgments
A research programme linked to this article was conducted initially under an international collaboration supported in the authors’ respective countries by NSF Grant # 0303510 (USA) and EPSRC Grant ref: GR/S86501 (UK). Support by sponsors of the Advanced Steel Processing and Products Research Center at the Colorado School of Mines is also acknowledged.
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Edmonds, D., Matlock, D., Speer, J. (2011). Developments in High Strength Steels with Duplex Microstructures of Bainite or Martensite with Retained Austenite: Progress with Quenching and Partitioning Heat Treatment. In: Weng, Y., Dong, H., Gan, Y. (eds) Advanced Steels. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-17665-4_24
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