Abstract
The synthesis and study of “metal oxide nanoparticles”, has gain greater attention over the past 10 years among interdisciplinary researchers. The major interest may be as a result of their unique physical and chemical properties, which gives rise to their various industrial usage in the field of catalysis, electronics, solar energy conversion, and others. As the particle size diminishes, the ratio of surface atoms to those inherent rises, enabling the surface properties to dictate the overall properties of the nano-materials. Also, metal oxide nanoparticles manifest different optical and electrical properties in proportion to that of the bulk material. Hence, as the size of the solid becomes smaller, the band gap becomes larger. This, therefore, gave scientists the unique opportunity of nanofabrication synthesizing highly complex nanostructure with different electronic and optical properties just by manipulating its particle size.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
C.N.R. Rao, Transition metal oxides. Annu. Rev. Phys. Chem. 40(1), 291–326 (1989)
R. Sui, P. Charpentier, Synthesis of metal oxide nanostructures by direct sol-gel chemistry in supercritical fluids. Chem. Rev. 112(6), 3057–3082 (2012)
H.H. Kung, Transition Metal Oxides: Surface Chemistry and Catalysis (Elsevier, Amsterdam, 1989)
C. Noguera, Physics and Chemistry at Oxide Surfaces (Cambridge University Press, Cambridge, UK, 1996)
J.A. Rodriguez, G. Liu, T. Jirsak, Hrbek, Z. Chang, J. Dvorak, A. Maiti, J. Am. Chem. Soc. 124, 5247 (2002)
M. Valden, X. Lai, D.W. Goodman, Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties. Science 281(5383), 1647–1650 (1998)
H. Gleiter, Nanostructured materials, state of the art and perspectives. Nanostruct. Mater. 6, 3–14 ((1995))
H. Zhang, J.F. Bandfield, J. Mater. Chem. 8, 2073 (1998)
J. Jeevanandam, A. Barhoum, Y.S. Chan, A. Dufresne, M.K. Danquah, Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations. Beilstein J. Nanotechnol. 9(1), 1050–1074 (2018)
S. Machado, J.G. Pacheco, H.P.A. Nouws, J.T. Albergaria, C. Delerue-Matos, Characterization of green zero-valent iron nanoparticles produced with tree leaf extracts. Sci. Total Environ. 533, 76–81 (2015)
S.S. Weissenrieder, J. Müller, Thin Solid Films 300, 30 (1997)
M. Anpo, K. Chiba, M. Tomonari, S. Coluccia, M. Che, M.A. Fox, Bull. Chem. Soc. Jpn. 64, 543 (1991)
T. Yoshida, K. Terada, D. Schlettwein, T. Oekermann, T. Sugi-ura, H. Minoura, Adv. Mater. 12, 1214 (2000)
S. Bhaviripudi, E. Mile, S.A. Steiner, A.T. Zare, M.S. Dresselhaus, A.M. Belcher, J. Kong, CVD synthesis of single-walled carbon nanotubes from gold nanoparticle catalysts. J. Am. Chem. Soc. 129(6), 1516–1517 (2007)
N. Kumar, S. Kumbhat, Carbon-Based Nanomaterials. Essentials in Nanoscience and Nanotechnology (Wiley, Hoboken, 2016), pp. 189–236
D.K. Tiwari, J. Behari, P. Sen, Application of nanoparticles in waste water treatment. World Appl. Sci. J. 3(3), 417–433 (2008)
M. Salavati-niasari, F. Davar, N. Mir, Synthesis and characterization of metallic copper nanoparticles via thermal decomposition. Polyhedron 27, 3514–3518 (2008)
P. Christian, F. Von der Kammer, M. Baalousha, Th Hofmann, Nanoparticles: structure, properties, preparation and behaviour in environmental media. Ecotoxicology 17, 326–343 (2008)
J.F. McCarthy, L.D. McKay, Colloid transport in the subsurface: past, present, and future challenges. Vadose Zone J. 3, 326–337 (2004)
S. Mann, S.L. Burkett, S.A. Davis, C.E. Fowler, N.H. Mendelson, S.D. Sims, D. Walsh, N.T. Whilton, Sol-gel synthesis of organized matter . Chem. Mater. 9(11), 2300–2310 (1997)
J.D.H. Akiba, Structural study on iron oxide nanoparticles prepared by sol-gel method. Int. J. Sci. Eng. Res. 9(7), (2018)
H.N. Azlina, J.N. Hasnidawani, H. Norita, S.N. Surip, Synthesis of SiO2 nanostructures using sol-gel method. Acta Phys. Pol., A 129(4), 842–844 (2016)
C.H. Bartholomew, R.J. Farrauto, Fundamentals of Industrial Catalytic Processes, 2nd edn. (Wiley-Interscience, Hoboken, 2006)
H.K. Kammler, L. Mädler, S.E. Pratsinis, Flame synthesis of nanoparticles. Chem. Eng. Technol.: Ind. Chem.-Plant Equip.-Process Eng.-Biotechnol. 24(6), 583–596 (2001)
W.Y. Teoh, R. Amal, L. Mädler, Flame spray pyrolysis: an enabling technology for nanoparticles design and fabrication. Nanoscale 2, 1324–1347 (2010)
K.R. Nemade, S.A. Waghuley, Synthesis of MgO nanoparticles by solvent mixed spray pyrolysis technique for optical investigation. Int. J. Metals (2014), Article ID 389416, 4 p
Y.S Cho, S. Ji, Y.S. Kim, Synthesis of polymeric Nanoparticles by emulsion polymerization for particle self-assembly applications. J. Nanosci. Nanotechnol. 19(10), 6398–6407 (2019)
C.Y. Tai, C.T. Tai, M.H. Chang, H.S. Liu, Synthesis of magnesium hydroxide and oxide nanoparticles using a spinning disk reactor. Ind. Eng. Chem. Res. 46(17), 5536–5541 (2007)
T. Trindade, P. O’Brien, N.L. Pickett, Nanocrystalline semiconductors: synthesis, properties, and perspectives. Chem. Mater. 13(11), 3843–3858 (2001)
J. Khatei, Semiconductor nanocrystals or quantum dots. Resonance 77 (2013)
X.D. Li, T.P. Chen, P. Li, Y. Liu, K.C. Leong, Effects of free electrons and quantum confinement in ultrathin ZnO flims: a comparison between undoped and Al-doped ZnO. Opt. Express. 21(12), 14131–14138 (2013)
R. Viswanatha, S. Sapra, B. Satpati, P.V. Satyam, B.N. Dev, D.D. Sarma, Understanding the quantum size effects in ZnO nanocrystals. J. Mater. Chem. 14(4), 661–668 (2004)
J.S. Yoo, Selective gas-phase oxidation at oxide nanoparticles on microporous materials. Catal. Today 41, 409–432 (1998)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this chapter
Cite this chapter
Emeji, I.C., Ama, O.M., Aigbe, U.O., Khoele, K., Osifo, P.O., Ray, S.S. (2020). Properties and Synthesis of Metal Oxide Nanoparticles in Electrochemistry. In: Ama, O., Ray, S. (eds) Nanostructured Metal-Oxide Electrode Materials for Water Purification. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-43346-8_5
Download citation
DOI: https://doi.org/10.1007/978-3-030-43346-8_5
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-43345-1
Online ISBN: 978-3-030-43346-8
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)