Skip to main content

Hierarchically Ordered Microporous Surfaces

  • Chapter
  • First Online:
Breath Figures

Abstract

Hierarchically ordered microporous surfaces are addressed. Hierarchically structured honeycomb films obtained by self-assembly of block copolymers are surveyed. Block copolymers in which one of the blocks could be selectively removed give rise to hierarchical micro- and nanoporous films. Demixing polymer blend solutions performed on structured substrates results in multiscale-ordered surfaces. Formation of hierarchically ordered breath-figures topographies on patterned substrates is reviewed. Combining the breath-figures approach with photo-crosslinking strategies gives rise to hierarchical microporous surfaces. Combination of electrospinning or electrospraying and breath figures also results in hierarchical micro-scaled topographies. Hierarchically ordered microporous surfaces emerge from combination of the breath-figures method and nanoparticles. Characterization of hierarchical, multi-scale surfaces with using transmission electron microscopy combined with small and ultra-small angle scattering (SAXS, UAXS) is reviewed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 16.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Hayakawa, T., and S. Horiuchi. 2003. From angstroms to micrometers: Self-organized hierarchical structure within a polymer film. Angewandte Chemie International Edition 42 (20): 2285–2289.

    Article  CAS  Google Scholar 

  2. Wong, K.H., et al. 2007. Honeycomb structured porous films from amphiphilic block copolymers prepared via RAFT polymerization. Polymer 48 (17): 4950–4965.

    Article  CAS  Google Scholar 

  3. Escalé, P., et al. 2010. Hierarchical structures based on self-assembled diblock copolymers within honeycomb micro-structured porous films. Soft Matter 6 (14): 3202–3210.

    Article  Google Scholar 

  4. ———. 2016. When block copolymer self-assembly in hierarchically ordered honeycomb films depicts the breath figure process. Soft Matter 12 (3): 790–797.

    Article  Google Scholar 

  5. Bertrand, A., et al. 2016. Hierarchically porous bio-inspired films prepared by combining “breath figure” templating and selectively degradable block copolymer directed self-assembly. Chemical Communications 52 (61): 9562–9565.

    Article  CAS  Google Scholar 

  6. Ji, E., et al. 2017. Hierarchical honeycomb-structured films by directed self-assembly in “breath figure” templating of ionizable “clicked” PH3T-b-PMMA diblock copolymers: An ionic group/counter-ion effect on porous polymer film morphology. Chemical Communications 53 (11): 1876–1879.

    Article  CAS  Google Scholar 

  7. ———. 2017. Self-assembly of Ionizable “clicked” P3HT-b-PMMA copolymers: Ionic bonding group/Counterion effects on morphology. Macromolecules 50 (1): 235–243.

    Article  CAS  Google Scholar 

  8. Muñoz-Bonilla, A., et al. 2009. Self-organized hierarchical structures in polymer surfaces: Self-assembled nanostructures within breath figures. Langmuir 25 (11): 6493–6499.

    Article  Google Scholar 

  9. De León, A.S., et al. 2012. Hierarchically structured multifunctional porous interfaces through water templated self-assembly of ternary systems. Langmuir 28 (25): 9778–9787.

    Article  Google Scholar 

  10. ———. 2013. Fabrication of structured porous films by breath figures and phase separation processes: Tuning the chemistry and morphology inside the pores using click chemistry. ACS Applied Materials & Interfaces 5 (9): 3943–3951.

    Article  Google Scholar 

  11. Boker, A., et al. 2004. Hierarchical nanoparticle assemblies formed by decorating breath figures. Nature Materials 3 (5): 302–306.

    Article  Google Scholar 

  12. Samanta, S., et al. 2011. Multifunctional porous poly(vinylidene fluoride)-graft-poly(butyl methacrylate) with good Li+ ion conductivity. Macromolecular Chemistry and Physics 212 (2): 134–149.

    Article  CAS  Google Scholar 

  13. Ma, H., et al. 2011. Fabrication of freestanding honeycomb films with through-pore structures via air/water interfacial self-assembly. Chemical Communications 47 (4): 1154–1156.

    Article  CAS  Google Scholar 

  14. Deleuze, C., et al. 2012. Hierarchically structured hybrid honeycomb films via micro to nanosized building blocks. Soft Matter 8 (33): 8559–8562.

    Article  CAS  Google Scholar 

  15. Saito, Y., M. Shimomura, and H. Yabu. 2014. Breath figures of nanoscale bricks: A universal method for creating hierarchic porous materials from inorganic nanoparticles stabilized with mussel-inspired copolymers. Macromolecular Rapid Communications 35 (20): 1763–1769.

