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Catalytic CO2 Conversion to Added-Value Energy Rich C1 Products

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An Economy Based on Carbon Dioxide and Water

Abstract

Carbon-dioxide emission from various sources is the primary cause of rapid climate change. Its utilization and storage are becoming a pivotal issue to reduce the risk of future devastating effect. The conversion of carbon-dioxide as an abundant and inexpensive feedstock to valuable chemicals is a challenging contemporary issue having multi-facets. There is a need to elucidate the process of utilizing CO2 to gain a fundamental understanding to overcome the challenges. This chapter focuses on converting CO2 to C1 valuable chemicals via hydrogenation (methane, methanol, syngas, formic acid) and reforming reactions (syngas). The first four parts of this chapter cover the production of methane, methanol and formic acid via hydrogenation reaction and syngas via reverse water gas shift reaction. Moreover, the last part of the chapters consists of reforming whereby CO2 acts as a mild oxidant for the production of syngas (CO + H2). The chapter covers different aspects, including the current challenges in the process, the state of the art and design of catalysts, and mechanistic consideration, all of which are critically evaluated to give the insight into each reaction.

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Authors and Affiliations

  1. Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore, 119260, Republic of Singapore

    Jangam Ashok, Sonali Das, Nikita Dewangan & Sibudjing Kawi

  2. Laboratory of Catalysis and Catalytic Processes, Department of Energy, Politecnico di Milano, Milan, Italy

    Leonardo Falbo & Carlo Giorgio Visconti

Authors
  1. Jangam Ashok
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  2. Leonardo Falbo
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  3. Sonali Das
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  4. Nikita Dewangan
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  5. Carlo Giorgio Visconti
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  6. Sibudjing Kawi
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Corresponding authors

Correspondence to Carlo Giorgio Visconti or Sibudjing Kawi .

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Editors and Affiliations

  1. IC²R srl, Lab H124, Tecnopolis, Valenzano, Italy

    Michele Aresta

  2. Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore, Singapore

    Iftekhar Karimi

  3. Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore, Singapore

    Sibudjing Kawi

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Ashok, J., Falbo, L., Das, S., Dewangan, N., Visconti, C.G., Kawi, S. (2019). Catalytic CO2 Conversion to Added-Value Energy Rich C1 Products. In: Aresta, M., Karimi, I., Kawi, S. (eds) An Economy Based on Carbon Dioxide and Water. Springer, Cham. https://doi.org/10.1007/978-3-030-15868-2_5

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