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Charge Carrier Generation, Recombination, and Extraction in Polymer–Fullerene Bulk Heterojunction Organic Solar Cells

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Book cover Elementary Processes in Organic Photovoltaics

Part of the book series: Advances in Polymer Science ((POLYMER,volume 272))

Abstract

In this chapter we review the basic principles of photocurrent generation in bulk heterojunction organic solar cells, discuss the loss channels limiting their efficiency, and present case studies of several polymer–fullerene blends. Using steady-state and transient, optical, and electrooptical techniques, we create a precise picture of the fundamental processes that ultimately govern solar cell efficiency.

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References

  1. Liu Y, Zhao J, Li Z, Mu C, Ma W, Hu H, Jiang K, Lin H, Ade H, Yan H (2014) Nat Commun 5:5293

    Article  CAS  Google Scholar 

  2. Heliatek (2013) http://www.heliatek.com/de/presse/pressemitteilungen/details/heliatek-erreicht-neuen-organischen-photovoltaik-weltrekord-mit-einer-effizienz-von-132

  3. Bakulin A, Rao A, Pavelyev V, van Loosdrecht P, Pshenichnikov M, Niedzialek D, Cornil J, Beljonne D, Friend RH (2012) Science 335:1340

    Article  CAS  Google Scholar 

  4. Grancini G, Maiuri M, Fazzi D, Petrozza A, Egelhaaf H-J, Brida D, Cerullo G, Lanzani G (2013) Nat Mater 12:29

    Article  CAS  Google Scholar 

  5. Gagorik AG, Mohin JW, Kowalewski T, Hutchison GR (2015) Adv Funct Mater 25:1996

    Article  CAS  Google Scholar 

  6. Burke TM, McGehee MD (2014) Adv Mater 26:1923

    Article  CAS  Google Scholar 

  7. Monahan NR, Williams KW, Kumar B, Nuckolls C, Zhu X-Y (2015) Phys Rev Lett 114:247003

    Article  Google Scholar 

  8. Poelking C, Tietze M, Elschner C, Olthof S, Hertel D, Baumeier B, Würthner F, Meerholz K, Leo K, Andrienko D (2015) Nat Mater 14:434

    Article  CAS  Google Scholar 

  9. Poelking C, Andrienko D (2015) J Am Chem Soc 137:6320

    Article  CAS  Google Scholar 

  10. Scharber MC, Koppe M, Gao J, Cordella F, Loi MA, Denk P, Morana M, Egelhaaf H-J, Forberich K, Dennler G, Gaudiana R, Waller D, Zhu Z, Shi X, Brabec CJ (2010) Adv Mater 22:367

    Article  CAS  Google Scholar 

  11. Vandewal K, Ma Z, Bergqvist J, Tang Z, Wang E, Henriksson P, Tvingstedt K, Andersson MR, Zhang F, Inganäs O (2012) Adv Funct Mater 22:3480

