Skip to main content

Properties and Synthesis of Metal Oxide Nanoparticles in Electrochemistry

  • Chapter
  • First Online:
Book cover Nanostructured Metal-Oxide Electrode Materials for Water Purification

Abstract

The synthesis and study of “metal oxide nanoparticles”, has gain greater attention over the past 10 years among interdisciplinary researchers. The major interest may be as a result of their unique physical and chemical properties, which gives rise to their various industrial usage in the field of catalysis, electronics, solar energy conversion, and others. As the particle size diminishes, the ratio of surface atoms to those inherent rises, enabling the surface properties to dictate the overall properties of the nano-materials. Also, metal oxide nanoparticles manifest different optical and electrical properties in proportion to that of the bulk material. Hence, as the size of the solid becomes smaller, the band gap becomes larger. This, therefore, gave scientists the unique opportunity of nanofabrication synthesizing highly complex nanostructure with different electronic and optical properties just by manipulating its particle size.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. C.N.R. Rao, Transition metal oxides. Annu. Rev. Phys. Chem. 40(1), 291–326 (1989)

    Article  CAS  Google Scholar 

  2. R. Sui, P. Charpentier, Synthesis of metal oxide nanostructures by direct sol-gel chemistry in supercritical fluids. Chem. Rev. 112(6), 3057–3082 (2012)

    Google Scholar 

  3. H.H. Kung, Transition Metal Oxides: Surface Chemistry and Catalysis (Elsevier, Amsterdam, 1989)

    Google Scholar 

  4. C. Noguera, Physics and Chemistry at Oxide Surfaces (Cambridge University Press, Cambridge, UK, 1996)

    Book  Google Scholar 

  5. J.A. Rodriguez, G. Liu, T. Jirsak, Hrbek, Z. Chang, J. Dvorak, A. Maiti, J. Am. Chem. Soc. 124, 5247 (2002)

    Google Scholar 

  6. M. Valden, X. Lai, D.W. Goodman, Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties. Science 281(5383), 1647–1650 (1998)

    Google Scholar 

  7. H. Gleiter, Nanostructured materials, state of the art and perspectives. Nanostruct. Mater. 6, 3–14 ((1995))

    Google Scholar 

  8. H. Zhang, J.F. Bandfield, J. Mater. Chem. 8, 2073 (1998)

    Article  CAS  Google Scholar 

  9. J. Jeevanandam, A. Barhoum, Y.S. Chan, A. Dufresne, M.K. Danquah, Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations. Beilstein J. Nanotechnol. 9(1), 1050–1074 (2018)

    Article  CAS  Google Scholar 

  10. S. Machado, J.G. Pacheco, H.P.A. Nouws, J.T. Albergaria, C. Delerue-Matos, Characterization of green zero-valent iron nanoparticles produced with tree leaf extracts. Sci. Total Environ. 533, 76–81 (2015)

    Article  CAS  Google Scholar 

  11. S.S. Weissenrieder, J. Müller, Thin Solid Films 300, 30 (1997)

    Article  CAS  Google Scholar 

  12. M. Anpo, K. Chiba, M. Tomonari, S. Coluccia, M. Che, M.A. Fox, Bull. Chem. Soc. Jpn. 64, 543 (1991)

    Article  CAS  Google Scholar 

  13. T. Yoshida, K. Terada, D. Schlettwein, T. Oekermann, T. Sugi-ura, H. Minoura, Adv. Mater. 12, 1214 (2000)

    Article  CAS  Google Scholar 

  14. S. Bhaviripudi, E. Mile, S.A. Steiner, A.T. Zare, M.S. Dresselhaus, A.M. Belcher, J. Kong, CVD synthesis of single-walled carbon nanotubes from gold nanoparticle catalysts. J. Am. Chem. Soc. 129(6), 1516–1517 (2007)

    Google Scholar 

  15. N. Kumar, S. Kumbhat, Carbon-Based Nanomaterials. Essentials in Nanoscience and Nanotechnology (Wiley, Hoboken, 2016), pp. 189–236

    Google Scholar 

  16. D.K. Tiwari, J. Behari, P. Sen, Application of nanoparticles in waste water treatment. World Appl. Sci. J. 3(3), 417–433 (2008)

    Google Scholar 

  17. M. Salavati-niasari, F. Davar, N. Mir, Synthesis and characterization of metallic copper nanoparticles via thermal decomposition. Polyhedron 27, 3514–3518 (2008)

