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Seminal Publications in Electrochemistry and Electroanalysis

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Book cover Electroanalytical Methods

Abstract

This compilation of seminal publications in electrochemistry and electroanalysis is neither complete nor are all the listed contributions of the same importance. The authors feel that it might be of interest and very rewarding for people who use electroanalytical methods in the laboratory to go back to the roots and read some of the publications which later initiated strong developments of the science that is presented in this book. Many of the contributions to science cited here became an inherent part of textbooks and common knowledge so that the original work is usually not referred to and access to this information is difficult. The following web pages give access to much more information on the history of electrochemistry and electroanalysis:

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References

  1. L. GALVANI (1737–1798) publishes electrical experiments with frogs: (1791) De Bononiensi Scientiarum et Artium Instituto atque Academia Commentarii VII: 363, [Ostwalds Klassiker Bd 52 (1894)]

    Google Scholar 

  2. A. VOLTA (1745–1827) communicates the construction of an electrochemical pile in a letter to Sir Joseph Banks, published in: (1800) Philos Trans II: 405 (*)

    Google Scholar 

  3. W. CRUIKSHANKS (1745–1800) publishes the first qualitative analysis (copper) performed with the help of electrolysis: (1800) Nicholsons Journal 4: 187

    Google Scholar 

  4. H. DAVY (1778–1829) publishes a theory of electrolysis: (1807) Philos Trans 1

    Google Scholar 

  5. H. DAVY (1778–1829) discovers sodium and potassium by electrolysis: (1808) Philos Trans (*)

    Google Scholar 

  6. J. J. BERZELIUS (1779–1848) publishes an electrochemical theory of the chemical bond: (1812) J Chem Phys 6: 119

    Google Scholar 

  7. G. S. OHM (1789–1854) publishes the law that became known as Ohm’s law: (1826) Schweigger’s J 46: 137

    Google Scholar 

  8. M. FARADAY (1791–1867) publishes numerous observations on electrochemistry, including the famous law and introduced the modern electrochemical nomenclature (e.g., ion, anion, cation, electrolyte, electrode): (1832–1834) Philos Trans, (Ostwalds Klassiker Bd. 81, 86, 87, 126, 128, 131, 134, 136, Leipzig, 1896–1903) (*); see also: “Faraday as a discoverer” by J. Tyndall (1894)

    Google Scholar 

  9. W. GIBBS (1822–1908) publishes the first electrogravimetric analysis: (1864) Fresenius Z Anal Chem 3: 334

    Google Scholar 

  10. G. J. LIPPMANN (1845–1921) introduces the capillary electrometer that bears his name: Ann Phys 225:546

    Google Scholar 

  11. H. L. F. v. HELMHOLTZ (1821–1894) introduces the dropping mercury electrode, publishes a model of the electrical double layer: (1879) Wied Ann 7: 337

    Google Scholar 

  12. H. L. F. v. HELMHOLTZ (1821–1894) reports in his Faraday Lecture the electrochemical cell with a glass membrane as the separator and build by his assistant W. GIESE (1847–?): (1881) J Chem Soc 39: 277. This was the first glass electrode, although neither Giese nor Helmholtz realized its significance for pH measurements (*)

    Google Scholar 

  13. S.A. ARRHENIUS (1859–1927) publishes the theory of dissociation of electrolytes in water: (1887) Z physik Chem I: 631 (*)

    Google Scholar 

  14. F. W. OSTWALD (1853–1932) publishes a law, which later became known as Ostwalds’ dilution law: (1888) Z physik Chem 2: 36 (*)

    Google Scholar 

  15. W. NERNST (1864–1941) publishes in his habilitation “Die elektro-motorische Wirksamkeit der Jonen”, Leipzig, 1889, the fundamental equation which relates the potential to ion activities: (1889) Z phys Chem 4: 29

