Skip to main content

Carbon Dots Synthesized from Green Precursors with an Amplified Photoluminescence: Synthesis, Characterization, and Its Application

  • Chapter
  • First Online:
Plant Nanobionics

Abstract

The carbon dots (CDs) are widely applied in the field of bioimaging and sensing owing to their high photoluminescence, biocompatibility, small size (<10 nm), and low toxicity. Besides, CDs also possess the upconversion PL (UCPL) properties and are able to harvest long wavelength light. These properties help them in the photocatalytic degradation of organic pollutants when irradiated by natural sunlight. Nevertheless, the reported preparation method of CDs has met several limitations, such as limited spectral efficiency, low product yield, lack of size control, the use of toxic chemicals, and high temperature for experiments. For this reason, using green precursors to produce CDs such as orange juice, soy milk, chitosan, and orange waste peels caught numerous researchers’ attention. Abundant green precursors could be potentially used as a carbon source to produce value-added CDs. This book chapter will focus on the synthesis and characterization of carbon dots synthesized from green precursors via sustainable method. We will also report the application of carbon dots for the bioimaging, sensing, photocatalysis, and biomedicine.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Alam A, Park BY, Ghouri ZK, Park M, Kim HY (2015) Synthesis of carbon quantum dot from cabbage with down and up-conversion photoluminescence properties: excellent imaging agent for biomedical application. Green Chem 17:3791–3797

    Article  CAS  Google Scholar 

  • Angamuthu R, Palanisamy P, Vasudevan V, Nagarajan S, Rajendran R, Vairamuthu R (2018) Quick synthesis of 2-propanol derived fluorescent carbon dots for bioimaging applications. Opt Mater 78:477–483

    Article  CAS  Google Scholar 

  • Anmei S, Qingmei Z, Yuye C, Yilin W (2018) Preparation of carbon quantum dots from cigarette filters and its application for fluorescence detection of Sudan I. Anal Chim Acta 1023:115–120

    Article  PubMed  CAS  Google Scholar 

  • Arora N, Sharma NN (2014) Arc discharge synthesis of carbon nanotubes: comprehensive review. Diam Relat Mater 50:135–150

    Article  CAS  Google Scholar 

  • Arumugam N, Kim J (2018) Synthesis of carbon quantum dots from broccoli and their ability to detect silver ions. Mater Lett 219:37–40

    Article  CAS  Google Scholar 

  • Baker SN, Baker GA (2010) Luminescent carbon nanodots: emergent nanolights. Angew Chem Int Ed 49:6726–6744

    Article  CAS  Google Scholar 

  • Bandi R, Gangapuram BR, Dadigala R, Eslavath R, Singh SS, Guttena V (2016) Facile and green synthesis of fluorescent carbon dots from onion waste and their potential applications as sensor and multicolour imaging agents. RSC Adv 6:28633–28639

    Article  CAS  Google Scholar 

  • Bao L, Zhang ZL, Tian ZQ, Zhang L, Liu C, Lin Y, Qi B, Pang DW (2011) Electrochemical tuning of luminescent carbon nanodots: from preparation to luminescence mechanism. Adv Mater 23:5801–5806

    Article  CAS  PubMed  Google Scholar 

  • Bottini M, Balasubramanian C, Dawson MI, Bergamaschi A, Bellucci S, Mustelin T (2006) Isolation and characterization of fluorescent nanoparticles from pristine and oxidized electric arc-produced single-walled carbon nanotubes. J Phys Chem B 110:831–836

    Article  CAS  PubMed  Google Scholar 

  • Cachier H, Bremond MP, Buat-MĂ©nard P (1989) Determination of atmospheric soot carbon with a simple thermal method. Tellus B 41:379–390

    Article  Google Scholar 

  • Cao L, Yang ST, Wang X, Luo PG, Liu JH, Sahu S, Liu Y, Sun YP (2012) Competitive performance of carbon “quantum” dots in optical bioimaging. Theranostics 2:295

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Cao LI, Meziani MJ, Sahu S, Sun YP (2012a) Photoluminescence properties of graphene versus other carbon nanomaterials. Acc Chem Res 46:171–180

    Article  PubMed  CAS  Google Scholar 

  • Chandra S, Pathan SH, Mitra S, Modha BH, Goswami A, Pramanik P (2012) Tuning of photoluminescence on different surface functionalized carbon quantum dots. RSC Adv 2:3602–3606

    Article  CAS  Google Scholar 

  • Choi Y, Thongsai N, Chae A, Jo S, Kang EB, Paoprasert P, Park SY, In I (2017) Microwave-assisted synthesis of luminescent and biocompatible lysine-based carbon quantum dots. Ind Eng Chem Res 47:329–335

