Abstract
Comparing to bulk silicon, silicon nanocrystals (Si NCs) possess particularly interesting properties and have further broadened applications in optics, microelectronics, photovoltaics, and other fields. In this chapter, novel fabrication process of Si NCs by using a plasma will be introduced firstly; next, some basic properties of resulted Si NCs, such as crystallinity, optical, and electrical properties, have been studied extensively; then, its application in organic/inorganic hybrid solar cells has been explored; structure design, device fabrication, and performance characterization of Si NC-based organic/inorganic hybrid solar cells have been described finally. In addition, effects of Si NCs on device performance are also discussed extensively.
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References
W.K. Leutwyler, S.L. Bürgi, H. Burgl, Semiconductor clusters, nanocrystals, and quantum dots. Science 271(5251), 933–937 (1996)
A.P. Alivisatos, Perspectives on the physical chemistry of semiconductor nanocrystals. J. Phys. Chem. 100(31), 13226–13239 (1996)
F.W. Wise, Lead salt quantum dots: the limit of strong quantum confinement. Acc. Chem. Res. 33(11), 773–780 (2000)
W.E. Buhro, V.L. Colvin, Semiconductor nanocrystals: shape matters. Nat. Mater. 2(3), 138–139 (2003)
D.V. Melnikov, J.R. Chelikowsky, Quantum confinement in phosphorus-doped silicon nanocrystals. Phys. Rev. Lett. 92(4), 046802 (2004)
I. Gur, N.A. Fromer, M.L. Geier, A.P. Alivisatos, Air-stable all-inorganic nanocrystal solar cells processed from solution. Science 310(5747), 462–465 (2005)
W.U. Huynh, J.J. Dittmer, A.P. Alivisatos, Hybrid nanorod-polymer solar cells. Science 295(5564), 2425–2427 (2002)
V. Colvin, M. Schlamp, A. Alivisatos, Light-emitting diodes made from cadmium selenide nanocrystals and a semiconducting polymer. Nature 370(6488), 354–357 (1994)
M. Schlamp, X. Peng, A. Alivisatos, Improved efficiencies in light emitting diodes made with CdSe (CdS) core/shell type nanocrystals and a semiconducting polymer. J. Appl. Phys. 82(11), 5837–5842 (1997)
O.E. Semonin, J.M. Luther, S. Choi, H.-Y. Chen, J. Gao, A.J. Nozik, M.C. Beard, Peak external photocurrent quantum efficiency exceeding 100% via MEG in a quantum dot solar cell. Science 334(6062), 1530–1533 (2011)
J.M. Luther, M. Law, M.C. Beard, Q. Song, M.O. Reese, R.J. Ellingson, A.J. Nozik, Schottky solar cells based on colloidal nanocrystal films. Nano Lett. 8(10), 3488–3492 (2008)
B.A. Ridley, B. Nivi, J.M. Jacobson, All-inorganic field effect transistors fabricated by printing. Science 286(5440), 746–749 (1999)
J. Ziegler, S. Xu, E. Kucur, F. Meister, M. Batentschuk, F. Gindele, T. Nann, Silica-coated InP/ZnS nanocrystals as converter material in white LEDs. Adv. Mater. 20(21), 4068–4073 (2008)
D. Huang, F. Liao, S. Molesa, D. Redinger, V. Subramanian, Plastic-compatible low resistance printable gold nanoparticle conductors for flexible electronics. J. Electrochem. Soc. 150(7), G412–G417 (2003)
R. Malakooti, L. Cademartiri, Y. Akçakir, S. Petrov, A. Migliori, G.A. Ozin, Shape-controlled Bi2S3 nanocrystals and their plasma polymerization into flexible films. Adv. Mater. 18(16), 2189–2194 (2006)
Y. Wang, N. Herron, Nanometer-sized semiconductor clusters: materials synthesis, quantum size effects, and photophysical properties. J. Phys. Chem. 95(2), 525–532 (1991)
M. Grätzel, Photoelectrochemical cells. Nature 414(6861), 338–344 (2001)
