Abstract
Carbon Nanotubes (CNTs) have excellent properties such as high electrical and thermal conductivity and mechanical characteristic owing to their outstanding high specific surface area-to-volume ratio. However, there are restrictions for direct utilization of CNTs for processing and fabrication of devices because of their agglomeration tendency, difficulties in controlling morphology and leaching out problem from the composite material which lead to prevent its objective application with its inherent properties. The purpose of using functionalized CNTs (f-CNTs) to get homogeneous CNTs-based nano-composite which leads to enhancement of mechanical, chemical, electrical and thermal properties of composite materials. The surface area and pore size play an important role for removal and sensing of toxicants for environmental applications. Electrospinning is the most suitable technique for tuning the pore size and surface area of material as per requirement. The f-CNTs having various functional groups (hydroxyl, acetic, phenolic, polymer, etc.) improve their dispersion in matrix, water flux, scavenging of toxicants and attachment to the template for the fabrication of various significant devices such as filtration systems, sensors, high strength conducting fibers, etc. In this chapter, we are focusing on different techniques for the synthesis of f-CNTs, f-CNTs-based polymer nano-composites and fabrication of its nano-fibers using electrospun techniques for environmental remediation. The chapter concludes with the future prospect and challenges.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58
Baughman RH, Zhakidov AA, de Heer WA et al (2002) Carbon nanotubes:the route toward applications. Science 297(5582):787–792
Gupta N, Gupta SM, Sharma SK et al (2019) Carbon nanotubes: synthesis, properties and engineering applications. Carbon Lett 29:419–447
Kurwadkar S, Hoang TV, Malwade K et al (2019) Application of carbon nanotubes for removal of emerging contaminants of concern in engineered water and wastewater treatment systems. Nanotechnol Environ Eng 4:12
Venkataraman A, Amadi EV, Chen Y et al (2019) Carbon Nanotube Assembly and Integration for Applications. Nanoscale Res Lett 14:220
Ajayan PM (1999) Nanotubes from carbon. Chem Rev 99(7):1787–1800
Manzetti S, Gabriel JP et al (2019) Methods for dispersing carbon nanotubes for nanotechnology applications: liquid nanocrystals, suspensions, polyelectrolytes, colloids and organization control. Int Nano Lett 9:31–49
Tucknott R, Yaliraki SN (2002) Aggregation properties of carbon nanotubes at interfaces. Chem Phys 281:455–463
Le VT, Ngo CL, Le QT et al (2013) Surface modification and functionalization of carbon nanotube with some organic compounds. Adv Nat Sci Nanosci Nanotechnol 4:1–5
Ma P-C, Siddiqui N A, Marom G et al (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos Part A 41:1345–1367.
Jun LY, Mubarak NM, Yee MJ et al (2018) An overview of functionalized carbon nanomaterial for organic pollutant removal. J Ind Eng Chem 67(2018):175–186
Mottaghitalab V, Xi B, Gordon SGM et al (2006) Polyaniline fibres containing single walled carbon nanotubes: enhanced performance artificial muscles. Synth Met 156(11–13):796–803
Bianco A, Kostarelos K, Prato M (2005) Applications of carbon nanotubes in drug delivery. Curr Opin Chem Biol 9(6):674–679