    Article  CAS  Google Scholar 

  • D’souza SL, Deshmukh B, Rawat KA, Bhamore JR, Lenka N, Kailasa SK (2016) Fluorescent carbon dots derived from vancomycin for flutamide drug delivery and cell imaging. New J Chem 40:7075–7083

    Article  CAS  Google Scholar 

  • D’souza SL, Chettiar SS, Koduru JR, Kailasa SK (2018) Synthesis of fluorescent carbon dots using Daucus carota subsp. sativus roots for mitomycin drug delivery. Optik 158:893–900

    Article  CAS  Google Scholar 

  • De B, Karak N (2013) A green and facile approach for the synthesis of water soluble fluorescent carbon dots from banana juice. RSC Adv 3:8286–8290

    Article  CAS  Google Scholar 

  • Demchenko AP, Dekaliuk MO (2013) Novel fluorescent carbonic nanomaterials for sensing and imaging. Methods Appl Fluoresc 1:042001

    Article  PubMed  CAS  Google Scholar 

  • Deng J, Lu Q, Mi N, Li H, Liu M, Xu M, Tan L, Xie Q, Zhang Y, Yao S (2014) Electrochemical synthesis of carbon nanodots directly from alcohols. Chem Eur J 20:4993–4999

    Article  CAS  PubMed  Google Scholar 

  • Ding H, Ji Y, Wei JS, Gao QY, Zhou ZY, Xiong HM (2017) Facile synthesis of red-emitting carbon dots from pulp-free lemon juice for bioimaging. J Mater Chem B 5:5272–5277

    Article  CAS  PubMed  Google Scholar 

  • Dong Y, Zhou N, Lin X, Lin J, Chi Y, Chen G (2010) Extraction of electrochemiluminescent oxidized carbon quantum dots from activated carbon. Chem Mater 22:5895–5899

    Article  CAS  Google Scholar 

  • Dong Y, Pang H, Yang HB, Guo C, Shao J, Chi Y, Li CM, Yu T (2013) Carbon-based dots co-doped with nitrogen and sulfur for high quantum yield and excitation-independent emission. Angew Chem Int Ed 52:7800–7804

    Article  CAS  Google Scholar 

  • Du FY, Zhang MM, Li XF, Li JN, Jiang XY, Li Z, Hua Y, Shao GB, Jin J, Shao QX, Zhou M, Gong AH (2014) Economical and green synthesis of bagasse derived fluorescent carbon dots for biomedical applications. Nanotechnology 25:315702–315712

    Article  PubMed  CAS  Google Scholar 

  • Essner JB, Laber CH, Ravula S, Polo-Parada L, Baker GA (2016) Pee-dots: biocompatible fluorescent carbon dots derived from the upcycling of urine. Green Chem 18:243–250

    Article  Google Scholar 

  • Fadllan A, Marwoto P, Aji MP, Susanto, Iswari RS (2017) Synthesis of carbon nanodots from waste paper with hydrothermal method. AIP Publishing 1788:030069

    Google Scholar 

  • Fan RJ, Sun Q, Zhang L, Zhang Y, Lu AH (2014) Photoluminescent carbon dots directly derived from polyethylene glycol and their application for cellular imaging. Carbon 71:87–93

    Article  CAS  Google Scholar 

  • Feng T, Ai X, An G, Yang P, Zhao Y (2016) Charge-convertible carbon dots for imaging-guided drug delivery with enhanced in vivo cancer therapeutic efficiency. ACS Nano 10:4410–4420

    Article  CAS  PubMed  Google Scholar 

  • Gonçalves H, Jorge PA, Fernandes JRA, da Silva JCE (2010) Hg (II) sensing based on functionalized carbon dots obtained by direct laser ablation. Sensors Actuators B Chem 145:702–707

    Article  CAS  Google Scholar 

  • Gondal MA, Qahtan TF, Dastageer MA, Saleh TA, Maganda YW, Anjum DH (2013) Effects of oxidizing medium on the composition, morphology and optical properties of copper oxide nanoparticles produced by pulsed laser ablation. Appl Surf Sci 286:149–155

    Article  CAS  Google Scholar 

  • Guo YM, Zhang LF, Cao FP, Leng YM (2016) Thermal treatment of hair for the synthesis of sustainable carbon quantum dots and the applications for sensing Hg2+. Sci Rep 6:35795

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Guo L, Li L, Liu M, Wan Q, Tian J, Huang Q, Wen Y, Liang S, Zhang X, Wei Y (2017) Bottom-up preparation of nitrogen doped carbon quantum dots with green emission under microwave-assisted hydrothermal treatment and their biological imaging. Mater Sci Eng C 84:60–66