L. Mangolini, E. Thimsen, U. Kortshagen, High-yield plasma synthesis of luminescent silicon nanocrystals. Nano Lett. 5(4), 655–659 (2005)
N. Daldosso, G. Das, S. Larcheri, G. Mariotto, G. Dalba, L. Pavesi, A. Irrera, F. Priolo, F. Iacona, F. Rocca, Silicon nanocrystal formation in annealed silicon-rich silicon oxide films prepared by plasma enhanced chemical vapor deposition. J. Appl. Phys. 101(11), 113510 (2007)
R.K. Baldwin, K.A. Pettigrew, J.C. Garno, P.P. Power, G.-y. Liu, S.M. Kauzlarich, Room temperature solution synthesis of alkyl-capped tetrahedral shaped silicon nanocrystals. J. Am. Chem. Soc. 124(7), 1150–1151 (2002)
K. Littau, P. Szajowski, A. Muller, A. Kortan, L. Brus, A luminescent silicon nanocrystal colloid via a high-temperature aerosol reaction. J. Phys. Chem. 97(6), 1224–1230 (1993)
R.J. Walters, G.I. Bourianoff, H.A. Atwater, Field-effect electroluminescence in silicon nanocrystals. Nat. Mater. 4(2), 143–146 (2005)
Z. Ding, B.M. Quinn, S.K. Haram, L.E. Pell, B.A. Korgel, A.J. Bard, Electrochemistry and electrogenerated chemiluminescence from silicon nanocrystal quantum dots. Science 296(5571), 1293–1297 (2002)
M. Ostraat, J. De Blauwe, M. Green, L. Bell, M. Brongersma, J. Casperson, R. Flagan, H. Atwater, Synthesis and characterization of aerosol silicon nanocrystal nonvolatile floating-gate memory devices. Appl. Phys. Lett. 79(3), 433–435 (2001)
T. Lu, M. Alexe, R. Scholz, V. Talelaev, M. Zacharias, Multilevel charge storage in silicon nanocrystal multilayers. Appl. Phys. Lett. 87(20), 202110 (2005)
C.-Y. Liu, Z.C. Holman, U.R. Kortshagen, Hybrid solar cells from P3HT and silicon nanocrystals. Nano Lett. 9(1), 449–452 (2008)
G. Conibeer, M. Green, E.-C. Cho, D. König, Y.-H. Cho, T. Fangsuwannarak, G. Scardera, E. Pink, Y. Huang, T. Puzzer, Silicon quantum dot nanostructures for tandem photovoltaic cells. Thin Solid Films 516(20), 6748–6756 (2008)
M.C. Beard, K.P. Knutsen, P. Yu, J.M. Luther, Q. Song, W.K. Metzger, R.J. Ellingson, A.J. Nozik, Multiple exciton generation in colloidal silicon nanocrystals. Nano Lett. 7(8), 2506–2512 (2007)
K.-Y. Cheng, R. Anthony, U.R. Kortshagen, R.J. Holmes, High-efficiency silicon nanocrystal light-emitting devices. Nano Lett. 11(5), 1952–1956 (2011)
V. Svrcek, D. Mariotti, T. Nagai, Y. Shibata, I. Turkevych, M. Kondo, Photovoltaic applications of silicon nanocrystal based nanostructures induced by nanosecond laser fragmentation in liquid media. J. Phys. Chem. C 115(12), 5084–5093 (2011)
X. Pi, Q. Li, D. Li, D. Yang, Spin-coating silicon-quantum-dot ink to improve solar cell efficiency. Sol. Energy Mater. Sol. Cells 95(10), 2941–2945 (2011)
R. Gresback, T. Nozaki, K. Okazaki, Synthesis and oxidation of luminescent silicon nanocrystals from silicon tetrachloride by very high frequency nonthermal plasma. Nanotechnology 22(30), 305605 (2011)
N. Shirahata, T. Hasegawa, Y. Sakka, T. Tsuruoka, Size-tunable UV-luminescent silicon nanocrystals. Small 6(8), 915–921 (2010)
A. Stegner, R. Pereira, K. Klein, R. Lechner, R. Dietmueller, M. Brandt, M. Stutzmann, H. Wiggers, Electronic transport in phosphorus-doped silicon nanocrystal networks. Phys. Rev. Lett. 100(2), 026803 (2008)
V. Švrček, T. Sasaki, Y. Shimizu, N. Koshizaki, Blue luminescent silicon nanocrystals prepared by ns pulsed laser ablation in water. Appl. Phys. Lett. 89(21), 213113 (2006)
Y. Ding, R. Yamada, R. Gresback, S. Zhou, X. Pi, T. Nozaki, A parametric study of non-thermal plasma synthesis of silicon nanoparticles from a chlorinated precursor. J. Phys. D. Appl. Phys. 47(48), 485202 (2014)