    Google Scholar 

  16. R. BEHREND (1856–1926) publishes the first potentiometric precipitation titration: (1893) Z physik Chem 11: 466

    Google Scholar 

  17. E. SALOMON (1874–?) publishes the first current-voltage curve in the form of discrete points: (1896) Z Elektrochem 3: 264 (see also his PhD thesis, Göttingen 1897)

    Google Scholar 

  18. W. BÖTTGER (1871–1949) publishes the first potentiometric acid-base titration: (1897) Z physik Chem 24: 253

    Google Scholar 

  19. E. SALOMON (1874–?) describes the first amperometric titration: Z Elektrochem 4:71 (see also his PhD thesis, Göttingen 1897)

    Google Scholar 

  20. F. CROTOGINO (1878–1947) publishes the first potentiometric redox titration: (1900) Z anorg Chem 24: 225

    Google Scholar 

  21. E. H. RIESENFELD (1877–1957) and W. NERNST (1864–1941) publish the first experiments involving an ion transfer between immiscible electrolyte solutions: (1901) Ann Phys 8:600

    Google Scholar 

  22. F. W. KÜSTER (1861–1917) and M. GRÜTERS publish the first conducto-metric titration: (1903) Z anorg Chem 35: 54

    Google Scholar 

  23. F. G. COTTRELL (1877–1948) publishes the equation which is known as the Cottrell equation: (1903) Z physik Chem 42: 385

    Google Scholar 

  24. B. KUČERA (1874–1921) introduces the dropping mercury electrode for electrocapillary studies: (1903) Ann Phys 11: 529

    Google Scholar 

  25. J. TAFEL (1862–1918) publishes his empirically discovered equation: (1905) Z phys Chem 50: 641

    Google Scholar 

  26. M. CREMER (1865–1935) publishes the observation of a voltage drop across a glass membrane and thus led the basis for modern glass electrodes: (1906) Z Biol 29: 562

    Google Scholar 

  27. S. P. L. SØRENSEN (1868–1939) introduces the concept of pH: (1909) Compt Rend Lab Carlsberg 8: 1, 396; (1909) Biochem Z 21: 131, 201; 22: 352 (*)

    Google Scholar 

  28. F. HABER (1868–1934) and Z. KLEMENSIEWICZ (1886–1963) publish the glass electrode for pH-measurements: (1909) Z physik Chem 67: 385

    Google Scholar 

  29. F. G. DONNAN (1870–1956) publishes a theory of membrane potentials: (1911) Z Elektrochem 17: 204; (1924) Chem Rev 1: 73

    Google Scholar 

  30. L. G. GOUY (1854–1926) [(1909) Compt Rend 149: 654 and (1910) J Phys 9: 457] and D. L. CHAPMAN (1869–1958) [(1913) Phil Mag 25: 475] publish a model of the electrical double layer

    Google Scholar 

  31. E. Ch. S. BIILMANN (1873–1946) introduces the quinhydrone electrode for pH measurements: (1921) Ann Chim 15:109

    Google Scholar 

  32. J. HEYROVSKÝ (1890–1967) publishes first results with the method which he soon called polarography: (1922) Chemicke Listy 16: 256; (1923) Philos Mag 45: 303

    Google Scholar 

  33. J. N. BRØNSTED (1879–1947) gives a new definition of acids and bases: Rec Trav Chim Pays-Bas 42: 718 (*)

    Google Scholar 

  34. P. J. W. DEBYE (1884–1966) and E. A. J. HÜCKEL (1896–1980) publish what is now known as the Debye-Hückel theory of strong electrolytes: Debye P, Hückel E (1923) Phys Z 24:185, 305

    Google Scholar 

  35. O. STERN (1888–1969) publishes his model of the electrical double layer: (1924) Z Elektrochem 30: 508

    Google Scholar 

  36. J. A. V. BUTLER (1899–1977) publishes his contribution to the equation which is known as the Butler-Volmer equation: (1924) Trans Faraday Soc 19: 734

    Google Scholar 

  37. J. HEYROVSKÝ (1890–1967) and M. SHIKATA (1895–1965) publish the construction of the first polarograph, which was the first automatic analyzer: (1925) Rec Trav chim Pays-Bas 46: 496