    Article  CAS  Google Scholar 

  • Han M, Zhu S, Lu S, Song Y, Feng T, Tao S, Liu J, Yang B (2018) Recent progress on the photocatalysis of carbon dots: classification, mechanism and applications. Nano Today 19:201–208

    Article  CAS  Google Scholar 

  • Hossain MA, Islam S (2013) Synthesis of carbon nanoparticles from kerosene and their characterization by SEM/EDX, XRD and FTIR. J Nanosci Nanotechnol 1:52–56

    Google Scholar 

  • Hou Y, Lu Q, Deng J, Li H, Zhang Y (2015) One-pot electrochemical synthesis of functionalized fluorescent carbon dots and their selective sensing for mercury ion. Anal Chim Acta 866:69–74

    Article  CAS  PubMed  Google Scholar 

  • Hu B, Wang K, Wu L, Yu SH, Antonietti M, Titirici MM (2010) Engineering carbon materials from the hydrothermal carbonization process of biomass. Adv Mater 22:813–828

    Article  CAS  PubMed  Google Scholar 

  • Hu S, Chang Q, Lin K, Yang J (2016) Tailoring surface charge distribution of carbon dots through heteroatoms for enhanced visible-light photocatalytic activity. Carbon 105:484–489

    Article  CAS  Google Scholar 

  • Huang H, Lv JJ, Zhou DL, Bao N, Xu Y, Wang AJ, Feng JJ (2013) One-pot green synthesis of nitrogen-doped carbon nanoparticles as fluorescent probes for mercury ions. RSC Adv 3:21691–21696

    Article  CAS  Google Scholar 

  • Jaleel JA, Pramod K (2017) Artful and multifaceted applications of carbon dot in biomedicine. J Control Release 269:302–321

    Article  PubMed  CAS  Google Scholar 

  • Jelinek R (2017) Carbon quantum dots: synthesis, properties and applications. Springer International Publishing AG, Cham

    Book  Google Scholar 

  • Ju E, Liu Z, Du Y, Tao Y, Ren J, Qu X (2014) Heterogeneous assembled nanocomplexes for ratiometric detection of highly reactive oxygen species in vitro and in vivo. ACS Nano 8:6014–6023

    Article  CAS  PubMed  Google Scholar 

  • Jia Zhang, Shu-Hong (2016) Carbon dots: large-scale synthesis, sensing and bioimaging. Mater Today 19(7):382–393

    Article  CAS  Google Scholar 

  • Kasibabu BSB, D’souza SL, Jha S, Kailasa SK (2015) Imaging of bacterial and fungal cells using fluorescent carbon dots prepared from Carica Papaya juice. J Fluoresc 25:803–810

    Article  CAS  PubMed  Google Scholar 

  • Kazemizadeh F, Malekfar R, Parvin P (2017) Pulsed laser ablation synthesis of carbon nanoparticles in vacuum. J Phys Chem Solids 104:252–256

    Article  CAS  Google Scholar 

  • Kshirsagar A, Khanna T, Khanna P, Dhanwe V, Khanna PK (2017) Flame deposition method for carbon nanoparticles employing green precursors and its composite with Au nanoparticles for photocatalytic degradation of methylene blue. Vacuum 146:633–640

    Article  CAS  Google Scholar 

  • Kumar A, Ray A, Laha D, Kumar T, Karmakar P, Kumar S (2017) Chemical green synthesis of carbon dots from Ocimum Sanctum for effective fluorescent sensing of Pb2+ ions and live cell imaging. Sensors Actuators B Chem 242:679–686

    Article  CAS  Google Scholar 

  • Li H, He X, Kang Z, Huang H, Liu Y, Liu J, Lian S, Tsang CHA, Yang X, Lee ST (2010) Water-soluble fluorescent carbon quantum dots and photocatalyst design. Angew Chem Int Ed 49:4430–4434

    Article  CAS  Google Scholar 

  • Li X, Wang H, Shimizu Y, Pyatenko A, Kawaguchi K, Koshizaki N (2011) Preparation of carbon quantum dots with tunable photoluminescence by rapid laser passivation in ordinary organic solvents. Chem Commun 47:932–934

    Article  Google Scholar 

  • Li W, Yue Z, Wang C, Zhang W, Liu G (2013) An absolutely green approach to fabricate carbon nanodots from soya bean grounds. RSC Adv 3:20662–20665