Miao F, Shao C, Li X et al (2016) Electrospun carbon nanofibers/carbon nanotubes/polyaniline ternary composites with enhanced electrochemical performance for flexible solid-state supercapacitors. ACS Sustain Chem Eng 4(3):1689–1696
Kumar S, Pavelyev V, Mishra P et al (2018) A review on chemooresistive gas sensors based on carbon nanotubes: device and technology transformations. Sens Actuators A 2831:174–186
Du L, Quan X, Fan X et al (2019) Conductive CNT/nanofiber composite hollow fiber membranes with electrospun support layer for water purification. J Membr Sci. https://doi.org/10.1016/j.memsci.2019.117613
Sankararamakrishanan N, GuptaA VSR et al (2014) Enhanced arsenic removal at neutral pH using functionalized multiwalled carbon nanotubes. J Environ Chem Eng 2(2):802–810
Salehi E, MadaeniS S, Rajabi L et al (2012) Novel chitosan/poly(vinyl) alcohol thin adsorptive membranes modified with amino functionalized multi-walled carbon nanotubes for Cu(II) removal from water: preparation, characterization, adsorption kinetics and thermodynamics. Sep Purif Technol 89:309–319
Wongaree M, Chiarakorn S, Chuangchote S et al (2016) Photocatalytic performance of electrospun CNT/TiO2 nanofibers in a simulated air purifier under visible light irradiation. Environ Sci Pollut Res 23:21395–21406
Dror Y, Salalha W, Khalfin RL et al (2003) Carbon nanotubes embedded in oriented polymer nanofibers by electrospinning. Langmuir 19(17):7012–7020
Ge JJ, Hou H, Li Q et al (2004) Assembly of well-aligned multiwalled carbon nanotubes in confined polyacrylonitrile environments: electrospun composite nanofiber sheets. J Am Chem Soc 126(48):15754–15761
Sobolciak P, Tanvir A, Popelka A et al (2018) Electrospun copolyamide mats modified by functionalized multiwall carbon nanotubes. Polym Compos 40(S2):E1451–E1460
Suja PS, Reshmi CR, Sagitha P et al (2017) Electrospun nanofibrous membranes for water purification. Polym Rev 57(3):467–504
Wang J, Lin Y (2008) Functionalized carbon nanotubes and nanofibers for biosensing Applications. Trends Analyt Chem 27(7):619–626
Tahhan M, Truong VT, Spinks GM et al (2003) Carbon nanotube and polyaniline composite actuators. Smart Mater Struc 12:26–31
Zong X, Kim K, Fang D et al (2002) Structure and process relationship of electrospun bioabsorbable nanofiber membranes. Polymer 43:4403–4412
Yoon K, Hsiao BS, Chu B et al (2008) Functional nanofibers for environmental applications. J Mater Chem 18:5326–5334
Zhou Y, Fang Y, Ramasamy RP et al (2019) Non-covalent functionalized of carbon nanotubes for electrochemical biosensor development. Sensors 19(2):392
Kjellstrom T, Lodh M, McMichael T et al (2006) Air and water pollution: burden and strategies for control in disease control priorities in developing countries, 2nd ed, pp 817–832
Miller KA, Siscovick DS, Sheppard L et al (2007) Long-term exposure to air pollution and incidence of cardiovascular events in women. N Engl J Med 356:447–458
Brook RD, Rajagopalan S, Pope CA et al (2010) Particulate matter air pollution and cardiovascular disease. Circulation 121:2331–2378
Mannucci PM, Harari S, Martinelli I et al (2015) Effects on health of air pollution: a narrative review. Intern Emerg Med 10:657–662
Rahimpour A, Jahanshahi M, Khalili S et al (2012) Novel functionalized carbon nanotubes for improving the surface properties and performance of polyethersulfone (PES) membrane. Desalination 286:99–107
