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Handbook of Materials Characterization pp 549–596Cite as

31P Solid-State NMR Spectroscopy of Adsorbed Phosphorous Probe Molecules: Acidity Characterization of Solid Acid Carbonaceous Materials for Catalytic Applications

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Abstract

In recent years, solid acid catalysis has evolved as sustainable route or eco-friendly replacement for their homogeneous counterparts in both industrial and academic settings. In this context, the acidity characterization of solid acid catalysts, in particular carbonaceous materials and composites, using phosphorus-31 magic-angle-spinning solid-state nuclear magnetic resonance (31P MAS SSNMR) spectroscopy is significantly influencing the current state-of-the-art at the interface of materials science and analytical chemistry. This book chapter provides a fair insight about 31P MAS SSNMR of adsorbed phosphorous probe molecules being used for the characterization of surface acidic properties of a variety of carbonaceous materials including graphene. In line with this, the catalytic applications of these carbon-based solid acid catalysts have also been discussed appropriately.

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Acknowledgements

Dr. B. Garg is thankful to the Science and Engineering Research Board (SERB), New Delhi, Government of India (YSS/2015/002036), for financial support. B. Garg additionally thanks to all the publishers for providing permissions in reusing the figures and schemes.

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  1. Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee, Uttarakhand, India

    Bhaskar Garg

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  1. Department of Physics, Federal University of Maranhão, São Luis, Maranhão, Brazil

    Surender Kumar Sharma

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Garg, B. (2018). 31P Solid-State NMR Spectroscopy of Adsorbed Phosphorous Probe Molecules: Acidity Characterization of Solid Acid Carbonaceous Materials for Catalytic Applications. In: Sharma, S. (eds) Handbook of Materials Characterization. Springer, Cham. https://doi.org/10.1007/978-3-319-92955-2_14

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