Abstract
Hierarchically ordered microporous surfaces are addressed. Hierarchically structured honeycomb films obtained by self-assembly of block copolymers are surveyed. Block copolymers in which one of the blocks could be selectively removed give rise to hierarchical micro- and nanoporous films. Demixing polymer blend solutions performed on structured substrates results in multiscale-ordered surfaces. Formation of hierarchically ordered breath-figures topographies on patterned substrates is reviewed. Combining the breath-figures approach with photo-crosslinking strategies gives rise to hierarchical microporous surfaces. Combination of electrospinning or electrospraying and breath figures also results in hierarchical micro-scaled topographies. Hierarchically ordered microporous surfaces emerge from combination of the breath-figures method and nanoparticles. Characterization of hierarchical, multi-scale surfaces with using transmission electron microscopy combined with small and ultra-small angle scattering (SAXS, UAXS) is reviewed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Hayakawa, T., and S. Horiuchi. 2003. From angstroms to micrometers: Self-organized hierarchical structure within a polymer film. Angewandte Chemie International Edition 42 (20): 2285–2289.
Wong, K.H., et al. 2007. Honeycomb structured porous films from amphiphilic block copolymers prepared via RAFT polymerization. Polymer 48 (17): 4950–4965.
Escalé, P., et al. 2010. Hierarchical structures based on self-assembled diblock copolymers within honeycomb micro-structured porous films. Soft Matter 6 (14): 3202–3210.
———. 2016. When block copolymer self-assembly in hierarchically ordered honeycomb films depicts the breath figure process. Soft Matter 12 (3): 790–797.
Bertrand, A., et al. 2016. Hierarchically porous bio-inspired films prepared by combining “breath figure” templating and selectively degradable block copolymer directed self-assembly. Chemical Communications 52 (61): 9562–9565.
Ji, E., et al. 2017. Hierarchical honeycomb-structured films by directed self-assembly in “breath figure” templating of ionizable “clicked” PH3T-b-PMMA diblock copolymers: An ionic group/counter-ion effect on porous polymer film morphology. Chemical Communications 53 (11): 1876–1879.
———. 2017. Self-assembly of Ionizable “clicked” P3HT-b-PMMA copolymers: Ionic bonding group/Counterion effects on morphology. Macromolecules 50 (1): 235–243.
Muñoz-Bonilla, A., et al. 2009. Self-organized hierarchical structures in polymer surfaces: Self-assembled nanostructures within breath figures. Langmuir 25 (11): 6493–6499.
De León, A.S., et al. 2012. Hierarchically structured multifunctional porous interfaces through water templated self-assembly of ternary systems. Langmuir 28 (25): 9778–9787.
———. 2013. Fabrication of structured porous films by breath figures and phase separation processes: Tuning the chemistry and morphology inside the pores using click chemistry. ACS Applied Materials & Interfaces 5 (9): 3943–3951.
Boker, A., et al. 2004. Hierarchical nanoparticle assemblies formed by decorating breath figures. Nature Materials 3 (5): 302–306.
Samanta, S., et al. 2011. Multifunctional porous poly(vinylidene fluoride)-graft-poly(butyl methacrylate) with good Li+ ion conductivity. Macromolecular Chemistry and Physics 212 (2): 134–149.
Ma, H., et al. 2011. Fabrication of freestanding honeycomb films with through-pore structures via air/water interfacial self-assembly. Chemical Communications 47 (4): 1154–1156.
Deleuze, C., et al. 2012. Hierarchically structured hybrid honeycomb films via micro to nanosized building blocks. Soft Matter 8 (33): 8559–8562.
Saito, Y., M. Shimomura, and H. Yabu. 2014. Breath figures of nanoscale bricks: A universal method for creating hierarchic porous materials from inorganic nanoparticles stabilized with mussel-inspired copolymers. Macromolecular Rapid Communications 35 (20): 1763–1769.
———. 2013. Dispersion of Al 2 O 3 nanoparticles stabilized with mussel-inspired amphiphilic copolymers in organic solvents and formation of hierarchical porous films by the breath figure technique. Chemical Communications 49 (54): 6081–6083.
Geldhauser, T., et al. 2009. Influence of the relative humidity on the demixing of polymer blends on prepatterned substrates. Macromolecules 43 (2): 1124–1128.
Cui, L., et al. 2005. Ordered porous polymer films via phase separation in humidity environment. Polymer 46 (14): 5334–5340.
Hecht, U., C.M. Schilz, and M. Stratmann. 1998. Influence of relative humidity during film formation processes on the structure of ultrathin polymeric films. Langmuir 14 (23): 6743–6748.
Madej, W., et al. 2008. Breath figures in polymer and polymer blend films spin-coated in dry and humid ambience. Langmuir 24 (7): 3517–3524.
Ge, W., and C. Lu. 2011. Hierarchical honeycomb patterns with tunable microstructures: Controllable fabrication and application as replication templates. Soft Matter 7 (6): 2790–2796.
Connal, L.A., and G.G. Qiao. 2006. Preparation of porous poly(dimethylsiloxane)-based honeycomb materials with hierarchal surface features and their use as soft-lithography templates. Advanced Materials 18 (22): 3024–3028.
Connal, L.A., et al. 2008. Fabrication of reversibly crosslinkable, 3-dimensionally conformal polymeric microstructures. Advanced Functional Materials 18 (20): 3315–3322.
Connal, L.A., and G.G. Qiao. 2007. Honeycomb coated particles: Porous doughnuts, golf balls and hollow porous pockets. Soft Matter 3 (7): 837–839.
Ding, J., et al. 2012. Constructing honeycomb micropatterns on nonplanar substrates with high glass transition temperature polymers. Journal of Colloid and Interface Science 380: 99–104.
Zhang, Z., et al. 2012. Influence of polymer elasticity on the formation of non-cracking honeycomb films. Advanced Materials 24 (31): 4327–4330.
Greiser, C., S. Ebert, and W.A. Goedel. 2008. Using breath figure patterns on structured substrates for the preparation of hierarchically structured microsieves. Langmuir 24 (3): 617–620.
Kojima, M., et al. 2010. Photo-patterning of honeycomb films prepared from amphiphilic copolymer containing photochromic spiropyran. Chemical Communications 46 (22): 3970–3972.
Angiolini, L., et al. 2008. Chiroptical switching based on Photoinduced proton transfer between Homopolymers bearing side-chain Spiropyran and Azopyridine moieties. Macromolecular Chemistry and Physics 209 (19): 2049–2060.
Kwak, G., et al. 2006. Nanoporous, honeycomb-structured network fibers spun from semiflexible, ultrahigh molecular weight, disubstituted aromatic polyacetylenes: Superhierarchical structure and unique optical anisotropy. Chemistry of Materials 18 (23): 5537–5542.
Zheng, J., et al. 2012. Construction of hierarchical structures by electrospinning or electrospraying. Polymer 53 (2): 546–554.
Fashandi, H., and M. Karimi. 2012. Pore formation in polystyrene fiber by superimposing temperature and relative humidity of electrospinning atmosphere. Polymer 53 (25): 5832–5849.
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Rodríguez-Hernández, J., Bormashenko, E. (2020). Hierarchically Ordered Microporous Surfaces. In: Breath Figures . Springer, Cham. https://doi.org/10.1007/978-3-030-51136-4_6
Download citation
DOI: https://doi.org/10.1007/978-3-030-51136-4_6
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-51135-7
Online ISBN: 978-3-030-51136-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)