    Article  CAS  Google Scholar 

  • Li C, Liu W, Sun X, Pan W, Wang J (2017) Multi sensing functions integrated into one carbon-dot based platform via different types of mechanisms. Sensors Actuators B Chem 252:544–553

    Article  CAS  Google Scholar 

  • Liang F, Tanaka M, Choi S, Watanabe T (2017) Formation of different arc-anode attachment modes and their effect on temperature fluctuation for carbon nanomaterial production in DC arc discharge. Carbon 117:100–111

    Article  CAS  Google Scholar 

  • Liao J, Cheng Z, Zhou L (2016) Nitrogen-doping enhanced fluorescent carbon dots: green synthesis and their applications for bioimaging and label-free detection of Au3+ ions. ACS Sustain Chem Eng 4:3053–3061

    Article  CAS  Google Scholar 

  • Lim S, Shen W, Gao Z (2015) Carbon quantum dots and their applications. Chem Soc Rev 44:362–381

    Article  CAS  PubMed  Google Scholar 

  • Lin PY, Hsieh CW, Kung ML, Chu LY, Huang HJ, Chen HT, Wu DC, Kuo CH, Hsieh SL, Hsieh S (2014) Eco-friendly synthesis of shrimp egg-derived carbon dots for fluorescent bioimaging. J Biotechnol 189:114–119

    Article  PubMed  CAS  Google Scholar 

  • Liu S, Tian JQ, Wang L, Zhang YW, Qin XY, Luo YL, Asiri AM, Al-Youbi AO, Sun XP (2012) Hydrothermal treatment of grass: a low-cost, green route to nitrogen-doped, carbon-rich, photoluminescent polymer nanodots as an effective fluorescent sensing platform for label-free detection of Cu(II) ions. Adv Mater 24:2037–2041

    Article  CAS  PubMed  Google Scholar 

  • Liu X, Pang J, Xu F, Zhang X (2016) Simple approach to synthesize amino-functionalized carbon dots by carbonization of chitosan. Sci Rep 6:31100

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Liu F, Zhang W, Chen W, Wang J, Yang Q, Zhu W, Wang J (2017) One-pot synthesis of NiFe2O4 integrated with EDTA-derived carbon dots for enhanced removal of tetracycline. Chem Eng J 310:187–196

    Article  CAS  Google Scholar 

  • Liu W, Diao H, Chang H, Wang H, Li T, Wei W (2017a) Green synthesis of carbon dots from rose-heart radish and application for Fe3+ detection and cell imaging. Sensors Actuators B Chem 241:190–198

    Article  CAS  Google Scholar 

  • Lu WB, Qin XY, Liu S, Chang GH, Zhang YW, Luo YL, Asiri AM, Al-Youbi AO, Sun XP (2012) Economical, green synthesis of fluorescent carbon nanoparticles and their use as probes for sensitive and selective detection of mercury(II) ions. Anal Chem 84:5351–5357

    Article  CAS  PubMed  Google Scholar 

  • Lu W, Qin X, Asiri AM, Al-Youbi AO, Sun X (2013) Green synthesis of carbon nanodots as an effective fluorescent probe for sensitive and selective detection of mercury (II) ions. J Nanopart Res 15:1344

    Article  CAS  Google Scholar 

  • Lu KQ, Quan Q, Zhang N, Xu YJ (2016) Multifarious roles of carbon quantum dots in heterogeneous photocatalysis. J Energy Chem 25:927–935

    Article  Google Scholar 

  • Luo Z, Vora PM, Mele EJ, Johnson AC, Kikkawa JM (2009) Photoluminescence and band gap modulation in graphene oxide. Appl Phys Lett 94:111909

    Article  CAS  Google Scholar 

  • Ma Z, Ming H, Huang H, Liu Y, Kang Z (2012) One-step ultrasonic synthesis of fluorescent N-doped carbon dots from glucose and their visible-light sensitive photocatalytic ability. New J Chem 36:861–864

    Article  CAS  Google Scholar 

  • Martynenko IV, Litvin AP, Purcell-Milton F, Baranov AV, Fedorov AV, Gun’ko YK (2017) Application of semiconductor quantum dots in bioimaging and biosensing. J Mater Chem B 5:6701–6727

    Article  CAS  PubMed  Google Scholar 

  • Mehta VN, Jha S, Kailasa SK (2014) One-pot green synthesis of carbon dots by using Saccharum officinarum juice for fluorescent imaging of bacteria (Escherichia coli) and yeast (Saccharomyces cerevisiae) cells. Mater Sci Eng C 38:20–27

