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Osmium and Ruthenium Poly(pyridyl) Redox Polymers as Electrode Coatings

  • Chapter
Electroactive Polymer Electrochemistry

Abstract

The properties of modified electrodes are intricately linked to properties of the modifying layer applied. Of prime importance is of course the redox potential of the electroactive component in the layer. The mediating properties of the modified electrodes and their application as sensors or in other devices, are closely linked to the redox potential of the coating. The second factor to be considered is the structure of the layer and the manner in which this structure is affected by the contacting electrolyte. This last factor strongly influences electrochemical processes which are controlled by factors such as ion and substrate penetration into the layer. The working of the modified electrode is therefore an interplay between the redox properties of the mediator and the structural properties of the medium in which it is encapsulated. In preparing modified electrodes, as much attention should therefore be paid to the physical nature of the coating as to the choice of the redox active species. Layers that contain the same redox couple, but where the matrix is different, can show quite different electrochemical properties. For example, electrodes coated with polymers prepared by electrochemical polymerization can show quite different properties from those prepared from preformed polymers by solvent evaporation.

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References

  1. N. Oyama, T. Ohsaka, T. Ushirogouchi, S. Sanpel, and S. Nakamura, Bull. Chem. Soc. Jpn. 61, 3103 (1988).

    Article  CAS  Google Scholar 

  2. H. S. White, J. Leddy, and A. J. Bard, J. Am. Chem. Soc. 104, 4811 (1982).

    Article  CAS  Google Scholar 

  3. Y-M. Tsou and F. C. Anson, J. Electrochem. Soc. 131, 595 (1984).

    Article  CAS  Google Scholar 

  4. E. T. T. Jones and L. R. Faulkner, J. Electroanal. Chem. Soc. 222, 201 (1987).

    Article  CAS  Google Scholar 

  5. M. Majda and L. R. Faulkner, J. Electroanal. Chem. 137, 149 (1982).

    Google Scholar 

  6. M. Majda and L. R. Faulkner, J. Electroanal. Chem. 169, 77 (1984).

    Article  CAS  Google Scholar 

  7. M. Majda and L. R. Faulkner, J. Electroanal. Chem. 169, 97 (1987).

    Google Scholar 

  8. X. Chen, R. He, and L. R. Faulkner, J. Electroanal. Chem. 222, 223 (1987).

    Article  CAS  Google Scholar 

  9. M. Sharp, B. Lindholm, and E. L. Lind, J. Electroanal. Chem. 274, 35 (1989).

    Article  CAS  Google Scholar 

  10. F. C. Anson, Y. M. Tsou, and J. M. Saveant, J. Electroanal. Chem. 178, 113 (1984).

    Article  CAS  Google Scholar 

  11. J. Leddy and A. J. Bard, J. Electroanal. Chem. 189, 203 (1985).

    CAS  Google Scholar 

  12. H. D. Abruna, P. Denisevich, M. Umana, T. J. Meyer, and R. W. Murray, J. Am. Chem. Soc. 103, I (1981).

    Google Scholar 

  13. P. Denisevich, K. W. Willman, and R. W. Murray, J. Am. Chem. Soc. 103, 4727 (1981).

    Article  CAS  Google Scholar 

  14. T. Ikeda, C. R. Leidner, and R. W. Murray, J. Am. Chem. Soc. 103, 7422 (1981).

    Article  CAS  Google Scholar 

  15. T. Ikeda, R. H. Schmehl, R. Denisevich, K. W. Willman, and R. W. Murray J. Am. Chem. Soc. 104, 2683 (1982).

    Article  CAS  Google Scholar 

  16. J. S. Facci, R. H. Schmehl, and R. W. Murray, J. Am. Chem. Soc. 104, 4959 (1982).

    Article  CAS  Google Scholar 

  17. P. Denisevich, H. D. Abruna, C. R. Leidner, T. J. Meyer, and R. W. Murray, Inorg. Chem. 21, 2153 (1982).

    Article  CAS  Google Scholar 

  18. J. M. Calvert, R. H. Schmehl, B. R. Sullivan, J. S. Facci, T. J. Meyer, and R. W. Murray, Inorg. Chem. 22, 2151 (1983).