    Article  CAS  Google Scholar 

  12. Bartelt JA, Lam D, Burke TM, Sweetnam SM, McGehee MD (2015) Adv Energy Mater 5:1500577

    Google Scholar 

  13. Zhao J, Li Y, Lin H, Liu Y, Jiang K, Mu C, Ma T, Lin Lai JY, Hu H, Yu D, Yan H (2015) Energy Environ Sci 8:520

    Article  CAS  Google Scholar 

  14. Mikhnenko OV, Azimi H, Scharber M, Morana M, Blom PWM, Loi MA (2012) Energy Environ Sci 5:6960

    Article  CAS  Google Scholar 

  15. Foertig A, Kniepert J, Gluecker M, Brenner T, Dyakonov V, Neher D, Deibel C (2014) Adv Funct Mater 24:1306

    Article  CAS  Google Scholar 

  16. Kirchartz T, Pieters BE, Kirkpatrick J, Rau U, Nelson J (2011) Phys Rev B 83:115209

    Article  Google Scholar 

  17. Baranovskii SD (2014) Phys Status Solidi 251:487

    Article  CAS  Google Scholar 

  18. Bartesaghi D, Pérez IDC, Kniepert J, Roland S, Turbiez M, Neher D, Koster LJA (2015) Nat Commun 6:7083

    Article  CAS  Google Scholar 

  19. Würfel U, Neher D, Spies A, Albrecht S (2015) Nat Commun 6:6951

    Article  Google Scholar 

  20. Strobel T, Deibel C, Dyakonov V (2010) Phys Rev Lett 105:266602

    Article  Google Scholar 

  21. Wagenpfahl A, Rauh D, Binder M, Deibel C, Dyakonov V (2010) Phys Rev B 82:115306

    Article  Google Scholar 

  22. Tress W, Leo K, Riede M (2011) Adv Funct Mater 21:2140

    Article  CAS  Google Scholar 

  23. Rau U (2007) Phys Rev B 76:085303

    Article  Google Scholar 

  24. Vandewal K, Tvingstedt K, Gadisa A, Inganäs O, Manca JV (2009) Nat Mater 8:904

    Article  CAS  Google Scholar 

  25. Burke TM, Sweetnam S, Vandewal K, McGehee MD (2015) Adv Energy Mater 5

    Google Scholar 

  26. Deibel C, Strobel T, Dyakonov V (2010) Adv Mater 22:4097

    Article  CAS  Google Scholar 

  27. Shoaee S, Subramaniyan S, Xin H, Keiderling C, Tuladhar PS, Jamieson F, Jenekhe SA, Durrant JR (2013) Adv Funct Mater 23:3286

    Article  CAS  Google Scholar 

  28. Dimitrov SD, Durrant JR (2014) Chem Mater 26:616

    Article  CAS  Google Scholar 

  29. Scharber MC, Lungenschmied C, Egelhaaf H-J, Matt G, Bednorz M, Fromherz T, Gao J, Jarzab D, Loi MA (2011) Energy Environ Sci 4:5077

    Article  CAS  Google Scholar 

  30. Tvingstedt K, Vandewal K, Zhang F, Inganäs O (2010) J Phys Chem C 114:21824

    Article  CAS  Google Scholar 

  31. Inal S, Schubert M, Sellinger A, Neher D (2010) J Phys Chem Lett 1:982

    Article  CAS  Google Scholar 

  32. Kern J, Schwab S, Deibel C, Dyakonov V (2011) Phys Status Solidi—Rapid Res Lett 5:364

    Google Scholar 

  33. Vandewal K, Albrecht S, Hoke ET, Graham KR, Widmer J, Douglas JD, Schubert M, Mateker WR, Bloking JT, Burkhard GF, Sellinger A, Fréchet JMJ, Amassian A, Riede MK, McGehee MD, Neher D, Salleo A (2014) Nat Mater 13:63