Dyke CA, James MT (2004) Covalent functionalization of single-walled carbon nanotubes for materials applications. J Phys Chem A 108(51):11151–11159
Liu L, Barber AH, Nuriel S et al (2005) Mechanical properties of functionalized single-walled carbon-nanotube/poly(vinyl alcohol) nanocomposites. Adv Func Mater 15:975–980
Wang C, Zhou G, Liu H et al (2006) Chemical functionalization of carbon nanotubes by carboxyl groups on stone-wales defects: a density functional theory study. J Phys Chem B 110(21):10266–10271
Li H, Cheng F, Duft AM et al (2005) Functionalization of single-walled carbon nanotubes with well-defined polystyrene by click coupling. J Am Chem Soc 127(41):14518–14524
Mickelson ET, Huffman CB, Rinzler AG et al (1998) Fluorination of single-wall carbon nanotubes. Chem Phys Lett 296:188–194
Yang A, X Wang T R, Lee S, et al (2007) Room temperature gas sensing properties of SnO2/multiwallcarbon-nanotube composite nanofibers. Appl Phys Lett 91:133110–133113
Liu L, Wang TX, Li JX et al (2003) Self-assembly of gold nanoparticles to carbon nanotubes using a thiol-terminated pyrene as interlinker. Chem Phys Lett 367(5–6):747–752
Khabashesku VN, Billups WE, Margrave JL et al (2002) Fluorination of single-wall carbon nanotubes and subsequent derivatization reactions. Acc Chem Res 35:1087–1095
Touhara H, Inahara J, Mizuno T et al (2002) Fluorination of cup-stacked carbon nanotubes, structure and properties. Fluorine Chem 114:181–188
Tagmatarchis N, Prato MJ (2004) Functionalization of carbon nanotubes via 1,3- dipolar cycloadditions. J Mater Chem 14:437–439
Dyachkova TP, Rukhov AV, Tkachev AG et al (2018) Functionalization of carbon nanotubes: methods, mechanisms and technological realization. Adv Mater Technol 02:018–041
Balasubramanian K, Burghard M (2005) Chemically functionalized carbon nanotubes. Small 1:180–192
Hu H, Zhao B, Hamon MA et al (2003) Sidewall functionalization of single-walled carbon nanotubes by addition of dichlorocarbene. J Am Chem Soc 125:14893–14900
Holzinger M, Steinmetz J, Samaille D et al (2004) [2+1] Cycloaddition for cross linking SWCNTs. Carbon 42:941–947
Kim KS, Bae DJ, Kim JR et al (2002) Modification of electronic structures of a carbon nanotube by hydrogen functionalization. Adv Mater 14:1818–1821
Holzinger M, Abraham J, Whelan P et al (2003) Functionalization of single walled carbon nanotubes with (R-) oxycarbonyl nitrenes. J Am Chem Soc 125:8566–8580
Sahoo NG, Cheng HKF, Li L (2011) Covalent functionalization of carbon nanotubes for ultimate interfacial adhesion to liquid crystalline polymer.Soft Matter 7:9505–9514.
Hariharasubramanian A, Ravichandran YD, Rajesh R et al (2014) Covalent functionalization of single-walled carbon nanotubes with anthracene by green chemical approach and their temperature dependent magnetic and electrical conductivity studies. Mater Chem Phys 143:838–844
Wang S, Richard L, Ben W et al (2008) Load-transfer in functionalized carbon nanotubes/polymer composites. Chem Phys Lett 457:371–375
Huang J, Gao M, Pan T et al (2014) Effective thermal conductivity of epoxy matrix filled with poly(ethyleneimine) functionalized carbon nanotubes. Compos Sci Technol 95:16–20
Hu A, Zhang T, Yuan S et al (2017) Functionalization of multi-walled carbon nanotubes with phenylenediamine for enhanced CO2 adsorption. Adsorption 23:3–85