    Article  CAS  Google Scholar 

  19. P. G. Pickup and R. W. Murray, J. Am. Chem. Soc. 105, 4510 (1983).

    Article  CAS  Google Scholar 

  20. P. G. Pickup and R.W. Murray, J. Electrochem. Soc. 131, 833 (1984).

    Article  CAS  Google Scholar 

  21. J. M. Calvert, D. L. Peebles, and R. J. Nowak, Inorg. Chem. 24, 3111 (1985).

    Article  CAS  Google Scholar 

  22. C. D. Ellis, W. R. Murphy, and T. J. Meyer, J. Am. Chem. Soc. 103, 7480 (1981).

    Article  CAS  Google Scholar 

  23. P. G. Pickup, W. Kutner, C. R. Leidner, and R. W. Murray, J. Am. Chem. Soc. 106, 1991 (1984).

    Article  CAS  Google Scholar 

  24. C. R. Leidner and R. W. Murray, J. Am. Chem. Soc. 106, 1606 (1984).

    Article  CAS  Google Scholar 

  25. A. G. Ewing, B. R. Feldman, and R. W. Murray, J. Electroanal. Chem. Soc. 172, 145 (1984).

    Article  CAS  Google Scholar 

  26. J. C. Jernigan, C. E. D. Chidsey, and R. W. Murray, J. Am. Chem. Soc. 107, 2824 (1985).

    Article  CAS  Google Scholar 

  27. J. Leddy, A. J. Bard, J. T. Maloy, and J. M. Saveant, J. Electroanal. Chem. Soc. 187, 205 (1985).

    Article  CAS  Google Scholar 

  28. J. M. Calvert and T. J. Meyer, Inorg. Chem. 20, 27 (1981).

    Article  CAS  Google Scholar 

  29. S. M. Geraty and J. G. Vos, J. Chem. Soc. Dalton Trans. 3073 (1987).

    Google Scholar 

  30. J. M. Clear, J. M. Kelly, C. M. O’Connell, and J. G. Vos, J. Chem. Res, (M) 3039 (1981).

    Google Scholar 

  31. E. M. Kober, J. L. Marshall, W. J. Dressick, B. P. Sullivan, J. V. Casper, and T. J. Meyer, Inorg. Chem. 24, 2755 (1985).

    Article  CAS  Google Scholar 

  32. B. P. Sullivan, D. J. Salmon, and T. J. Meyer, Inorg. Chem. 17, 3334 (1978).

    Article  CAS  Google Scholar 

  33. E. C. Johnson, B. P. Sullivan, D. J. Salmon, S. A. Adeyemi, and T. J. Meyer, Inorg. Chem. 17, 2211 (1978).

    Article  CAS  Google Scholar 

  34. D. A. Buckingham, F. P. Dwyer, H. A. Goodwin, and A. M. Sargeson, Aust. J. Chem. 17, 325 (1964).

    Article  CAS  Google Scholar 

  35. E. M. Kober, J. V. Casper, R. S. Lumpkin, and T. J. Meyer, J. Phys. Chem. 90, 3722 (1986).

    Article  CAS  Google Scholar 

  36. J. M. Clear, J. M. Kelly, D. C. Pepper, and J. G. Vos, Inorg. Chim. Acta 33, L139 (1979).

    Article  CAS  Google Scholar 

  37. B. Durham, S. R. Wilson, D. J. Hodgson, and T. J. Meyer, J. Am. Chem. Soc. 102, 600 (1980).

    Article  CAS  Google Scholar 

  38. J. M. Calvert and T. J. Meyer, Inorg. Chem. 21, 3978 (1982).

    Article  CAS  Google Scholar 

  39. S. M. Geraty and J. G. Vos, J. Electroanal. Chem. 176, 389 (1984).

    Article  CAS  Google Scholar 

  40. O. Haas and J. G. Vos, J. Electroanal. Chem. 113, 139 (1980).

    Article  CAS  Google Scholar 

  41. O. Haas, M. Kriens, and J. G. Vos, J. Am. Chem. Soc. 103, 1318 (1981).

    Article  CAS  Google Scholar 

  42. O. Haas, H. R. Zumbrunnen, and J. G. Vos, Electrochim. Acta 30, 1551 (1985).

    Article  CAS  Google Scholar 

  43. R. J. Forster and J. G. Vos, Macromolecules 23, 4372 (1990).

    Article  CAS  Google Scholar 

  44. D. Leech, R. J. Forster, M. R. Smyth, and J. G. Vos, J. Mater. Chem. 1, 629 (1991).

    Article  CAS  Google Scholar 

  45. J. M. Calvert, J. V. Casper, R. A. Binstead, T. D. Westmoreland, and T. J. Meyer, J. Am. Chem. Soc. 104, 6620 (1982).