Y. Ding, R. Gresback, Q. Liu, S. Zhou, X. Pi, T. Nozaki, Silicon nanocrystal conjugated polymer hybrid solar cells with improved performance. Nano Energy 9, 25–31 (2014)
Y. Ding, R. Gresback, R. Yamada, K. Okazaki, T. Nozaki, Hybrid silicon nanocrystal/poly (3-hexylthiophene-2, 5-diyl) solar cells from a chlorinated silicon precursor. Jpn. J. Appl. Phys. 52(11S), 11NM04 (2013)
L.M. Wheeler, N.R. Neale, T. Chen, U.R. Kortshagen, Hypervalent surface interactions for colloidal stability and doping of silicon nanocrystals. Nat. Commun. 4, 2197 (2013)
S. Rivillon, F. Amy, Y.J. Chabal, M.M. Frank, Gas phase chlorination of hydrogen-passivated silicon surfaces. Appl. Phys. Lett. 85, 2583 (2004)
M. Brodsky, M. Cardona, J. Cuomo, Infrared and Raman spectra of the silicon-hydrogen bonds in amorphous silicon prepared by glow discharge and sputtering. Phys. Rev. B 16(8), 3556 (1977)
Y. Ding, D. He, H. Shirai, Deposition of low dielectric constant SiOC films by using an atmospheric pressure microplasma jet. J. Phys. D. Appl. Phys. 42(12), 125503 (2009)
A. Grill, D.A. Neumayer, Structure of low dielectric constant to extreme low dielectric constant SiCOH films: Fourier transform infrared spectroscopy characterization. J. Appl. Phys. 94(10), 6697–6707 (2003)
N. Benissad, K. Aumaille, A. Granier, A. Goullet, Structure and properties of silicon oxide films deposited in a dual microwave-rf plasma reactor. Thin Solid Films 384(2), 230–235 (2001)
M. Wolkin, J. Jorne, P. Fauchet, G. Allan, C. Delerue, Electronic states and luminescence in porous silicon quantum dots: the role of oxygen. Phys. Rev. Lett. 82(1), 197 (1999)
Y. Ding, M. Sugaya, Q. Liu, S. Zhou, T. Nozaki, Oxygen passivation of silicon nanocrystals: influences on trap states, electron mobility, and hybrid solar cell performance. Nano Energy 10, 322–328 (2014)
G. Higashi, Y. Chabal, G. Trucks, K. Raghavachari, Ideal hydrogen termination of the Si (111) surface. Appl. Phys. Lett. 56(7), 656–658 (1990)
R. Gresback, Y. Murakami, Y. Ding, R. Yamada, K. Okazaki, T. Nozaki, Optical extinction spectra of silicon nanocrystals: size dependence upon the lowest direct transition. Langmuir 29(6), 1802–1807 (2013)
Y. Ding, S. Zhou, F.B. Juangsa, M. Sugaya, Y. Asano, X. Zhang, Y. Zhao, T. Nozaki, Optical, electrical, and photovoltaic properties of silicon nanoparticles with different crystallinities. Appl. Phys. Lett. 107(23), 233108 (2015)
D. Selmarten, M. Jones, G. Rumbles, P. Yu, J. Nedeljkovic, S. Shaheen, Quenching of semiconductor quantum dot photoluminescence by a π-conjugated polymer. J. Phys. Chem. B 109(33), 15927–15932 (2005)
M. Sykora, L. Mangolini, R.D. Schaller, U. Kortshagen, D. Jurbergs, V.I. Klimov, Size-dependent intrinsic radiative decay rates of silicon nanocrystals at large confinement energies. Phys. Rev. Lett. 100(6), 067401 (2008)
S. Godefroo, M. Hayne, M. Jivanescu, A. Stesmans, M. Zacharias, O. Lebedev, G. Van Tendeloo, V.V. Moshchalkov, Classification and control of the origin of photoluminescence from Si nanocrystals. Nat. Nanotechnol. 3(3), 174–178 (2008)
S.W. Lin, D.H. Chen, Synthesis of water-soluble blue photoluminescent silicon nanocrystals with oxide surface passivation. Small 5(1), 72–76 (2009)
Y. He, C. Yin, G. Cheng, L. Wang, X. Liu, G. Hu, The structure and properties of nanosize crystalline silicon films. J. Appl. Phys. 75(2), 797–803 (1994)
M. Wright, A. Uddin, Organic—inorganic hybrid solar cells: a comparative review. Sol. Energy Mater. Sol. Cells 107, 87–111 (2012)