Qian D, Dickeya EC, Andrews R et al (2000) Load transfer and deformation mechanisms in carbon nanotube-polystyrene composite. Appl Phys Lett 76:2868–2870
Feng JJ (2002) The stretching of an electrified non-Newtonian jet: a model for electrospinning. Phys Fluids 14:3912–3926
Yarin AL, Koombhongse S, Reneker DH et al (2001) Bending instability in electrospinning of nanofibers. J Appl Phys 89:3018–3026
Bognitzki M, Czado W, Frese T et al (2001) Nanostructured fibers via electrospinning. Adv Mater 13:70–72
Theron A, Zussman E, Yarin AL et al (2001) Electrostatic field-assisted alignment of electruspun nanofibres. Nanotechnology 12:384–390
Megelski S, Stephens JS, Rabolt JF et al (2002) Micro and nanostructured surface morphology on electrospun polymer fibre. Macromolecules 35:8456–8466
Tian X, He Y, Song Y et al (2020) Flexible cross-linked electrospun carbon nanofiber mats derived from pitch as dual-functional materials for supercapacitors. Energy Fuels. https://doi.org/10.1021/acs.energyfuels.0c02847
Kim J-S, Reneker DH (1999) Mechanical properties of composites using ultrafine electrospun fibers. Polym Compos 20:124–131
Koombhongse S, Liu WX, Reneker DH et al (2001) Flat polymer ribbons and other shapes by electrospinning. J Polym Sci Part B Polym Phys 39:2598–2606
Matthews J, Wnek GE, Simpson DG et al (2002) Electrospinning of collagen nanofibers. Biomacromol 3(2):232–238
Fong H, Chun I, Reneker DH et al (1999) Beaded nanofibers formed during electrospinning. Polymer 40:4585–4592
Breuer O, Sundararaj U (2004) Big returns from small fibers: a review of polymer/carbon nanotube composites. Polym Comp 25:630–645
Dersch R, Steinhart M, Boudriot U et al (2005) Nanoprocessing of polymers: applications in medicine, sensors, catalysis, photonics. Polym Adv Technol 16:276–282
Curran SA, Ajayan PA, Blau WJ et al (1998) A composite from poly(m-phenylenevinylene-co-2,5-dioctoxyp-phenylenevinylene) and carbon nanotubes: a novel material for molecular optoelectronics. Adv Mater 10:1091–1093
Bradley K, Gabriel JCP, Gruner G et al (2003) Flexible nanotube electronics. Nano Lett 3:1353–1355
Kymakis E, Amaratunga GAJ (2004) Optical properties of polymer-nanotube composites. Synth Met 142:161–167
Smith JG Jr, Connell JW, Delozier DM et al (2004) Space durable polymer/carbon nanotube films for electrostatic charge mitigation. Polymer 45:825–836
Wnek G, Carr ME, Simpson DG et al (2003) Electrospinning of nanofiber fibrinogen structures. Nano Lett 3:213–216
Joshi PP, Merchant SA, Wang Y et al (2005) Amperometric biosensors based on redox polymer–carbon nanotube–enzyme composites. Anal Chem 77:3183–3188
Safadi B, Andrews R, Grulke EA et al (2002) Multiwalled carbon nanotube polymer composites: synthesis and characterization of thin films. J Appl Polym Sci 84:2660–2669
Haggenmueller R, Gommans HH, Rinzler AG et al (2000) Aligned single-wall carbon nanotubes in composites by melt processing methods. Chem Phys Lett 330:219–225
Andrews R, Jacques D, Minot M et al (2002) Fabrication of carbon multiwall nanotube/polymer composites by shear mixing. Macromol Mater Eng 287:395–403
Jia Z, Wang Z, Xu C et al (1999) Study on poly(methyl methacrylate)/carbon nanotube composites. Mater Sci Eng A 271:395–400
Wu P K, Fitz-Gerald J, Pique A et al Deposition of nanotubes and nanotube composites using matrix-assisted pulsed laser evaporation. Mater Res Soc Proc 617:J2.3.1–6.