    Article  CAS  Google Scholar 

  46. J. M. Clear, J. M. Kelly, and J. G. Vos, Makromol. Chem. 184, 613 (1983).

    Article  CAS  Google Scholar 

  47. T. Shimidzu, K. Izaki, Y. Akai, and T. Iyoda, Polym. J. 13, 889 (1981).

    Article  CAS  Google Scholar 

  48. J. van Houten and R. J. Watts, J. Am. Chem. Soc. 98, 4853 (1976).

    Article  Google Scholar 

  49. J. van Houten and R. J. Watts, Inorg. Chem. 17, 3381 (1978).

    Article  Google Scholar 

  50. B. Durham, J. V. Casper, J. K. Nagle, and T. J. Meyer, J. Am. Chem. Soc. 104, 4803 (1982).

    Article  CAS  Google Scholar 

  51. A. B. P. Lever, Inorganic Electronic Spectroscopy ( Elsevier, New York, 1968 ).

    Google Scholar 

  52. C. K. Balhausen, Absorption Spectra and Chemical Bonding in Complexes ( Pergamon, New York, 1972 ), p. 114.

    Google Scholar 

  53. G. J. Samuels and T. J. Meyer, J. Am. Chem. Soc. 103, 307 (1981).

    Article  CAS  Google Scholar 

  54. O. Haas, N. Muller, and H. Gerischer, Electrochim. Acta 27, 991 (1982).

    Article  CAS  Google Scholar 

  55. M. E. G. Lyons, H. G. Fay, J. G. Vos, and A. J. Kelly, J. Electroanal. Chem. 250, 207 (1988).

    Article  CAS  Google Scholar 

  56. R. J. Forster and J. G. Vos, Langmuir 10, 4330 (1994).

    Article  CAS  Google Scholar 

  57. R. J. Forster and J. G. Vos, J. Inorganic and Organometallic Polymers 1, 67 (1991).

    Article  CAS  Google Scholar 

  58. R. J. Forster, A. J. Kelly, J. G. Vos, and M. E. G. Lyons, J. Electroanal. Chem. 270, 365 (1989).

    Article  CAS  Google Scholar 

  59. R. J. Forster and J. G. Vos, J. Electroanal. Chem. 314, 135 (1991).

    Article  CAS  Google Scholar 

  60. R. J. Forster and J. G. Vos, Electrochim. Acta 37, 159 (1992).

    Article  CAS  Google Scholar 

  61. R. J. Forster, J. G. Vos, and M. E. G. Lyons, J. Chem. Soc. Faraday Trans. 87, 3761 (1991).

    Article  CAS  Google Scholar 

  62. R. J. Forster, J. G. Vos, and M. E. G. Lyons, J Chem. Soc. Faraday Trans. 87, 3769 (1991).

    Article  CAS  Google Scholar 

  63. E. M. Kober, J. V. Casper, B. P. Sullivan, and T. J. Meyer, Inorg. Chem. 27, 4587 (1988).

    Article  CAS  Google Scholar 

  64. B. P. Sullivan, D. J. Salmon, T. J. Meyer, and J. Peedin, Inorg. Chem. 18, 3369 (1979).

    Article  CAS  Google Scholar 

  65. J. G. Gaudiello, P. G. Bradley, K. A. Norton, W. H. Woodruff, and A. J. Bard, Inorg. Chem. 23, 3 (1984).

    Article  CAS  Google Scholar 

  66. A. Juris, V. Balzani, F. Barigelletti, S. Campagna, P. Belser, and A. von Zelewsky, Coord. Chem. Rev. 84, 85 (1988).

    Article  CAS  Google Scholar 

  67. S. D. Ernst and W. Kaim, Inorg. Chem. 28, 1520 (1989).

    Article  CAS  Google Scholar 

  68. E Barigelletti, A. Juris, V. Balzan, P. Belser, and A. von Zelewsky, Inorg. Chem. 26, 4115 (1987).

    Article  CAS  Google Scholar 

  69. A. Juris, S. Campagna, V. Balzani, G. Gremaud, and A. von Zelewsky, Inorg. Chem. 27, 3652 (1988).

    Article  CAS  Google Scholar 