    Article  CAS  Google Scholar 

  • Mehta VN, Jha S, Basu H, Singhal RK, Kailasa SK (2015) One-step hydrothermal approach to fabricate carbon dots from apple juice for imaging of mycobacterium and fungal cells. Sensors Actuators B Chem 213:434–443

    Article  CAS  Google Scholar 

  • MenĂ©ndez JA, Arenillas A, Fidalgo B, Fernández Y, Zubizarreta L, Calvo EG, BermĂşdez JM (2010) Microwave heating processes involving carbon materials. Fuel Process Technol 91:1–8

    Article  CAS  Google Scholar 

  • Ming H, Ma Z, Liu Y, Pan K, Yu H, Wang F, Kang Z (2012) Large scale electrochemical synthesis of high quality carbon nanodots and their photocatalytic property. Dalton Trans 41:9526–9531

    Article  CAS  PubMed  Google Scholar 

  • Mumei Han, Liping Wang, Siheng Li, Liang Bai, Yunjie Zhou, Yue Sun, Hui Huang, Hao Li, Yang Liu, Zhenhui Kang (2017) High-bright fluorescent carbon dot as versatile sensing platform. Talanta 174:265–273

    Article  CAS  PubMed  Google Scholar 

  • Namdari P, Negahdari B, Eatemadi A (2017) Synthesis, properties and biomedical applications of carbon-based quantum dots : an updated review. Biomed Pharmacother 87:209–222

    Article  CAS  PubMed  Google Scholar 

  • Nersisyan HH, Lee JH, Ding JR, Kim KS, Manukyan KV, Mukasyan AS (2017) Combustion synthesis of zero-, one-, two-and three-dimensional nanostructures: current trends and future perspectives. Prog Energy Combust Sci 63:79–118

    Article  Google Scholar 

  • Pandey S, Shah R, Mewada A, Thakur M, Oza G, Sharon M (2013) Gold nanorods mediated controlled release of doxorubicin: nano-needles for efficient drug delivery. J Mater Sci Mater Med 24:1671–1681

    Article  CAS  PubMed  Google Scholar 

  • Park SY, Lee HU, Park ES, Lee SC, Lee JW, Jeong SW, Kim CH, Lee YC, Huh YS, Lee J (2014) Photoluminescent green carbon nanodots from food-waste-derived sources: large-scale synthesis, properties, and biomedical applications. ACS Appl Mater Interfaces 6:3365–3370

    Article  CAS  PubMed  Google Scholar 

  • Peng Z, Han X, Li S, Al-Youbi AO, Bashammakh AS, El-Shahawi MS, Leblanc RM (2017) Carbon dots: biomacromolecule interaction, bioimaging and nanomedicine. Coord Chem Rev 343:256–277

    Article  CAS  Google Scholar 

  • Pham-Truong TN, Petenzi T, Ranjan C, Randriamahazaka H, Ghilane J (2018) Microwave assisted synthesis of carbon dots in ionic liquid as metal free catalyst for highly selective production of hydrogen peroxide. Carbon 130:544–552

    Article  CAS  Google Scholar 

  • Prasannan A, Imae T (2013) One-pot synthesis of fluorescent carbon dots from orange waste peels. Ind Eng Chem Res 52:15673–15678

    Article  CAS  Google Scholar 

  • Qin XY, Lu WB, Asiri AM, Al-Youbi AO, Sun XP (2012) Green, low-cost synthesis of photoluminescent carbon dots by hydrothermal treatment of willow bark and their application as an effective photocatalyst for fabricating Au nanoparticles/reduced graphene oxide nanocomposites for glucose detection. Cat Sci Technol 3:1027–1035

    Article  CAS  Google Scholar 

  • Rahy A, Zhou C, Zheng J, Park SY, Kim MJ, Jang I, Cho SJ, Yang DJ (2012) Photoluminescent carbon nanoparticles produced by confined combustion of aromatic compounds. Carbon 50:1298–1302

    Article  CAS  Google Scholar 

  • Ramanan V, Thiyagarajan SK, Raji K, Suresh R, Sekar R, Ramamurthy P (2016) Outright green synthesis of fluorescent carbon dots from eutrophic algal blooms for in vitro imaging. ACS Sustain Chem Eng 4:4724–4731

    Article  CAS  Google Scholar 

  • Roshni V, Praveen OD (2017) Fluorescent N-doped Carbon Dots from Mustard Seeds: One step Green Synthesis and its Application as an effective Hg (II) Sensor. Braz J Anal Chem 4(14):17–24

    Google Scholar 

  • Sachdev A, Gopinath P (2015) Green synthesis of multifunctional carbon dots from coriander leaves and their potential application as antioxidants, sensors and bioimaging agents. Analyst 140:4260–4269

