Abstract
The past few decades were marked by significant achievements in the field of chelating polymer ligands including those of different types of polymers and various chelating fragments. The chelating polymers classification adopted in this book includes, primarily, the method of preparation and structure of the polymer backbone and then its functionality. These ligands provide broad control over the metal chelate distribution and allow to preparing polymeric materials with enhanced stability, tunable solubility in aqueous and organic media, as well as interesting optical, magnetic, and fluorescent properties. This chapter analyzes the synthetic methodologies and spatial structures such chelating polymer polymers as linear, branched, cross-linked, grafted polymers, dendrimers, star and hyperbranched polymers, as well as liquid-crystalline polymers and polymeric films. Special attention is paid to the features of chelating polymer ligand preparation methods: (co)polymerization of chelating monomers, methods of controlled radical polymerization, click chemistry methods, method of cation polymerization, chemical oxidized polymerization, electropolymerization, photo- and microwave-assisted polymerization, cyclopolymerization, asymmetrical polymerization, post-polymerization modification, polycondensation reactions, «green» synthesis, and grafted polymerization. The problems and future prospects of such chelating polymer ligands are outlined.
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Dzhardimalieva, G.I., E. Uflyand, I. (2018). Polymer Chelating Ligands: Classification, Synthesis, Structure, and Chemical Transformations. In: Chemistry of Polymeric Metal Chelates. Springer Series in Materials Science, vol 257. Springer, Cham. https://doi.org/10.1007/978-3-319-56024-3_2
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