  70. A. Juris, R. Belser, F. Baribelletti, A. von Zelewsky, and V. Balzani, Inorg. Chem. 25, 256 (1986).

    Article  CAS  Google Scholar 

  71. F. Barigelletti, P. Belser, A. von Zelewsky, A. Juris, and V. Balzani, J. Phys. Chem. 89, 3680 (1985).

    Article  CAS  Google Scholar 

  72. F. Barigelletti, A. Juris, V. Balzani, P. Belser, and A. von Zelewsky, Inorg. Chem. 26, 3335 (1983).

    Article  Google Scholar 

  73. Y. Kawanishi, N. Kitamura, and S. Tazuka, Inorg. Chem. 28, 2968 (1989).

    Article  CAS  Google Scholar 

  74. H. Taube, PureAppl. Chem. 51, 901 (1979).

    Article  CAS  Google Scholar 

  75. A. C. Sarupa and R. F. Fenske, Inorg. Chem. 14, 247 (1975).

    Article  Google Scholar 

  76. P. M. Treichel, H. J. Mueh, and B. E. Bursten, Isr. J. Chem. 15, 253 (1977).

    CAS  Google Scholar 

  77. P. M. Treichel, H. J. Mueh, and B. E. Bursten, J. Organomet. Chem. 110, C49 (1976).

    Article  CAS  Google Scholar 

  78. B. A. Moyer and T. J. Meyer, J. Am. Chem. Soc. 100, 3601 (1978).

    Article  CAS  Google Scholar 

  79. B. A. Moyer and T. J. Meyer, J. Am. Chem. Soc. 101, 1326 (1979).

    Article  CAS  Google Scholar 

  80. B. A. Moyer and T. J. Meyer, Inorg. Chem. 20, 436 (1981).

    Article  CAS  Google Scholar 

  81. B. Durham, J. L. Walsh, C. L. Carter, and T. J. Meyer, Inorg. Chem. 19, 860 (1980).

    Article  CAS  Google Scholar 

  82. N. M. D. Brown, H. X. You, R. J. Forster, and J. G. Vos, J. Mater. Chem. 1, 517 (1990).

    Article  Google Scholar 

  83. C. P. Andrieux, in Electrochemistry, Sensors and Analysis, vol. 25 ( M. R. Smyth and J. G. Vos, eds.) Analytical Symposia Series (Elsevier, Amsterdam 1986 ), 235.

    Google Scholar 

  84. R. Daum, J. R. Lenhard, D. R. Rolison, and R. W. Murray, J. Am. Chem. Soc. 102, 4649 (1980).

    Article  CAS  Google Scholar 

  85. A. H. Shroeder, F. B. Kaufman, V. Patel, and E. M. Engler, J Electroanal. Chem. 113, 193 (1980).

    Article  Google Scholar 

  86. T. R. Henning, H. S. White, and A. J. Bard, J. Am. Chem. Soc. 103, 3937 (1981).

    Article  CAS  Google Scholar 

  87. R. J. Nowak, F. A. Schultz, M. Umana, R. Lam, and R. W. Murray, Anal. Chem. 52, 315 (1980).

    Article  CAS  Google Scholar 

  88. P. Ferruti and R. Barbucci, Adv. Polym. Sci. 58, 55 (1984).

    Article  CAS  Google Scholar 

  89. A. Eisenberg, Macromolecules 3, 147 (1970).

    Article  CAS  Google Scholar 

  90. E. F. Bowden, M. F. Dautartas, and J. F. Evans, J. Electroanal. Chem. 219, 49 (1987).

    Article  CAS  Google Scholar 

  91. M. F. Dautartas, E. F. Bowden, and J. F. Evans, J. Electroanal. Chem. 219, 71 (1987).

    Article  CAS  Google Scholar 

  92. E. F. Bowden, M. F. Dautartas, and J. F. Evans, J. Electroanal. Chem. 219, 91 (1987).

    Article  CAS  Google Scholar 

  93. A. R. Hillman, D. C. Loveday, and S. Bruckenstein, J. Electroanal. Chem. 300, 67 (1991).

    Article  CAS  Google Scholar 

  94. A. R. Hillman, in Electrochemical Science and Technology of Polymers vol. 1 ( R. G. Linford, ed.) ( Elsevier, Amsterdam, 1987 ), p. 103.