J. Weickert, R.B. Dunbar, H.C. Hesse, W. Wiedemann, L. Schmidt-Mende, Nanostructured organic and hybrid solar cells. Adv. Mater. 23(16), 1810–1828 (2011)
A. Salant, M. Shalom, Z. Tachan, S. Buhbut, A. Zaban, U. Banin, Quantum rod-sensitized solar cell: nanocrystal shape effect on the photovoltaic properties. Nano Lett. 12(4), 2095–2100 (2012)
S. Ren, L.-Y. Chang, S.-K. Lim, J. Zhao, M. Smith, N. Zhao, V. Bulovic, M. Bawendi, S. Gradecak, Inorganic–organic hybrid solar cell: bridging quantum dots to conjugated polymer nanowires. Nano Lett. 11(9), 3998–4002 (2011)
Z. Yang, A. Janmohamed, X. Lan, F.P. García de Arquer, O. Voznyy, E. Yassitepe, G.-H. Kim, Z. Ning, X. Gong, R. Comin, Colloidal quantum dot photovoltaics enhanced by perovskite shelling. Nano Lett. 15(11), 7539–7543 (2015)
A. Abrusci, I.-K. Ding, M. Al-Hashimi, T. Segal-Peretz, M.D. McGehee, M. Heeney, G.L. Frey, H.J. Snaith, Facile infiltration of semiconducting polymer into mesoporous electrodes for hybrid solar cells. Energy Environ. Sci. 4(8), 3051–3058 (2011)
J. Von Behren, T. Van Buuren, M. Zacharias, E. Chimowitz, P. Fauchet, Quantum confinement in nanoscale silicon: the correlation of size with bandgap and luminescence. Solid State Commun. 105(5), 317–322 (1998)
H. Hoppe, N.S. Sariciftci, Morphology of polymer/fullerene bulk heterojunction solar cells. J. Mater. Chem. 16(1), 45–61 (2006)
Z. Zhou, L. Brus, R. Friesner, Electronic structure and luminescence of 1.1-and 1.4-nm silicon nanocrystals: oxide shell versus hydrogen passivation. Nano Lett. 3(2), 163–167 (2003)
M.C. Scharber, D. Muhlbacher, M. Koppe, P. Denk, C. Waldauf, A.J. Heeger, C.J. Brabec, Design rules for donors in bulk-heterojunction solar cells-towards 10% energy-conversion efficiency. Adv. Mat.-Deerfield Beach Then Weinheim 18(6), 789 (2006)
P. Vanlaeke, A. Swinnen, I. Haeldermans, G. Vanhoyland, T. Aernouts, D. Cheyns, C. Deibel, J. D’Haen, P. Heremans, J. Poortmans, P3HT/PCBM bulk heterojunction solar cells: relation between morphology and electro-optical characteristics. Sol. Energy Mater. Sol. Cells 90(14), 2150–2158 (2006)
H.-L. Yip, A.K.-Y. Jen, Recent advances in solution-processed interfacial materials for efficient and stable polymer solar cells. Energy Environ. Sci. 5(3), 5994–6011 (2012)
Y. Ding, R. Gresback, S. Zhou, X. Pi, T. Nozaki, Silicon nanocrystals synthesized using very high frequency non-thermal plasma and their application in photovoltaics. J. Phys. D. Appl. Phys. 48, 314011 (2015)
P.W. Blom, V.D. Mihailetchi, L.J.A. Koster, D.E. Markov, Device physics of polymer: fullerene bulk heterojunction solar cells. Adv. Mater. 19(12), 1551–1566 (2007)
P. Cheng, Y. Li, X. Zhan, Efficient ternary blend polymer solar cells with indene-C 60 bisadduct as an electron-cascade acceptor. Energy Environ. Sci. 7(6), 2005–2011 (2014)
Acknowledgments
The authors would thank all contributors to the publication, who have been important for this work. This work was financially supported by the National Natural Science Foundation of China (No. 61504069), the 111 Project of China (B16027), and Grant-in-Aid for Scientific Research (b) of Japan (No. 26289045).
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Ding, Y., Nozaki, T. (2018). Silicon Nanocrystal-Based Organic/Inorganic Hybrid Solar Cells. In: Ikhmayies, S. (eds) Advances in Silicon Solar Cells. Springer, Cham. https://doi.org/10.1007/978-3-319-69703-1_7
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