    Article  CAS  Google Scholar 

  18. P. Christian, F. Von der Kammer, M. Baalousha, Th Hofmann, Nanoparticles: structure, properties, preparation and behaviour in environmental media. Ecotoxicology 17, 326–343 (2008)

    Article  CAS  Google Scholar 

  19. J.F. McCarthy, L.D. McKay, Colloid transport in the subsurface: past, present, and future challenges. Vadose Zone J. 3, 326–337 (2004)

    Article  CAS  Google Scholar 

  20. S. Mann, S.L. Burkett, S.A. Davis, C.E. Fowler, N.H. Mendelson, S.D. Sims, D. Walsh, N.T. Whilton, Sol-gel synthesis of organized matter . Chem. Mater. 9(11), 2300–2310 (1997)

    Google Scholar 

  21. J.D.H. Akiba, Structural study on iron oxide nanoparticles prepared by sol-gel method. Int. J. Sci. Eng. Res. 9(7), (2018)

    Google Scholar 

  22. H.N. Azlina, J.N. Hasnidawani, H. Norita, S.N. Surip, Synthesis of SiO2 nanostructures using sol-gel method. Acta Phys. Pol., A 129(4), 842–844 (2016)

    Article  CAS  Google Scholar 

  23. C.H. Bartholomew, R.J. Farrauto, Fundamentals of Industrial Catalytic Processes, 2nd edn. (Wiley-Interscience, Hoboken, 2006)

    Google Scholar 

  24. H.K. Kammler, L. Mädler, S.E. Pratsinis, Flame synthesis of nanoparticles. Chem. Eng. Technol.: Ind. Chem.-Plant Equip.-Process Eng.-Biotechnol. 24(6), 583–596 (2001)

    Article  CAS  Google Scholar 

  25. W.Y. Teoh, R. Amal, L. Mädler, Flame spray pyrolysis: an enabling technology for nanoparticles design and fabrication. Nanoscale 2, 1324–1347 (2010)

    Article  CAS  Google Scholar 

  26. K.R. Nemade, S.A. Waghuley, Synthesis of MgO nanoparticles by solvent mixed spray pyrolysis technique for optical investigation. Int. J. Metals (2014), Article ID 389416, 4 p

    Google Scholar 

  27. Y.S Cho, S. Ji, Y.S. Kim, Synthesis of polymeric Nanoparticles by emulsion polymerization for particle self-assembly applications. J. Nanosci. Nanotechnol. 19(10), 6398–6407 (2019)

    Google Scholar 

  28. C.Y. Tai, C.T. Tai, M.H. Chang, H.S. Liu, Synthesis of magnesium hydroxide and oxide nanoparticles using a spinning disk reactor. Ind. Eng. Chem. Res. 46(17), 5536–5541 (2007)

    Article  CAS  Google Scholar 

  29. T. Trindade, P. O’Brien, N.L. Pickett, Nanocrystalline semiconductors: synthesis, properties, and perspectives. Chem. Mater. 13(11), 3843–3858 (2001)

    Article  CAS  Google Scholar 

  30. J. Khatei, Semiconductor nanocrystals or quantum dots. Resonance 77 (2013)

    Google Scholar 

  31. X.D. Li, T.P. Chen, P. Li, Y. Liu, K.C. Leong, Effects of free electrons and quantum confinement in ultrathin ZnO flims: a comparison between undoped and Al-doped ZnO. Opt. Express. 21(12), 14131–14138 (2013)

    Google Scholar 

  32. R. Viswanatha, S. Sapra, B. Satpati, P.V. Satyam, B.N. Dev, D.D. Sarma, Understanding the quantum size effects in ZnO nanocrystals. J. Mater. Chem. 14(4), 661–668 (2004)

    Article  CAS  Google Scholar 

  33. J.S. Yoo, Selective gas-phase oxidation at oxide nanoparticles on microporous materials. Catal. Today 41, 409–432 (1998)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ikenna Chibuzor Emeji .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Emeji, I.C., Ama, O.M., Aigbe, U.O., Khoele, K., Osifo, P.O., Ray, S.S. (2020). Properties and Synthesis of Metal Oxide Nanoparticles in Electrochemistry. In: Ama, O., Ray, S. (eds) Nanostructured Metal-Oxide Electrode Materials for Water Purification. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-43346-8_5

Download citation

Publish with us

Policies and ethics