    Google Scholar 

  95. H. Daifuku, K. Aoki, K. Tokuda, and H. Matsuda, J. Electroanal. Chem. 183, 1 (1985).

    Article  CAS  Google Scholar 

  96. A. J. Bard and L. R. Faulkner, Electrochemical Methods, Fundamentals and Applications ( Wiley, New York, 1980 ).

    Google Scholar 

  97. D. M. Mohliner, J. Electroanal. Chem. 146, 417 (1983).

    Article  Google Scholar 

  98. A. Sevcik, Collect. Czech. Chem. Commun. 44, 327 (1948).

    Google Scholar 

  99. K. Aoki, K. Tokuda, and H. Matsuda, J. Electroanal. Chem. 146, 417 (1983).

    Article  CAS  Google Scholar 

  100. F. G. Cottrell, Z. Phys. Chem. 42, 385 (1902).

    Google Scholar 

  101. C. P. Andrieux and J. M. Saveant, J. Phys. Chem. 92, 6761 (1988).

    Article  CAS  Google Scholar 

  102. W. T. Yap and R. A. Durst, J. Electroanal. Chem. 216, 11 (1987).

    Article  CAS  Google Scholar 

  103. W. T. Yap, R. A. Durst, E. A. Blubaugh, and D. D. Blubaugh, J. Electroanal. Chem. 144, 69 (1983).

    Article  CAS  Google Scholar 

  104. J. M. Saveant, J. Phys. Chem. 92, 4526 (1988).

    Article  Google Scholar 

  105. S. M. Oh and L. R. Faulkner, J. Electroanal. Chem. 269, 77 (1989).

    Article  CAS  Google Scholar 

  106. R. W. Murray, in Electroanalytical Chemistry, vol. 13 ( A. J. Bard, ed.) ( Dekker, New York, 1983 ), p. 191.

    Google Scholar 

  107. R. C. Bowers and R. W. Murray, Anal. Chem. 38, 461 (1966).

    Article  CAS  Google Scholar 

  108. D. Ghesquiere, B. Ban, and C. Chachaty, Macromolecules 10, 743 (1977).

    Article  CAS  Google Scholar 

  109. D. R. Rillema, D. S. Jones, and H. A. Levy, J. Chem. Soc., Chem. Commun. 849 (1979).

    Google Scholar 

  110. R. Lange and K. Doblhofer, J. Electroanal. Chem. 237, 13 (1987).

    Article  CAS  Google Scholar 

  111. R. J. Forster, Ph.D. diss. Dublin City University, 1990.

    Google Scholar 

  112. T. Ohsaka, N. Oyama, S. Yamaguchi, and H. Matsuda, Bull. Chem. Soc. Jpn. 54, 2475 (1981).

    Article  CAS  Google Scholar 

  113. K. J. Vetter, Electrochemical Kinetics ( Academic Press, New York and London, 1987 ), p. 107.

    Google Scholar 

  114. H. Matsuda, Bull. Chem. Soc. Jpn. 53, 3439 (1980).

    Article  CAS  Google Scholar 

  115. M. J. Weaver, J. Phys. Chem. 83, 2645 (1976).

    Google Scholar 

  116. E. L. Lee, R. J. Cave, K. L. Guyer, P. D. Tyma, and M. J. Weaver, J. Am. Chem. Soc. 101, 1131 (1979).

    Article  Google Scholar 

  117. J. T. Hupp and M. J. Weaver, J. Electroanal. Chem. 131, 619 (1984).

    Article  CAS  Google Scholar 

  118. E. L. Lee and M. J. Weaver, Inorg. Chem. 19, 1077 (1980).

    Article  Google Scholar 

  119. M. E. G. Lyons, H. G. Fay, T. McCabe, J. Corrish, J. G. Vos, and A. J. Kelly, J. Chem. Soc. Faraday Trans. 86, 2905 (1990).

    Article  CAS  Google Scholar 

  120. C. E. D. Chidsey and R. W. Murray, Science 231, 25 (1986).

    Article  CAS  Google Scholar 

  121. R. Daum and R. W. Murray, J. Phys. Chem. 85, 389 (1981).

    Article  CAS  Google Scholar 

  122. S. M. Oh and L. R. Faulkner, J. Am. Chem. Soc. 111, 5613 (1989).

    Article  CAS  Google Scholar 

  123. D. Leech, Ph.D. diss. Dublin City University, 1991.

    Google Scholar 

  124. S. Yamaguchi, H. Matsuda, T. Ohsaka, and N. Oyama, Bull. Chem. Soc. Jpn. 56, 2952 (1983).

    Article  CAS  Google Scholar 

  125. T. Ohsaka, T. Okajima, and N. Oyama, J. Electroanal. Chem. 215, 191 (1986).

    Article  CAS  Google Scholar 

  126. T. Ohsaka, S. Kunimura, and N. Oyama, Electrochim. Acta 33, 639 (1983).

    Article  Google Scholar 

  127. C. Amatore, J. M. Saveant, and D. Tessier, J. Electroanal. Chem. 146, 37 (1983).

    Article  CAS  Google Scholar 

  128. T. Ohsaka, H. Yamamoto, and N. Oyama, J. Phys. Chem. 91, 3775 (1987).

    Article  CAS  Google Scholar 

  129. A. P. Clarke, J. G. Vos, A. Glidle, and A. R. Hillman, J. Chem. Soc. Faraday Trans. 89, 1695 (1993).

    Article  CAS  Google Scholar 

  130. A. P. Clarke, Ph.D. diss. Dublin City University, 1992.

    Google Scholar 

  131. A. R. Hillman, D. C. Loveday, M. J. Swann, S. Bruckenstein, and C. P. Wilde, J. Chem. Soc. Faraday Trans. 87, 2047 (1991).

    Article  CAS  Google Scholar 

  132. S. Bruckenstein and A. R. Hillman, J. Phys. Chem. 92, 4837 (1988).

    Article  CAS  Google Scholar 

  133. S. Bruckenstein and M. Shay, Electrochim. Acta 30, 1295 (1985).

    Article  CAS  Google Scholar 

  134. D. Orata and D. A. Buttry, J. Am. Chem. Soc. 109, 3574 (1987).

    Article  CAS  Google Scholar 

  135. M. R. Deakin and D. A. Buttry, Anal. Chem. 61, 1147A (1989).

    Article  CAS  Google Scholar 

  136. C. Lu and A. W. Czanderna, eds., Applications of Piezoelectric Crystal Microbalances, vol. 7 ( Elsevier, New York, 1984 ).