    Article  CAS  Google Scholar 

  34. Hodgkiss JM, Campbell AR, Marsh RA, Rao A, Albert-Seifried S, Friend RH (2010) Phys Rev Lett 104:177701

    Article  Google Scholar 

  35. Howard IA, Mauer R, Meister M, Laquai F (2010) J Am Chem Soc 132:14866

    Article  CAS  Google Scholar 

  36. Howard IA, Laquai F (2010) Macromol Chem Phys 211:2063

    Article  CAS  Google Scholar 

  37. Langevin PMP (1903) Ann Chim Phys 28:433

    CAS  Google Scholar 

  38. Pivrikas A, Sariciftci NS, Juška G, Österbacka R (2007) Prog Photovolt Res Appl 15:677

    Article  CAS  Google Scholar 

  39. Mingebach M, Walter S, Dyakonov V, Deibel C (2012) Appl Phys Lett 100:193302

    Article  Google Scholar 

  40. Koster LJA, Mihailetchi VD, Ramaker R, Blom PWM (2005) Appl Phys Lett 86:123509

    Article  Google Scholar 

  41. Deibel C, Wagenpfahl A, Dyakonov V (2009) Phys Rev B 80:075203

    Article  Google Scholar 

  42. Koster LJA, Mihailetchi VD, Blom PWM (2006) Appl Phys Lett 88:052104

    Article  Google Scholar 

  43. Heiber MC, Baumbach C, Dyakonov V, Deibel C (2015) Phys Rev Lett 114:136602

    Article  Google Scholar 

  44. Shuttle CG, O’Regan B, Ballantyne AM, Nelson J, Bradley DDC, de Mello J, Durrant JR (2008) Appl Phys Lett 92:093311

    Article  Google Scholar 

  45. Foertig A, Baumann A, Rauh D, Dyakonov V, Deibel C (2009) Appl Phys Lett 95:052104

    Article  Google Scholar 

  46. Gorenflot J, Heiber MC, Baumann A, Lorrmann J, Gunz M, Kämpgen A, Dyakonov V, Deibel C (2014) J Appl Phys 115:144502

    Article  Google Scholar 

  47. Montanari I, Nogueira AF, Nelson J, Durrant JR, Winder C, Loi MA, Sariciftci NS, Brabec C (2002) Appl Phys Lett 81:3001

    Article  CAS  Google Scholar 

  48. Nelson J (2003) Phys Rev B 67:155209

    Article  Google Scholar 

  49. Deibel C, Rauh D, Foertig A (2013) Appl Phys Lett 103:043307

    Article  Google Scholar 

  50. Deledalle F, Kirchartz T, Vezie MS, Campoy-Quiles M, Shakya Tuladhar P, Nelson J, Durrant JR (2015) Phys Rev X 5:011032

    Google Scholar 

  51. Baranovski S (2006) Charge transport in disordered solids with applications in electronics, 1 edn. Wiley, 498 p. ISBN: 978-0-470-09504-1

    Google Scholar 

  52. He Z, Zhong C, Su S, Xu M, Wu H, Cao Y (2012) Nat Photonics 6:593

    Article  CAS  Google Scholar 

  53. Liang Y, Xu Z, Xia J, Tsai S-T, Wu Y, Li G, Ray C, Yu L (2010) Adv Mater 22, E135

    Article  CAS  Google Scholar 

  54. Chen W, Xu T, He F, Wang W, Wang C, Strzalka J, Liu Y, Wen J, Miller DJ, Chen J, Hong K, Yu L, Darling SB (2011) Nano Lett 11:3707

    Article  Google Scholar 

  55. Yan H, Collins BA, Gann E, Wang C, Ade H, McNeill CR (2012) ACS Nano 6:677

    Article  CAS  Google Scholar 

  56. Lou SJ, Szarko JM, Xu T, Yu L, Marks TJ, Chen LX (2011) J Am Chem Soc 133:20661

    Article  CAS  Google Scholar 

  57. Mort J, Chen I, Troup A, Morgan M, Knights J, Lujan R (1980) Phys Rev Lett 45:1348

    Article  CAS  Google Scholar 

  58. Kniepert J, Schubert M, Blakesley JC, Neher D (2011) J Phys Chem Lett 2:700

    Article  CAS  Google Scholar 

  59. Foster S, Deledalle F, Mitani A, Kimura T, Kim K-B, Okachi T, Kirchartz T, Oguma J, Miyake K, Durrant JR, Doi S, Nelson J (2014) Adv Energy Mater 4:1400311

    Google Scholar 

  60. Lange I, Kniepert J, Pingel P, Dumsch I, Allard S, Janietz S, Scherf U, Neher D (2013) J Phys Chem Lett 4:3865

    Article  CAS  Google Scholar 

  61. Kniepert J, Lange I, Heidbrink J, Kurpiers J, Brenner TJK, Koster LJA, Neher D (2015) J Phys Chem C 119:8310

    Article  CAS  Google Scholar 

  62. Hedley GJ, Ward AJ, Alekseev A, Howells CT, Martins ER, Serrano LA, Cooke G, Ruseckas A, Samuel IDW (2013) Nat Commun 4:2867