    Google Scholar 

  38. J. HEYROVSKÝ (1890–1967) and J. BABICKA publish the first observation of a catalytic hydrogen wave: (1930) Coll Czech Chem Commun 2: 370

    Google Scholar 

  39. T. ERDEY-GRÚZ (1902–1976) and M. VOLMER (1885–1965) publish the equation which becomes later known as the Butler-Volmer equation, and they introduce the transfer coefficient: (1930) Z phys Chem A150: 203

    Google Scholar 

  40. Ch. ZBINDEN (1904–1983) publishes a copper determination which can be termed chronopotentiometric stripping microcoulometry: (1931) Bull de la soc chim biol 13: 35. This can be regarded as the key step towards anodic stripping voltammetry.

    Google Scholar 

  41. I. SLENDYK publishes the first example of a catalytic hydrogen wave caused by platinum traces: (1932) Coll Czech Chem Commun 4: 335

    Google Scholar 

  42. A.N. FRUMKIN (1895–1976) describes the influence of the electrical double layer on the kinetics of electrode reactions: (1933) Z Physik Chem 164A: 121

    Google Scholar 

  43. D. ILKOVIČ (1907–1980) publishes the equation which is known as the Ilkovic equation: (1934) Coll Czech Chem Commun 6: 498

    Google Scholar 

  44. A. O. BECKMANN ((1900–2004) invented the first pH meter based on vacuum-tube amplifier (US Patent No. 2,058,761)

    Google Scholar 

  45. J. HORIUTI (1901–1979) and M POLANYI (1891–1976) explain the meaning of the charge transfer coefficient by the help of transition-state theory: Horiuti J, Polanyi M (1935) Acta Physicochim URSS 2:505

    Google Scholar 

  46. L. SZEBELLEDY (1901–1944) and Z. SOMOGYI (1915–1945) establish coulometric analysis: (1938) Fresenius Z Anal Chem 112: 313, 323, 385, 391, 395, 400

    Google Scholar 

  47. I. M. KOLTHOFF (1894–1993) and H. A. LAITINEN (1915–1991) introduce the term voltammetry: (1940) Science 92: 152

    Google Scholar 

  48. V. G. LEVICH (1917–1987) publishes the equation describing the limiting current at a rotating disk electrode: (1942) Acta Physicochim USSR 17: 257

    Google Scholar 

  49. M. KALOUSEK (1915–1996) introduces what is later called ‘Kalousek commutator’: (1948) Coll Czech Chem Commun 13–105

    Google Scholar 

  50. J.E.B. RANDLES (1912–1998) develops linear sweep voltammetry and gives the equation for the peak current of linear sweep voltammetry known as the Randles-Sevcik equation: (1948) Trans Faraday Soc 44: 327. A. SEVCIK (1926–2006) derives a similar equation independently: (1948) Coll Czech Chem Commun 13: 349

    Google Scholar 

  51. G. C. BARKER (1915–2000) and I. L. JENKINS introduce square-wave po-larography: (1952) Analyst 77: 685

    Google Scholar 

  52. V. G. LEVICH (1917–1987) publishes his fundamental book Physico-chemical Hydrodynamics (Izd Akad Nauk SSSR, 2nd ed 1952, Engl Translation: Prentice Hall 1962)

    Google Scholar 

  53. W. KEMULA (1902–1985) introduces polarographic detection in liquid chromatography (so-called chromatopolarography): (1952) Roczn chem 26: 281

    Google Scholar 

  54. W. KEMULA (1902–1985) and Z. KUBLIK (1922–2005) introduce the hanging mercury drop electrode (HMDE or Kemula electrode) and anodic stripping voltammetry: (1956) Roczn chem 30: 1005; (1958) Anal Chim Acta 18: 104; (1959/60) J Electroanal Chem 1: 123