    Google Scholar 

  137. D. A. Buttry, in Electroanalytical Chemistry, vol. 17 ( A. J. Bard, ed.) ( Marcel Dekker, New York, 1991 ), p. 1.

    Google Scholar 

  138. A. R. Hillman, M. J. Swann, and S. Bruckenstein, J. Phys. Chem. 95, 3271 (1991).

    Article  CAS  Google Scholar 

  139. A. Glidle, A. R. Hillman, and S. Bruckenstein, J. Electroanal. Chem. 318, 411 (1991).

    Article  CAS  Google Scholar 

  140. G. Sauerbrey, Z. Phys. 155, 206 (1959).

    Article  CAS  Google Scholar 

  141. G. S. Ostrom and D. A. Buttry, J. Electroanal. Chem. 256, 411 (1988).

    Article  CAS  Google Scholar 

  142. G. Inzelt and J. Bacskai, Electrochim. Acta 37, 647 (1992).

    Article  CAS  Google Scholar 

  143. W. D. Hinsburg and K. K. Kanazawa, Rev. Sci. Instrum. 60, 489 (1989).

    Article  Google Scholar 

  144. A. R. Hillman, R. M. Eales, D. C. Loveday, M. J. Swann, A. Hamnet, S.J. Higgins, S. Bruckenstein, and C. P. Wilde, Faraday Discuss. Chem. Soc. 88, 151 (1989).