    Article  CAS  Google Scholar 

  16. ———. 2013. Dispersion of Al 2 O 3 nanoparticles stabilized with mussel-inspired amphiphilic copolymers in organic solvents and formation of hierarchical porous films by the breath figure technique. Chemical Communications 49 (54): 6081–6083.

    Article  CAS  Google Scholar 

  17. Geldhauser, T., et al. 2009. Influence of the relative humidity on the demixing of polymer blends on prepatterned substrates. Macromolecules 43 (2): 1124–1128.

    Article  Google Scholar 

  18. Cui, L., et al. 2005. Ordered porous polymer films via phase separation in humidity environment. Polymer 46 (14): 5334–5340.

    Article  CAS  Google Scholar 

  19. Hecht, U., C.M. Schilz, and M. Stratmann. 1998. Influence of relative humidity during film formation processes on the structure of ultrathin polymeric films. Langmuir 14 (23): 6743–6748.

    Article  CAS  Google Scholar 

  20. Madej, W., et al. 2008. Breath figures in polymer and polymer blend films spin-coated in dry and humid ambience. Langmuir 24 (7): 3517–3524.

    Article  CAS  Google Scholar 

  21. Ge, W., and C. Lu. 2011. Hierarchical honeycomb patterns with tunable microstructures: Controllable fabrication and application as replication templates. Soft Matter 7 (6): 2790–2796.

    Article  CAS  Google Scholar 

  22. Connal, L.A., and G.G. Qiao. 2006. Preparation of porous poly(dimethylsiloxane)-based honeycomb materials with hierarchal surface features and their use as soft-lithography templates. Advanced Materials 18 (22): 3024–3028.

    Article  CAS  Google Scholar 

  23. Connal, L.A., et al. 2008. Fabrication of reversibly crosslinkable, 3-dimensionally conformal polymeric microstructures. Advanced Functional Materials 18 (20): 3315–3322.

    Article  CAS  Google Scholar 

  24. Connal, L.A., and G.G. Qiao. 2007. Honeycomb coated particles: Porous doughnuts, golf balls and hollow porous pockets. Soft Matter 3 (7): 837–839.

    Article  CAS  Google Scholar 

  25. Ding, J., et al. 2012. Constructing honeycomb micropatterns on nonplanar substrates with high glass transition temperature polymers. Journal of Colloid and Interface Science 380: 99–104.

    Article  CAS  Google Scholar 

  26. Zhang, Z., et al. 2012. Influence of polymer elasticity on the formation of non-cracking honeycomb films. Advanced Materials 24 (31): 4327–4330.

    Article  CAS  Google Scholar 

  27. Greiser, C., S. Ebert, and W.A. Goedel. 2008. Using breath figure patterns on structured substrates for the preparation of hierarchically structured microsieves. Langmuir 24 (3): 617–620.

    Article  CAS  Google Scholar 

  28. Kojima, M., et al. 2010. Photo-patterning of honeycomb films prepared from amphiphilic copolymer containing photochromic spiropyran. Chemical Communications 46 (22): 3970–3972.

    Article  CAS  Google Scholar 

  29. Angiolini, L., et al. 2008. Chiroptical switching based on Photoinduced proton transfer between Homopolymers bearing side-chain Spiropyran and Azopyridine moieties. Macromolecular Chemistry and Physics 209 (19): 2049–2060.

    Article  CAS  Google Scholar 

  30. Kwak, G., et al. 2006. Nanoporous, honeycomb-structured network fibers spun from semiflexible, ultrahigh molecular weight, disubstituted aromatic polyacetylenes: Superhierarchical structure and unique optical anisotropy. Chemistry of Materials 18 (23): 5537–5542.

    Article  CAS  Google Scholar 

  31. Zheng, J., et al. 2012. Construction of hierarchical structures by electrospinning or electrospraying. Polymer 53 (2): 546–554.

    Article  CAS  Google Scholar 

  32. Fashandi, H., and M. Karimi. 2012. Pore formation in polystyrene fiber by superimposing temperature and relative humidity of electrospinning atmosphere. Polymer 53 (25): 5832–5849.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Rodríguez-Hernández, J., Bormashenko, E. (2020). Hierarchically Ordered Microporous Surfaces. In: Breath Figures . Springer, Cham. https://doi.org/10.1007/978-3-030-51136-4_6

Download citation

Publish with us

Policies and ethics