Kaur N, Kumar V, Dhakate SR et al (2016) Synthesis and characterization of multiwalled CNT–PAN based composite carbon nanofibers via electrospinning. Springerplus 5:483
Kaitao W, Mingbo G, Jian-jun W et al (2012) Functionalized carbon nanotube/polyacrylonitrile composite nanofibers: fabrication and properties. Polym Adv Technol 23. https://doi.org/10.1002/pat.1866
Ko F, Gogotsi Y, Ali A et al (2003) Electrospinning of continuous carbon nanotube-filled nanofiber yarns. Adv Mater 15:1161–1165
Ye H, Lam H, Titchenal N et al (2004) Reinforcement and rupture behavior of carbon nanotubes–polymer nanofibers. Appl Phys Lett 85:1775–1777
Liu J, Wang T, Uchida T et al (2005) Carbon nanotube core–polymer shell nanofibers. J Appl Polym Sci 96:1992–1995
Kim YA, Hayashi T, Fukai Y et al (2002) Effect of ball milling on morphology of cup-stacked carbon nanotubes. Chem Phys Lett 355:279–284
Yamamoto K, Akita S, Nakayama Y et al (1998) Orientation and purification of carbon nanotubes using ac electrophoresis. J Phys D Appl Phys 31:L34–L36
O’Connell MJ, Boul P, Ericson LM et al (2001) Reversible water-solubilization of single-walled nanotubes by polymer wrapping. Chem Phys Lett 342:265–271
Fane AG, Wang R, Hu MX et al (2015) Synthetic membranes for water purification: status and future. Angew Chem Int Ed 54:3368–3386
Xunda F, Tousley ME, Cowan MG et al (2014) Scalable fabrication of polymer membranes with vertically aligned 1 nm pores by magnetic field directed self assembly. ACS Nano 8:11977–11986
Ma H, Hsiao BS, Chu B et al (2013) Electrospun nanofibrous membrane for heavy metal ion adsorption. Curr Org Chem 17:1361–1370
Pereao OK, Bode-Aluko C, Ndayambaje G et al (2017) Electrospinning: polymer nanofibre adsorbent applications for metal ion removal. J Polym Environ 25(4):1175–1189
Nouri L, Ghodbane I, Hamdaoui O et al Batch sorption dynamics and equilibrium for the removal of cadmium ions from aqueous phase using wheat bran. J Hazard Mater 149(1):115–125.
Ogata T, Narita H, Tanaka M et al (2015) Adsorption behavior of rare earth elements on silica gel modified with diglycol amic acid. Hydrometallurgy 152:178–182
Shannon MA, Bohn PW, Elimelech M et al (2008) Science and technology for water purification in the coming decades. Nature 452:301–310
Wang EN, Karnik R (2012) Water desalination: graphene cleans up water. Nat Nanotechnol 7:552–554
Yan K-K, Jiao L, Lin S et al (2018) Superhydrophobic electrospun nanofiber membrane coated by carbon nanotubes network for membrane distillation. Desalination 437:26–33
Du L, Quan X, Fan X et al (2020) Conductive CNT/nanofiber composite hollow fiber membranes with electrospun support layer for water purification.J Membr Sci 596:117613. https://doi.org/10.1016/j.memsci.2019.117613.
Ahmed FE, Lalia BS, Hashaikeh R et al (2015) A review on electrospinning for membrane fabrication: challenges and applications. Desalination 356:15–30
Wang X, Hsiao BS (2016) Electrospun nanofiber membranes. Curr Opin Chem Eng 12:62–81
Wu J, Wang N, Wang L et al (2012) Electrospun porous structure fibrous film with high oil adsorption capacity. ACS Appl Mater Interfaces 4(6):3207–3212
Jiang Z, Tijing LD, Amarjargal A et al (2015) Removal of oil from water using magnetic bicomponent composite nanofibers fabricated by electrospinning. Compos B Eng 77:311–318
Ye T, Durkin DP, Maocong Hu et al (2016) Enhancement of nitrite reduction kinetics on electrospun Pd-carbon nanomaterial catalysts for water purification. ACS Appl Mater Interf 8:17739–17744
Rasheed T, Bilal M, Nabeel F et al (2019) Environmentally-related contaminants of high concern: potential sources and analytical modalities for detection, quantification, and treatment. Environ Int 122:52–66
Almasian A, Jalali M, Chizari L et al (2017) Surfactant grafted PDA-PAN nanofiber: optimization of synthesis, characterization and oil absorption property. Chem Eng J 326:1232–1241
Katheresan V, Kansedo J, Lau SY et al (2018) Efficiency of various recent waste water dye removal methods: a review. J Environ Chem Eng 6(4):4676–4697
Malwal D, Gopinath P (2016) Fabrication and applications of ceramic nanofibers in water remediation: a review. Crit Rev Environ Sci Technol 46(5):500–534