    Article  CAS  PubMed  Google Scholar 

  • Sachdev A, Matai I, Kumar SU, Bhushan B, Dubey P, Gopinath P (2013) A novel one-step synthesis of PEG passivated multicolour fluorescent carbon dots for potential biolabeling application. RSC Adv 3:16958–16961

    Article  CAS  Google Scholar 

  • Sachdev A, Matai I, Gopinath P (2014) Implications of surface passivation on physicochemical and bioimaging properties of carbon dots. RSC Adv 4:20915–20921

    Article  CAS  Google Scholar 

  • Sahu S, Behera B, Maiti TK, Mohapatra S (2012) Simple one-step synthesis of highly luminescent carbon dots from orange juice: application as excellent bio-imaging agents. Chem Commun 48:8835–8837

    Article  CAS  Google Scholar 

  • Schneider J, Reckmeier CJ, Xiong Y, von Seckendorff M, Susha AS, Kasák P, Rogach AL (2017) Molecular fluorescence in citric acid-based carbon dots. J Phys Chem C 121:2014–2022

    Article  CAS  Google Scholar 

  • Shahidi S, Rashidian M, Dorranian D (2018) Preparation of antibacterial textile using laser ablation method. Opt Laser Technol 99:145–153

    Article  CAS  Google Scholar 

  • Sharma V, Tiwari P, Mobin SM (2017) Sustainable carbon-dots: recent advances in green carbon dots for sensing and bioimaging. J Mater Chem B 5:8904–8924

    Article  CAS  PubMed  Google Scholar 

  • Shen LM, Liu J (2016) New development in carbon quantum dots technical applications. Talanta 156-157:245–256

    Article  CAS  PubMed  Google Scholar 

  • Sim LC, Wong JL, Hak CH, Tai JY, Leong KH, Saravanan P (2018) Sugarcane juice derived carbon dot–graphitic carbon nitride composites for bisphenol A degradation under sunlight irradiation. Beilstein J Nanotechnol 9:353–363

    Article  PubMed  PubMed Central  CAS  Google Scholar 

  • Sk MA, Ananthanarayanan A, Huang L, Lim KH, Chen P (2014) Revealing the tunable photoluminescence properties of graphene quantum dots. J Mater Chem C 2:6954–6960

    Article  CAS  Google Scholar 

  • Ĺ tÄ›pánková S, Kozák O, ZboĹ™il R (2015) Surfactant-based fluorescent quantum carbon dots: synthesis and application. Adv Mater Res 1088:381–385

    Article  Google Scholar 

  • Sun X, Lei Y (2017) Fluorescent carbon dots and their sensing applications. Trends Anal Chem 89:163–180

    Article  CAS  Google Scholar 

  • Sun YP, Zhou B, Lin Y, Wang W, Fernando KS, Pathak P, Meziani MJ, Harruff BA, Wang X, Wang H, Luo PG (2006) Quantum-sized carbon dots for bright and colorful photoluminescence. J Am Chem Soc 128:7756–7757

    Article  CAS  PubMed  Google Scholar 

  • Sun D, Ban R, Zhang PH, Wu GH, Zhang JR, Zhu JJ (2013) Hair fiber as a precursor for synthesizing of sulfur-and nitrogen-co-doped carbon dots with tunable luminescence properties. Carbon 64:424–434

    Article  CAS  Google Scholar 

  • Sun DL, Hong RY, Wang F, Liu JY, Kumar MR (2016) Synthesis and modification of carbon nanomaterials via AC arc and dielectric barrier discharge plasma. Chem Eng J 283:9–20

    Article  CAS  Google Scholar 

  • Tian L, Ghosh D, Chen W, Pradhan S, Chang X, Chen S (2009) Nanosized carbon particles from natural gas soot. Chem Mater 21:2803–2809

    Article  CAS  Google Scholar 

  • Wang Y, Hu A (2014) Carbon quantum dots: synthesis, properties and applications. J Mater Chem C 2:6921–6939

    Article  CAS  Google Scholar 

  • Wang L, Zhou HS (2014) Green synthesis of luminescent nitrogen-doped carbon dots from milk and its imaging application. Anal Chem 86:8902–8905

    Article  CAS  PubMed  Google Scholar 

  • Wang X, Cao L, Lu FS, Meziani MJ, Li HT, Qi G, Zhou B, Harruff BA, Kermarrec F, Sun YP (2009) Photoinduced electron transfers with carbon dots. Chem Commun 25:3774–3776

    Article  CAS  Google Scholar 

  • Wang X, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson JM, Domen K, Antonietti M (2009a) A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat Mater 8:76–80