    Google Scholar 

  55. G. MAMANTOV, P. PAPOFF and P. DELAHAY publish on anodic stripping analysis with hanging mercury drop electrodes employing current and potential step methods: (1957) J Am Chem Soc 79: 4034

    Google Scholar 

  56. A. H. MAKI and D. H. GESKE develop the electrochemical ESR cell: (1959) J Chem Phys 30: 1356

    Google Scholar 

  57. G. C. BARKER (1915–2000) and A. W. GARDNER introduce pulse polarography: (1960) Fresenius Z. Anal. Chem 173: 79. [They published it as early as 1958, however, in a lesser known journal: (1958) At Energy Res Establ, Harwell, C/R 2297).

    Google Scholar 

  58. S. BRUCKENSTEIN and T. NAGAI report the first potentiometric stripping analysis: (1961) Anal Chem 33: 1201

    Google Scholar 

  59. E. PUNGOR (1923–2007) and E. HOLLOS-ROKOSINYI develop the first ion-selective electrode after the invention of the glass electrode: (1961) Acta Chim Hung 27: 63

    Google Scholar 

  60. A. Y. GOKHSHTEIN and Y. P. GOKHSHTEIN (1906–1996) introduce the static mercury drop electrode: (1962) Zh fiz khim 36: 651

    Google Scholar 

  61. J. O’M. BOCKRIS, M. A. V. DEVANATHAN and K. MÜLLER publish their model of the electrical double layer: (1963) Proc Royal Soc (London) A 274: 55

    Google Scholar 

  62. T. KUWANA, R.K. DARLINGTON and D.W. LEDDY develop spectroelec-trochemistry by using optically transparent electrodes: (1964) Anal Chem 36: 2023

    Google Scholar 

  63. R. S. NICHOLSON and I. SHAIN publish the characteristic equations for cyclic voltammetry which they developed using numerical methods: Anal Chem 36:706

    Google Scholar 

  64. R. A. MARCUS publishes his theory for electron transfer reactions: (1965) J Chem Phys 43: 679

    Google Scholar 

  65. P. R. MOSES, L. WIER and R. W. MURRAY introduce chemically modified electrodes: (1975) Anal Chem 47: 1889

    Google Scholar 

  66. D. JAGNER and A. GRANELI introduce potentiometric stripping analysis on a broad scale: (1976) Anal Chim Acta 83: 19

    Google Scholar 

  67. R. N. ADAMS (1924–2002) starts to use microelectrodes: (1976) Anal Chem 48: 1126A

    Google Scholar 

  68. A. MERZ and A. J. BARD [(1978) J Am Chem Soc 100: 3222] as well as M. R. VAN DE MARK and L. L. MILLER publish the first papers on polymer film electrodes: (1978) J Am Chem Soc 100: 3223

    Google Scholar 

  69. K. B. OLDHAM publishes an analytical formula describing an entire linear scan voltammogram: J Electroanal Chem 105:373

    Google Scholar 

  70. K. AOKI, J. OSTERYOUNG and R. A. OSTERYOUNG (1927–2004) introduce differential double pulse polarography: (1980) J Electroanal Chem 110: 1

    Google Scholar 

  71. R. MALPAS, R. A. FREDLEIN and A. J. BARD [(1979) J Electroanal Chem 98: 171]; J. H. KAUFMAN, K. K. KANAZAWA and G. B. SREET [(1984) Phys Rev Lett 53: 2461], as well as S. BRUCKENSTEIN and S. SWATHIRAJAN [(1985) Electrochim Acta 30: 851] develop the electrochemical quartz crystal microbalance (EQCM) technique.

    Google Scholar 

  72. A. J. BARD, F.-R. FAN, J. KWAK and O. LEV publish the first true scanning electrochemical microscopy (SECM): (1989) Anal Chem 61: 132

    Google Scholar 

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Scholz, F., Inzelt, G., Stojek, Z. (2010). Seminal Publications in Electrochemistry and Electroanalysis. In: Scholz, F., et al. Electroanalytical Methods. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-02915-8_18

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