Gopal P, Mira P, Hak-Yong K et al (2015) Electrospun ZnO hybrid nanofibers for photo degradation of wastewater containing organic dyes: a review. J Ind Eng Chem 21:26–35
Peng C, Zhang J, Xiong Z et al (2015) Fabrication of porous hollow g-Al2O3 nanofibers by facile electrospinning and its application for water remediation. Microporous Mesoporous Mater 215:133–142
Gupta VK, Suhas (2009) Application of low-cost adsorbents for dye removal : a review. J Environ Manag 90(8):2313–2342
Wei L, Bingnan M, Yiqi Y et al (2019) Feasibility of industrial-scale treatment of dye wastewater via bio-adsorption technology. Bioresour Technol 277:157–170
Simate GS, Iyuke SE, Ndlovu S et al (2012) Human Health Effects of Residual Carbon Nanotubes and Traditional Water Treatment Chemicals in Drinking Water. Environ Int 39(1):38–49
Sun Y, Wang Y, Dong Q et al (2014) Electrolysis removal of methyl orange dye from water by electrospun activated carbon fibers modified with carbon nanotubes. Chem Eng J 253(1):73–77
Jadhav AH (2015) Preparation, characterization, and kinetic study of end opened carbon nanotubes incorporated polyacrylonitrile electrospun nanofibers for the adsorption of pyrene from aqueous solution. Chem Eng J 259:348–356
Dai Y (2016) enhanced performance of immobilized laccase in electrospun fibrous membranes by carbon nanotubes modification and its application for bisphenol A removal from water. J Hazard Mater 317:485–493
Peter AT, Vargo JD, Rupasinghe TP et al (2016) Synthesis, optimization, and performance demonstration of electrospun carbon nanofiber-carbon nanotubes composite sorbents for point of use water treatment. ACS Appl Mater Interfaces 8(18):11431–11440
Zhu H, Qiu S, Jiang W et al (2011) Evaluation of electrospun polyvinyl chloride/polystyrene fibers as sorbent materials for oil spill cleanup. Environ Sci Technol 45(10):4527–4531
Xianfeng W, Jianyong Y, Sun G et al (2016) Electrospun nanofibrous materials: a versatile medium for effective oil/water separation. Mater Today 19(7):403–414
Jianliang X, Weiyang L, Yihu S et al (2018) Graphene/nanofiber aerogels: performance regulation towards multiple applications in dye adsorption and oil/water separation. Chem Eng J 338:202–210
Dorneanu PP, Cojocaru C, Olaru N et al (2017) Electrospun PVDF fibers and a novel PVDF/CoFe2O4 fibrous composite as nanostructured sorbent materials for oil spill cleanup. Appl Surf Sci 424:389–396
Dorneanu PP, Cojocaru C, Samoila P et al (2018) Novel fibrous composites based on electrospun PSF and PVDF ultrathin fibers reinforced with inorganic nanoparticles: evaluation as oil spill sorbents. Polym Adv Technol 29(5):1435–1446
Jin L, Hu B, Kuddannaya S et al (2018) A three-dimensional carbon nanotube nanofiber composite foam for selective adsorption of oils and organic liquids. Polym Compos 39(S1):E271–E277
Bandegi A, Moghbeli MR (2018) Effect of solvent quality and humidity on the porous formation and oil absorbency of SAN electrospun nanofibers. J Appl Polym Sci 135(1):45586
Khalaf DM, Elkatlawy SM, Sakr A-HA et al (2020) Enhanced oil/water separation via electrospun poly(acrylonitrile-co-vinyl acetate)/single-wall carbon nanotubes fibrous nanocomposite membrane. J Appl Polym Sci 137:49033
Tian L, Zhang C, He X et al (2017) Novel reusable porous polyimide fibers for hot-oil adsorption. J Hazard Mater 340:67–76
Wang K, Zhang T C, Wei B et al (2020) Durable CNTs reinforced porous electrospun superhydrophobic membrane for efficient gravity driven oil/water separation. Colloids Surf A Physicochem Eng Aspects. https://doi.org/10.1016/j.colsurfa.2020.125342
Li P, Wang C, Zhang Y et al (2014) Air filtration in the free molecular flow regime: a review of high-efficiency particulate air filters based on carbon nanotubes. Small 10:4543–4561
Givehchi R, Tan Z (2015) The effect of capillary force on airborne nanoparticle filtration. J Aerosol Sci 83:12–24
Park H-S, Park YO (2005) Filtration properties of electrospun ultrafine fiber webs. Korean J Chem Eng 22:165–172
Kosmider K, Scott J (2002) Polymeric nanofibres exhibit an enhanced air filtration performance. Filtr Sep 39:20–22.