    Article  CAS  PubMed  Google Scholar 

  • Wang Q, Zheng H, Long Y, Zhang L, Gao M, Bai W (2011) Microwave–hydrothermal synthesis of fluorescent carbon dots from graphite oxide. Carbon 49:3134–3140

    Article  CAS  Google Scholar 

  • Wang J, Wang CF, Chen S (2012) Amphiphilic egg-derived carbon dots: rapid plasma fabrication, pyrolysis process, and multicolor printing patterns. Angew Chem 124:9431–9435

    Article  Google Scholar 

  • Wang R, Lu KQ, Tang ZR, Xu YJ (2017) Recent progress on carbon quantum dots: synthesis, properties and applications in photocatalysis. J Mater Chem A 5:3717–3734

    Article  CAS  Google Scholar 

  • Wang Y, Zheng J, Wang J, Yang Y, Liu X (2017a) Rapid microwave-assisted synthesis of highly luminescent nitrogen-doped carbon dots for white light-emitting diodes. Opt Mater 73:319–329

    Article  CAS  Google Scholar 

  • Wang Z, Long P, Feng Y, Qin C, Feng W (2017b) Surface passivation of carbon dots with ethylene glycol and their high-sensitivity to Fe3+. RSC Adv 7:2810–2816

    Article  CAS  Google Scholar 

  • Wei J, Liu B, Yin P (2014) Dual functional carbonaceous nanodots exist in a cup of tea. RSC Adv 4:63414–63419

    Article  CAS  Google Scholar 

  • Wen X, Yu P, Toh YR, Ma X, Tang J (2014) On the upconversion fluorescence in carbon nanodots and graphene quantum dots. Chem Commun 50:4703–4706

    Article  CAS  Google Scholar 

  • Wu ZL, Zhang P, Gao MX, Liu CF, Wang W, Leng F, Huang CZ (2013) One-pot hydrothermal synthesis of highly luminescent nitrogen-doped amphoteric carbon dots for bioimaging from Bombyxmori silk–natural proteins. J Mater Chem B 1:2868–2873

    Article  CAS  PubMed  Google Scholar 

  • Xu X, Ray R, Gu Y, Ploehn HJ, Gearheart L, Raker K, Scrivens WA (2004) Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments. J Am Chem Soc 126:12736–12737

    Article  CAS  PubMed  Google Scholar 

  • Xu M, Li Z, Zhu X, Hu N, Wei H, Yang Z, Zhang Y (2013) Hydrothermal/solvothermal synthesis of graphene quantum dots and their biological applications. Nano Biomed Eng 5:65–71

    Article  CAS  Google Scholar 

  • Xu Y, Liu J, Gao C, Wang E (2014) Applications of carbon quantum dots in electrochemiluminescence: a mini review. Electrochem Commun 48:151–154

    Article  CAS  Google Scholar 

  • Yan Z, Zhang Z, Chen J (2016) Biomass-based carbon dots: synthesis and application in imatinib determination. Sensors Actuators B Chem 225:469–473

    Article  CAS  Google Scholar 

  • Yang ST, Cao L, Luo PG, Lu F, Wang X, Wang H, Meziani MJ, Liu Y, Qi G, Sun YP (2009) Carbon dots for optical imaging in vivo. J Am Chem Soc 131:11308–11309

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Yang P, Zhao J, Wang J, Cui H, Li L, Zhu Z (2015) Pure carbon nanodots for excellent photocatalytic hydrogen generation. RSC Adv 5:21332–21335

    Article  CAS  Google Scholar 

  • Yang X, Yang X, Li Z, Li S, Han Y, Chen Y, Bu X, Su C, Xu H, Jiang Y, Lin Q (2015a) Photoluminescent carbon dots synthesized by microwave treatment for selective image of cancer cells. J Colloid Interface Sci 456:1–6

    Article  CAS  PubMed  Google Scholar 

  • Yang X, Wang Y, Shen X, Su C, Yang J, Piao M, Jia F, Gao G, Zhang L, Lin Q (2017) One-step synthesis of photoluminescent carbon dots with excitation-independent emission for selective bioimaging and gene delivery. J Colloid Interface Sci 49:1–7

    Article  CAS  Google Scholar 

  • Yu CY, Xuan TT, Chen YW, Zhao ZJ, Sun Z, Li HL (2015) A facile, green synthesis of highly fluorescent carbon nanoparticles from oatmeal for cell imaging. J Mater Chem C 3:9514–9518

    Article  CAS  Google Scholar 

  • Yu H, Shi R, Zhao Y, Waterhouse GI, Wu LZ, Tung CH, Zhang T (2016) Smart utilization of carbon dots in semiconductor photocatalysis. Adv Mater 28:9454–9477