    Article  CAS  Google Scholar 

  145. A. R. Hillman, D. C. Loveday, M. J. Swann, and S. Bruckenstein, J. Chem. Soc. Faraday Trans. 86, 233 (1990).

    Article  Google Scholar 

  146. A. R. Hillman, D. C. Loveday, and S. Bruckenstein, J. Electroanal. Chem. 274, 157 (1989).

    Article  CAS  Google Scholar 

  147. S. Bruckenstein, C. P. Wilde, M. Shay, A. R. Hillman, and D. C. Loveday, J. Electroanal. Chem. 258, 457 (1989).

    Article  CAS  Google Scholar 

  148. A. R. Hillman, D. C. Loveday, S. Bruckenstein, and C. P. Wilde, J. Chem. Soc. Faraday Trans. 86, 437 (1990).

    Article  CAS  Google Scholar 

  149. M. D. Ward, J. Electrochem. Soc. 135, 2747 (1988).

    Article  CAS  Google Scholar 

  150. M. D. Ward, J. Phys. Chem. 92, 2049 (1988).

    Article  Google Scholar 

  151. P. T. Varineau and D. A. Buttry, J. Phys. Chem. 91, 1292 (1987).

    Article  CAS  Google Scholar 

  152. A. J. Kelly, T. Ohsaka, N. Oyama, R. J. Forster, and J. G. Vos, J. Electroanal. Chem. 287, 185 (1990).

    Article  CAS  Google Scholar 

  153. A. J. Kelly and N. Oyama, J. Phys. Chem. 95, 9579 (1991).

    Article  CAS  Google Scholar 

  154. A. R. Hillman, N. A. Hughes, and S. Bruckenstein, J. Electrochem. Soc. 139, 74 (1992).

    Article  CAS  Google Scholar 

  155. G. Inzelt, J. Electroanal. Chem. 287, 171 (1990).

    Article  CAS  Google Scholar 

  156. G. Inzelt and J. Bacskai, J. Electroanal. Chem. 308, 255 (1991).

    Article  CAS  Google Scholar 

  157. R. Borjas and D. A. Buttry, J. Electroanal. Chem. 280, 73 (1990).

    Article  CAS  Google Scholar 

  158. T. Kawai, T. Kuwabara, S. Wang, and K. Yoshino, J. Electrochem. Soc. 137, 3793 (1990).

    Article  CAS  Google Scholar 

  159. S. Gottesfeld, A. Redonda, I. Rubinstein, and S. W. Feldberg, J. Electroanal. Chem. 265, 15 (1989).

    Article  CAS  Google Scholar 

  160. A. P. Clarke, J. G. Vos, and A. R. Hillman, J. Electroanal. Chem. 356, 287 (1993).

    Article  CAS  Google Scholar 

  161. A. R. Hillman, D. C. Loveday, and S. Bruckenstein, Langmuir7, 191 (1991).

    Google Scholar 

  162. B. A. Martin and H. E. Hager, J. Appl. Phys. 65, 2627 (1989).

    Article  Google Scholar 

  163. S. Bruckenstein, C. P. Wilde, M. Shay, and A. R. Hillman, J. Phys. Chem. 94, 787 (1990).

    Article  CAS  Google Scholar 

  164. S. Bruckenstein, A. R. Hillman, and M. J. Swann, J. Electrochem. Soc. 137, 1323 (1990).

    Article  CAS  Google Scholar 

  165. G. E. Walrafen, J. Chem. Phys. 52, 4176 (1970).

    Article  Google Scholar 

  166. G. Inzelt, R. W. Day, J. F. Kinstle, and J. Q. Chambers, J. Electroanal. Chem. 161, 147 (1984).

    Article  CAS  Google Scholar 

  167. P. Joo and J. Q. Chambers, J. Electrochem. Soc. 132, 1345 (1985).

    Article  CAS  Google Scholar 

  168. H. P. Gregor, J. Belle, and R. A. Marcus, J. Am. Chem. Soc. 76, 1984 (1954).

    Article  CAS  Google Scholar 

  169. R. Naegali, J. Redepenning, and F. C. Anson, J. Phys. Chem. 90, 6227 (1986).

    Article  Google Scholar 

  170. J. Koryta and J. Dvorak, Principles of Electrochemistry ( Wiley, New York, 1987 ).

    Google Scholar 

  171. S. B. Tuwiner, Diffusion and Membrane Technology ( Chapman and Hall, New York, 1962 ).

    Google Scholar 

  172. R. Schumacher, G. Borges, and K. K. Kanazawa, Surf. Sci. 163, L621 (1985).

    Article  CAS  Google Scholar 

  173. R. Schumacher, J. G. Gordon, and O. Melroy, J. Electroanal. Chem. 216, 127 (1987).

    Article  CAS  Google Scholar 

  174. R. Beck, U. Pittermann, and K. G. Weil, J. Electrochem. Soc. 139, 453 (1992).

    Article  CAS  Google Scholar 

  175. Y. Marcus, Ion Solvation ( Wiley-Interscience, New York, 1985 ).

    Google Scholar 

  176. F. Helfferich, Ion Exchange ( McGraw-Hill, New York, 1962 ).

    Google Scholar 

  177. H. P. Gregor, J. Am. Chem. Soc. 73, 642 (1951).

    Article  Google Scholar 

  178. R. W. Murray, A. G. Ewing, and R. A. Durst, Anal. Chem. 59, 379A (1987).

    CAS  Google Scholar 

  179. F. C. Anson, J. Phys. Chem. 84, 3336 (1980).

    Article  Google Scholar 

  180. D. A. Buttry and F. C. Anson, J. Am. Chem. Soc. 106, 59 (1984).

    Article  CAS  Google Scholar 

  181. D. C. Bookbinder and M. S. Wrighton, J. Am. Chem. Soc. 102, 5123 (1980).

    Article  CAS  Google Scholar 

  182. H. D. Abruna and A. J. Bard, J. Am. Chem. Soc. 103, 6898 (1981).

    Article  CAS  Google Scholar 

  183. H. Akahoshi, S. Toshima, and K. Itaya, J. Phys. Chem. 85, 818 (1982).

    Article  Google Scholar 

  184. Z. Zhang and W. R. Seitz, Anal. Chim. Acta 160, 47 (1984).

    Article  CAS  Google Scholar 

  185. C. K. Chiang, Polymer 22, 1454 (1981).

    Article  Google Scholar 

  186. T. Ohsaka, K. Naoi, S. Ogano, and S. Nakamura, J. Electrochem. Soc. 134, 2096 (1987).

    Article  Google Scholar 

  187. C. E. D. Chidsey and R. W. Murray, J. Phys. Chem. 90, 1479 (1986).

    Article  CAS  Google Scholar 

  188. R. J. Forster and J. G. Vos, in Comprehensive Analytical Chemistry,vol. 27 (M. R. Smyth and J. G. Vos, eds.) (Elsevier, Amsterdam, 1992), chap. 7.

    Google Scholar 

  189. L. R. Faulkner, Chem. Eng. News 62, 28 (1984).

    Google Scholar 

  190. R. W. Murray, Phil. Trans. R. Soc. Lond. 302, 253 (1981).

    Article  Google Scholar 

  191. W. J. Albery and A. R. Hillman, Ann. Rep. Prog. Chem. C78, 377 (1981).

    Article  Google Scholar 

  192. W. J. Albery, A. W. Foulds, K. J. Hall, and A. R. Hillman, J. Electrochem. Soc. 127, 654 (1980).

    Article  CAS  Google Scholar 

  193. W. J. Albery and A. R. Hillman, J. Electroanal. Chem. 170, 27 (1984).

    Article  CAS  Google Scholar 

  194. W. J. Albery, W. R. Bowen, F. S. Fisher, A. W. Foulds, K. J. Hall, A. R. Hillman, R. G. Edgell, and A. F. Orchard, J Electroanal. Chem. 107, 37 (1980).