Sridhar R, Lakshminarayanan R, Madhaiyan K et al (2015) Electrosprayed nanoparticles and electrospun nanofibers based on natural materials: applications in tissue regeneration, drug delivery and pharmaceuticals. Chem Soc Rev 44:790–814
Lu P, Ding B (2008) Applications of electrospun fibers. Recent Pat Nanotechnol 2:169–182
Bhardwaj N, Kundu SC (2010) Electrospinning: a fascinating fiber fabrication technique. Biotechnol Adv 28:325–347
Qin XH, Wang SY (2006) Filtration properties of electrospinning nanofibers. J Appl Polym Sci 102:1285–1290
Matulevicius J, Kliucininkas L, Martuzevicius D et al (2014) Design and characterization of electrospun polyamide nanofiber media for air filtration applications. J Nanomater. https://doi.org/10.1155/2014/859656
Vitchuli N, Shi Q, Nowak J et al (2010) Electrospun ultrathin nylon fibers for protective applications. J Appl Polym Sci 116:2181–2187
Li L, Frey MW, GreenT B et al (2006) Modification of air filter media with nylon-6 nanofibers. J Eng Fibers Fabr 1:1–22
Desai K, Kit K, Li J et al (2009) Nanofibrous chitosan non-wovens for filtration applications. Polymer 50:3661–3669
Chattopadhyay S, Hatton TA, Rutledge GC et al (2016) Aerosol filtration using electrospun cellulose acetate fibers. J Mater Sci 51:204–217
Babu DJ, Puthusseri D, Kühl FG et al (2018) SO2 gas adsorption on carbon nanomaterials: a comparative study. Beilstein J Nanotechnol 9:1782–1792
Babaei M, Anbia M, Kazemipour M (2019) study of the effect of functionalization of carbon naotubes on gas separation. Braz J Chem Eng 36:1613–1620
Babaei M, Anbia M, Kazemipour M (2016) Synthesis of zeolite/carbon nanotube composite for gas separation. Can J Chem. https://doi.org/10.1139/cjc-2016-0305
Li Y, Zhu Z, Yu J et al (2015) Carbon nanotubes enhanced fluorinated polyurethane macroporous membranes for waterproof and breathable application. ACS Appl Mater Interf 7:13538–13546
Iqbal N, Wang X, Yu J et al (2017) Robust and flexible carbon nanofibers doped with amine functionalized carbon nanotubes for efficient CO2 capture. Adv Sustain Syst 1:1600028
Zhang X, Yin J, Yoon J et al (2014) Recent advances in development of chiral fluorescent and colorimetric sensors. Chem Rev 114:4918–4959
Zhou Y, Zhang JF, Yoon J et al (2014) Fluorescence and colorimetric chemosensors for fluoride-ion detection. Chem Rev 114:5511–5571
Chen X, Zhou G, Peng X et al (2012) Biosensors and chemosensors based on the optical responses of polydiacetylenes. Chem Soc Rev 41:4610–4630
Kim HN, Ren WX, Kim JS et al (2012) Fluorescent and colorimetric sensors for detection of lead, cadmium, and mercury ions. Chem Soc Rev 41:3210–3244
Ko SK, Chen X, Yoon J et al (2011) Zebrafish as a good vertebrate model for molecular imaging using fluorescent probes. Chem Soc Rev 40:2120–2130
Bencic-Nagale S, Sternfeld T, Walt DR et al (2006) Microbead chemical switches: an approach to detection of reactive organophosphate chemical warfare agent vapors. J Am Chem Soc 128:5041–5048
Diaz de Grenu B, Moreno D, Torroba T et al (2014) Fluorescent discrimination between traces of chemical warfare agents and their mimics. J Am Chem Soc 136:4125–4128
Lei Z, Yang Y (2014) A concise colorimetric and fluorimetric probe for sarin related threats designed via the covalent-assembly approach. J Am Chem Soc 136:6594–6597