    Article  CAS  PubMed  Google Scholar 

  • Yuan Y, Guo B, Hao L, Liu N, Lin Y, Guo W, Li X, Gu B (2017) Doxorubicin-loaded environmentally friendly carbon dots as a novel drug delivery system for nucleus targeted cancer therapy. Colloids Surf B Biointerfaces 159:349–359

    Article  CAS  PubMed  Google Scholar 

  • Zhang J, Yu S (2015) Carbon dots: large-scale synthesis, sensing and bioimaging. Mater Today 19:382–393

    Article  CAS  Google Scholar 

  • Zhang Z, Shan Y, Wang J, Ling H, Zang S, Gao W, Zhao Z, Zhang H (2007) Investigation on the rapid degradation of congo red catalyzed by activated carbon powder under microwave irradiation. J Hazard Mater 147:325–333

    Article  CAS  PubMed  Google Scholar 

  • Zhang J, Yuan Y, Liang G, Yu SH (2015) Scale-up synthesis of fragrant nitrogen-doped carbon dots from bee pollens for bioimaging and catalysis. Adv Sci 2:1500002

    Article  CAS  Google Scholar 

  • Zhang L, Zheng W, Tang R, Wang N, Zhang W, Jiang X (2016) Gene regulation with carbon-based siRNA conjugates for cancer therapy. Biomaterials 104:269–278

    Article  CAS  PubMed  Google Scholar 

  • Zhang QQ, Chen BB, Zou HY, Li YF, Huang CZ (2018) Inner filter with carbon quantum dots: a selective sensing platform for detection of hematin in human red cells. Biosens Bioelectron 100:148–154

    Article  CAS  PubMed  Google Scholar 

  • Zhao QL, Zhang ZL, Huang BH, Peng J, Zhang M, Pang DW (2008) Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite. Chem Commun 41:5116–5118

    Article  CAS  Google Scholar 

  • Zhao S, Lan M, Zhu X, Xue H, Ng TW, Meng X, Lee CS, Wang P, Zhang W (2015) Green synthesis of bifunctional fluorescent carbon dots from garlic for cellular imaging and free radical scavenging. ACS Appl Mater Interfaces 7:17054–17060

    Article  CAS  PubMed  Google Scholar 

  • Zhong D, Miao H, Yang K, Yang X (2016) Carbon dots originated from carnation for fluorescent and colorimetric pH sensing. Mater Lett 166:89–92

    Article  CAS  Google Scholar 

  • Zhou J, Booker C, Li R, Zhou X, Sham TK, Sun X, Ding Z (2007) An electrochemical avenue to blue luminescent nanocrystals from multiwalled carbon nanotubes (MWCNTs). J Am Chem Soc 129:744–745

    Article  CAS  PubMed  Google Scholar 

  • Zhou M, Zhou Z, Gong A, Zhang Y, Li Q (2015) Synthesis of highly photoluminescent carbon dots via citric acid and Tris for iron (III) ions sensors and bioimaging. Talanta 143:107–113

    Article  CAS  PubMed  Google Scholar 

  • Zhou J, Deng W, Wang Y, Cao X, Chen J, Wang Q, Xu W, Du P, Yu Q, Chen J, Spector M (2016) Cationic carbon quantum dots derived from alginate for gene delivery: one-step synthesis and cellular uptake. Acta Biomater 42:209–219

    Article  CAS  PubMed  Google Scholar 

  • Zhu CZ, Zhai JF, Dong SJ (2012) Bifunctional fluorescent carbon nanodots: green synthesis via soy milk and application as metal-free electrocatalysts for oxygen reduction. Chem Commun 48:9367–9369

    Article  CAS  Google Scholar 

  • Zhu S, Meng Q, Wang L, Zhang J, Song Y, Jin H, Zhang K, Sun H, Wang H, Yang B (2013) Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging. Angew Chem 125:4045–4049

    Article  Google Scholar 

  • Zuo J, Jiang T, Zhao X, Xiong X, Xiao S, Zhu Z (2015) Preparation and application of fluorescent carbon dots. J Nanomater 2015:10

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lan Ching Sim .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Sim, L.C. et al. (2019). Carbon Dots Synthesized from Green Precursors with an Amplified Photoluminescence: Synthesis, Characterization, and Its Application. In: Prasad, R. (eds) Plant Nanobionics. Nanotechnology in the Life Sciences. Springer, Cham. https://doi.org/10.1007/978-3-030-16379-2_1

Download citation

Publish with us

Policies and ethics