    Article  CAS  Google Scholar 

  195. C. P. Andrieux, J. M. Dumas-Bouchiat, and J. M. Saveant, J. Electroanal. Chem. 131, 1 (1982).

    Article  CAS  Google Scholar 

  196. C. P. Andrieux, J. M. Dumas-Bouchiat, and J. M. Saveant, J. Electroanal. Chem. 169, 9 (1984).

    Article  CAS  Google Scholar 

  197. C. P. Andrieux and J. M. Saveant, J. Electroanal. Chem. 171, 65 (1984).

    Article  CAS  Google Scholar 

  198. C. P. Andrieux and J. M. Saveant, J. Electroanal. Chem. 142, 1 (1982).

    Article  CAS  Google Scholar 

  199. C. P. Andrieux and J. M. Saveant, J. Electroanal. Chem. 134, 163 (1982).

    Article  CAS  Google Scholar 

  200. A. P. Doherty, R. J. Forster, M. R. Smyth, and J. G. Vos, Anal. Chem. 64, 572 (1992).

    Article  CAS  Google Scholar 

  201. R. J. Forster and J. G. Vos, J. Chem. Soc. Faraday Trans. 87, 1863 (1991).

    Article  CAS  Google Scholar 

  202. A. P. Doherty and J. G. Vos, J. Chem. Soc. Faraday Trans. 88, 2903 (1992).

    Article  CAS  Google Scholar 

  203. C. R. Andrieux, O. Haas, and J. M. Saveant, J. Am. Chem. Soc. 108, 8175 (1986).

    Article  CAS  Google Scholar 

  204. A. R. Doherty, T. Buckley, D. Kelly, and J. G. Vos, Electroanalysis 6, 553 (1994).

    Article  CAS  Google Scholar 

  205. H. Larsson and M. Sharp, J Electroanal. Chem. 381, 133 (1995).

    Article  Google Scholar 

  206. M. Sharp and H. Larsson, J. Electroanal. Chem. 386, 189 (1995).

    Article  Google Scholar 

  207. M. F. Mathias and O. Haas, J Phys. Chem. 97, 9271 (1993).

    Article  Google Scholar 

  208. A. P. Doherty and J. G. Vos, Anal. Chem. 85, 3424 (1993).

    Article  Google Scholar 

  209. A. P. Doherty, M. A. Stanley, G. Arana, C. E. Koning, R. H. G. Brinkhuis, and J. G. Vos, Electroanalysis 4, 333 (1995).

    Article  Google Scholar 

  210. D. M. Kelly and J. G. Vos, Electrochim. Acta in press (1996).

    Google Scholar 

  211. A. R. Hillman, D. C. Loveday, A. Glidle, J. G. Vos, A. P. Clarke, D. Kelly, and S. Bruckenstein, Macromol. Symp. 80, 323 (1994).

    Article  CAS  Google Scholar 

  212. A. P. Clarke, J. G. Vos, A. R. Hillman, and A. Glidle, J. Electroanal. Chem. 389, 129 (1995).

    Article  Google Scholar 

  213. A. P. Clarke, J. G. Vos, H. L. Bradley, and A. R. Hillman, J. Phys. Chem. 99, 15973 (1995).

    Article  CAS  Google Scholar 

  214. B. A. Gregg and A. Heller, J. Phys. Chem. 95, 5970 (1991).

    Article  CAS  Google Scholar 

  215. B. A. Gregg and A. Heller, J. Phys. Chem. 95, 5976 (1991).

    Article  CAS  Google Scholar 

  216. B. A. Gregg and A. Heller, Anal. Chem. 62, 258 (1990).

    Article  CAS  Google Scholar 

  217. A. Heller, J. Phys. Chem. 96, 3579 (1992).

    Article  CAS  Google Scholar 

  218. A. Aoki, R. Rajagopalan, and A. Heller, J. Phys. Chem. 99, 5102 (1995).

    Article  CAS  Google Scholar 

  219. A. P. Doherty, M. A. Stanley, and J. G. Vos, Analyst 120, 2371 (1995).

    Article  CAS  Google Scholar 

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  1. School of Chemical Sciences, Dublin City University, Dublin 9, Ireland

    David M. Kelly & Johannes G. Vos

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  1. David M. Kelly
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  1. Trinity College, University of Dublin, Dublin, Ireland

    Michael E. G. Lyons

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Kelly, D.M., Vos, J.G. (1996). Osmium and Ruthenium Poly(pyridyl) Redox Polymers as Electrode Coatings. In: Lyons, M.E.G. (eds) Electroactive Polymer Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-1715-7_4

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