    Article  Google Scholar 

  63. Kniepert J, Lange I, van der Kaap NJ, Koster LJA, Neher D (2014) Adv Energy Mater 4:1301401

    Google Scholar 

  64. Peet J, Kim JY, Coates NE, Ma WL, Moses D, Heeger AJ, Bazan GC (2007) Nat Mater 6:497

    Article  CAS  Google Scholar 

  65. Peet J, Cho NS, Lee SK, Bazan GC (2008) Macromolecules 41:8655

    Article  CAS  Google Scholar 

  66. Jamieson FC, Agostinelli T, Azimi H, Nelson J, Durrant JR (2010) J Phys Chem Lett 1:3306

    Article  CAS  Google Scholar 

  67. Albrecht S, Schindler W, Kurpiers J, Kniepert J, Blakesley JC, Dumsch I, Allard S, Fostiropoulos K, Scherf U, Neher D (2012) J Phys Chem Lett 3:640

    Article  CAS  Google Scholar 

  68. Albrecht S, Vandewal K, Tumbleston JR, Fischer FSU, Douglas JD, Fréchet JMJ, Ludwigs S, Ade H, Salleo A, Neher D (2014) Adv Mater 26:2533

    Article  CAS  Google Scholar 

  69. Albrecht S, Janietz S, Schindler W, Frisch J, Kurpiers J, Kniepert J, Inal S, Pingel P, Fostiropoulos K, Koch N, Neher D (2012) J Am Chem Soc 134:14932

    Article  CAS  Google Scholar 

  70. Albrecht S, Tumbleston JR, Janietz S, Dumsch I, Allard S, Scherf U, Ade H, Neher D (2014) J Phys Chem Lett 5:1131

    Article  CAS  Google Scholar 

  71. Moet DJD, Lenes M, Morana M, Azimi H, Brabec CJ, Blom PWM (2010) Appl Phys Lett 96:213506

    Article  Google Scholar 

  72. Jarzab D, Cordella F, Gao J, Scharber M, Egelhaaf H-J, Loi MA (2011) Adv Energy Mater 1:604

    Article  CAS  Google Scholar 

  73. Hwang I-W, Cho S, Kim JY, Lee K, Coates NE, Moses D, Heeger AJ (2008) J Appl Phys 104:033706

    Article  Google Scholar 

  74. Rao A, Chow PCY, Gélinas S, Schlenker CW, Li C-Z, Yip H-L, Jen AK-Y, Ginger DS, Friend RH (2013) Nature 500:435

    Article  CAS  Google Scholar 

  75. Chow PCY, Gélinas S, Rao A, Friend RH (2014) J Am Chem Soc 136:3424

    Article  CAS  Google Scholar 

  76. Etzold F, Howard IA, Forler N, Cho DM, Meister M, Mangold H, Shu J, Hansen MR, Müllen K, Laquai F (2012) J Am Chem Soc 134:10569

    Article  CAS  Google Scholar 

  77. Etzold F, Howard IA, Forler N, Melnyk A, Andrienko D, Hansen MR, Laquai F (2015) Energy Environ Sci 8:1511

    Article  CAS  Google Scholar 

  78. Miller NC, Gysel R, Miller CE, Verploegen E, Beiley Z, Heeney M, McCulloch I, Bao Z, Toney MF, McGehee MD (2011) J Polym Sci Part B Polym Phys 49:499