Ishida M, Kim P, Choi J et al (2013) Benzimidazole-embedded N-fused aza-indacenes: synthesis and deprotonation-assisted optical detection of carbon dioxide. Chem Commun 49:6950–6952
Tomas-Barbera FA, Gil MI, Cremin P et al (2001) HPLC−DAD−ESIMS analysis of phenolic compounds in nectarines, peaches, and plums. J Agric Food Chem 49:4748–4760
Ashley DL, Bonin MA, Cardinali FL et al (1992) Determining volatile organic compounds in human blood from a large sample population by using purge and trap gas chromatography/mass spectrometry. Anal Chem 64:1021–1029
Han L, Andrady AL, Ensor DS et al (2013) Chemical sensing using electrospun polymer/carbon nanotube composite nanofibers with printed-on electrodes. Sensors Actuators B 186:52–55
Zhang P, Zhao X, Zhang X et al (2014) Electrospun doping of carbon nanotubes and platinum nanoparticles into the β-phase polyvinylidene difluoride nanofibrous membrane for biosensor and catalysis applications. ACS Appl Mater Interf 6:7563–7571
Gusmao AP, Rosenberger AG, Muniz EC et al (2021) Characterization of microfibers of carbon nanotubes obtained by electrospinning for use in electrochemical sensor. J Polym Environ 29:1551–1565
Mercante LA, Pavinatto A, Iwaki Le EO et al (2015) Electrospun polyamide 6/poly(allylamine hydrochloride) nanofibers functionalized with carbon nanotubes for electrochemical detection of dopamine. ACS Appl Mater Interf https://doi.org/10.1021/am508709c
Khuspe GD, Navale ST, Bandgar DK et al (2014) SnO2 nanoparticles-modified polyaniline films as highly selective, sensitive, reproducible and stable ammonia sensors. Electron Mater Lett 10:191–197
Mehrani Z, Ebrahimzadeh H, Asgharinezhad AA et al (2019) Determination of copper in food and water sources using poly m-phenylenediamine/CNT electrospun nanofiber. Microchem J 149:103975. https://doi.org/10.1016/j.microc.2019.103975
Ouyang Z, Li J, Wang J et al (2013) Fabrication, characterization and sensor application of electrospun polyurethane nanofibers filled with carbon nanotubes and silver nanoparticles. J Mater Chem B 1:2415–2424
Lala N, Thavasi V, Ramakrishna S et al (2009) Preparation of surface adsorbed and impregnated multiwalled carbon nanotube/nylon-6 nanofiber composites and investigation of their gas sensing ability. Sensors 9:86–101
Wang Z-G, Wang Y, Xu H et al (2009) Carbon nanotube-filled nanofibrous membranes electrospun from poly(acrylonitrile-co-acrylic acid for glucose biosensor. J Phys Chem C 113, 2955–2960
Patil PT, Anwane RS, Kondawar SB et al (2015) Development of electrospun polyaniline/ZnO composite nanofibers for LPG sensing. Proc Mater Sci 10:195–204
Acknowledgements
We would like to thank Director, CFEES for his constant support and encouragement during the work.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Bharti, Kumar, P., Rai, P.K. (2021). Functionalized Carbon Nanotubes-Based Electrospun Nano-Fiber Composite and Its Applications for Environmental Remediation. In: Tiwari, S.K., Sharma, K., Sharma, V., Kumar, V. (eds) Electrospun Nanofibers. Springer Series on Polymer and Composite Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-79979-3_13
Download citation
DOI: https://doi.org/10.1007/978-3-030-79979-3_13
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-79978-6
Online ISBN: 978-3-030-79979-3
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)