Abstract
Recently, the fugacity concept has been introduced and used to model the fate of chemicals which may be accidentally or deliberately released into the environment [1–3]. Its application to environmental fate determinations of toxic substances results in simplified equations for partitioning, transport, and reaction processes and their assembly into a coherent model. Expressing the distribution of contaminants in the environment in terms of fugacity rather than concentration facilitates interpretation of the dynamic processes to which the substances are subject.
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References
Mackay D.: Finding fugacity feasible. Environ. Sci. & Technol. 13, 1218 (1979)
Mackay, D., Paterson, S.: Calculating fugacity. Environ. Sci. & Technol. 15(9), 1006–1014 (1981)
Mackay, D., Paterson, S.: Fugacity revisited. Environ. Sci. & Technol. 16, 654–660 (1982)
Lewis, G.N.: The law of physico-chemical change. Daedalus, Proc. Am. Acad. 37, 49 (1901)
Prausnitz, J.M.: Molecular thermodynamics of fluid phase equilibrium. Prentice Hall, Englewood Cliffs, N.J. (1973)
Van Ness, H.C., Abbott, M.M.: Classical thermodynamics of non electrolyte solutions. McGraw Hill (1982)
Mackay, D., Bobra, A., Chan, D., Shiu, W.Y.: Vapor pressure correlations for low volatility environmental chemicals. Environ. Sci. & Technol. 16, 645–649 (1982)
Mackay, D., Bobra, A., Shiu, W.Y.: Relationships between aqueous solubility and octanol-water partition coefficients. Chemosphere 9, 701–711 (1980)
Mackay, D.: Correlation of bioconcentration factors. Environ. Sci. & Technol. 16, 274–278 (1982)
Karickhoff, S.W.: Semi-empirical estimation of sorption of hydrophobic pollutants on natural sediments and soils. Chemosphere 10, 833–849 (1981)
Baughman, G.L., Lassiter, R.R.: In: Estimating the hazard of chemical substances to aquatic life. ASTM Tech. Pub. 657, Cairns, J. Jr., Dickson, K.G., Maki, A.W., Eds. 35 (1978)
Burns, L.A., Cline, D.M., Lassiter, R.R.: Exposure analysis modeling system (EXAMS): User manual and system documentation. U.S. EPA Environmental Research Laboratory, Athens, GA(1981)
Smith, J.H., Mabey, W.R., Bohonos, N., Holt, B.R., Lee, S.S., Chou, T.-W., Bomberger, D.C., Mill, T.: Environmental pathways of selected chemicals in freshwater systems, Vol. II, EPA-600/7-78-074 (1978)
Neely, W.B., Mackay, D.: In: Modelling the fate of chemicals in the aquatic environment, Dickson, K.L., Maki, A.W., Cairns, J. (eds). Ann Arbor Science, Ann Arbor, MI. 127 (1982)
Schmidt-Bleek, F., Haberland, W., Klein, A.W., Caroli, S.: Steps towards environmental haward assessment of new chemicals (including a hazard ranking scheme, based on directive 79/831/EEC). Chemosphere 11, 383 (1982)
Hushon, J.M., Klein, A.W., Strachan, W.J.M., Schmidt-Bleek, F.: Use of OECD premarket data in environmental exposure analysis for new chemicals. Chemosphere 12, 887 (1983)
Georgopoulos, P.G., Seinfeld, J.H.: Statistical distributions of air pollutant concentration. Environ. Sci. & Technol. 7, 401A (1982)
Dean, R.B.: In: Chemistry in water reuse, W.J. Cooper (ed). Ann Arbor Science, Ann Arbor, MI (1981)
Mackay, D., Paterson, S.: Spatial concentration distributions. Environ. Sci. & Technol. 18, 207A(1984)
Hahn, G.J., Shapiro, S.S.: Statistical models in engineering. J. Wiley & Sons, Inc. (1967)
Aitchison, J., Brown, J.A.C.: The lognormal distribution. Cambridge University Press (1966)
Weibull, W.: A statistical distribution function of wide applicability, presented to the American society of mechanical engineers. Atlantic City, N.J. (1951)
Mackay, D., Joy, M, Paterson, S.: A quantitative water, air, sediment interaction (QWASI) fugacity model for describing the fate of chemicals in lakes. Chemosphere 12, 981–997 (1983)
Mackay, D., Paterson, S., Joy, M.: A quantitative water, air, sediment interaction (QWASI) fugacity model for describing the fate of chemicals in rivers. Chemosphere 12, 1193–1208 (1983)
Rosenblatt, D.H., Dacre, J.C., Cogley, D.R.: In: Environmental risk analysis for chemicals, Conway, R.J., ed. Van Nostrand Reinhold, New York, 474 (1980)
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Paterson, S., Mackay, D. (1985). The Fugacity Concept in Environmental Modelling. In: Reactions and Processes. The Handbook of Environmental Chemistry, vol 2 / 2C. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-39048-0_4
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DOI: https://doi.org/10.1007/978-3-540-39048-0_4
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