    Article  CAS  Google Scholar 

  79. Miller NC, Cho E, Junk MJN, Gysel R, Risko C, Kim D, Sweetnam S, Miller CE, Richter LJ, Kline RJ, Heeney M, McCulloch I, Amassian A, Acevedo-Feliz D, Knox C, Hansen MR, Dudenko D, Chmelka BF, Toney MF, Brédas J-L, McGehee MD (2012) Adv Mater 24:6071

    Article  CAS  Google Scholar 

  80. Zusan A, Vandewal K, Allendorf B, Hansen NH, Pflaum J, Salleo A, Dyakonov V, Deibel C (2014) Adv Energy Mater 4:1400922

    Google Scholar 

  81. Veldman D, Ipek O, Meskers SCJ, Sweelssen J, Koetse MM, Veenstra SC, Kroon JM, van Bavel SS, Loos J, Janssen RAJ (2008) J Am Chem Soc 130:7721

    Article  CAS  Google Scholar 

  82. Deibel C, Strobel T, Dyakonov V (2009) Phys Rev Lett 103:036402

    Article  Google Scholar 

  83. Gehrig DW, Howard IA, Sweetnam S, Burke TM, McGehee MD, Laquai F (2015) Macromol Rapid Commun 36:1054

    Article  CAS  Google Scholar 

  84. Gehrig DW, Howard IA, Laquai F (2015) J Phys Chem C 119:13509

    Article  CAS  Google Scholar 

  85. Zusan A, Gieseking B, Zerson M, Dyakonov V, Magerle R, Deibel C (2015) Sci Rep 5:8286

    Article  CAS  Google Scholar 

  86. Collins BA, Li Z, Tumbleston JR, Gann E, McNeill CR, Ade H (2013) Adv Energy Mater 3:65

    Article  Google Scholar 

  87. Fischer FSU, Trefz D, Back J, Kayunkid N, Tornow B, Albrecht S, Yager KG, Singh G, Karim A, Neher D, Brinkmann M, Ludwigs S (2015) Adv Mater 27:1223

    Article  CAS  Google Scholar 

  88. Fischer FSU, Kayunkid N, Trefz D, Ludwigs S, Brinkmann M (2015) Macromolecules 48:3974

    Article  CAS  Google Scholar 

  89. Scharsich C, Fischer FSU, Wilma K, Hildner R, Ludwigs S, Köhler A (2015) J Polym Sci Part B Polym Phys 53:1416

    Article  CAS  Google Scholar 

  90. Poelking C, Daoulas K, Troisi A, Andrienko D (2014) P3HT revisited – from molecular scale to solar cell devices Adv Polym Sci 265:139–180

    Google Scholar 

  91. Poelking C, Andrienko D (2013) Macromolecules 46:8941

    Article  CAS  Google Scholar 

  92. Gemünden P, Poelking C, Kremer K, Daoulas K, Andrienko D (2015) Macromol Rapid Commun 36:1047

    Article  Google Scholar 

  93. Andrienko D (2014) Supramolecular materials for opto-electronics. Royal Society of Chemistry, Cambridge

    Google Scholar 

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Acknowledgments

This work was partially supported by Deutsche Forschungsgemeinschaft (DFG) under the Priority Program “Elementary Processes of Organic Photovoltaics” (SPP 1355), BMBF grant MESOMERIE (FKZ 13N10723) and MEDOS (FKZ 03EK3503B), and DFG program IRTG 1404. The project has received funding from the NMP-20-2014—“Widening Materials Models” program under grant agreement number 646259 (MOSTOPHOS). F. Laquai thanks the Max Planck Society for funding the Max Planck Research Group.

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Correspondence to Carsten Deibel .

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Laquai, F., Andrienko, D., Deibel, C., Neher, D. (2017). Charge Carrier Generation, Recombination, and Extraction in Polymer–Fullerene Bulk Heterojunction Organic Solar Cells. In: Leo, K. (eds) Elementary Processes in Organic Photovoltaics. Advances in Polymer Science, vol 272. Springer, Cham. https://doi.org/10.1007/978-3-319-28338-8_11

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