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Non-NHCs Stable Singlet Carbene Ligands

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Transition Metal Complexes of Neutral eta1-Carbon Ligands

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 30))

Abstract

Carbene chemistry has been tremendously developed during the last 20 years. NHC carbenes have found many applications as ligands in organometallic chemistry or as catalysts in organocatalysis. On the other hand, the so-called “non-NHC stable carbenes” have had a restrained development to date in spite of the high potential of this family of carbenes which offers many more possibilities in structure modifications, resulting in original reactivities. This chapter gives an overview over non-NHC stable singlet carbenes and their properties as ligands.

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Authors and Affiliations

  1. Université de Toulouse, UPS, LHFA, 118 route de Narbonne, F-31062, Toulouse, France

    Tsuyoshi Kato, Eddy Maerten & Antoine Baceiredo

Authors
  1. Tsuyoshi Kato
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  2. Eddy Maerten
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  3. Antoine Baceiredo
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Correspondence to Antoine Baceiredo .

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Editors and Affiliations

  1. CNRS, Université Toulouse III, route de Narbonne 205 , Toulouse CX 4, 31077, France

    Remi Chauvin

  2. CNRS, Université Toulouse III, route de Narbonne 205 , Toulouse CX 4, 31077, France

    Yves Canac

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Kato, T., Maerten, E., Baceiredo, A. (2010). Non-NHCs Stable Singlet Carbene Ligands. In: Chauvin, R., Canac, Y. (eds) Transition Metal Complexes of Neutral eta1-Carbon Ligands. Topics in Organometallic Chemistry, vol 30. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-04722-0_5

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