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Atomic Clusters in the Gas Phase

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Gas Phase Inorganic Chemistry

Part of the book series: Modern Inorganic Chemistry ((MICE))

Abstract

Atomic clusters are systems represented by the simple chemical symbol A N , where A is the identity of the atom and N is the number of atoms constituting the cluster. They are related on one front (small N) to the variegated atoms and homonuclear diatomics, on another front to bulk elemental solids and liquids, and on yet another to the behavior of interfaces, since a high fraction of their atoms must be at the cluster surface.

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References

  1. Sugano, S., Nishina, Y., Ohnishi, S., Microclusters; Eds. Springer: New York, 1987.

    Google Scholar 

  2. Jena, P., Rao, B.K.; Khana, S.N., Eds. Physics and Chemistry of Small Clusters ,NATO-ASI Series No. 158; Plenum: New York, 1987.

    Google Scholar 

  3. Jena, P., Rao, B.K.; Khana, S.N.,J. Phys. Chem. 1987, 91(10).

    Google Scholar 

  4. Jena, P., Rao, B.K.; Khana, S.N.,Chem. Rev. 1986, 86(3).

    Google Scholar 

  5. Jena, P., Rao, B.K.; Khana, S.N.,. Z. Phys. D 1986, 3(2/3).

    Google Scholar 

  6. Jena, P., Rao, B.K.; Khana, S.N.,Surf. Sci. 1985, 156.

    Google Scholar 

  7. Jena, P., Rao, B.K.; Khana, S.N., Ber. Bunsenges. Phys. Chem. 1984, 88(3).

    Google Scholar 

  8. See, for example, Moskovits, M. Ed. Metal Clusters; Wiley: New York, 1986

    Google Scholar 

  9. Johnson, B.F.G., Ed. Transition Metal Clusters; Wiley: New York, 1980.

    Google Scholar 

  10. Muetterties, E.L., Burch, R.R.; Stolzenberg, A.M. Annu. Rev. Phys. Chem. 1982, 33 ,89.

    CAS  Google Scholar 

  11. Echt, O.; Sattler, K.; Recknagel, E. Phys. Rev. Lett. 1981, 47 ,1121.

    CAS  Google Scholar 

  12. Sattler, K.; Mühlbach, J.; Echt, O.; Pfau, P.; Recknagel, E. Phys. Rev. Lett. 1981, 47 ,160.

    CAS  Google Scholar 

  13. Knight, W.D.; Clemenger, K.; deHeer, W.A., Saunders, W.A., Chou, M.Y., Cohen, M.L. Phys. Rev. Lett 1984, 52 ,2141.

    CAS  Google Scholar 

  14. Cohen, M.L.; Chou, M.Y.; Knight, W.D.; deHeer, W.A. J. Phys. Chem. 1981, 91 ,3141

    Google Scholar 

  15. deHeer, W.A.; Knight, W.P.; Chou, M.Y.; Cohen, M.L. Solid State Phys. 1987, 40 ,94.

    Google Scholar 

  16. Cox, D.M., Trevor, D.J., Whetten, R.L.; Rohlfing, E.A.; Kaldor, A. Phys. Rev. B 1985, 32 ,7290.

    CAS  Google Scholar 

  17. Cox, D.M.; Trevor, D.J.; Whetten, R.L.; Rohlfing, E.A.; Kaldor, A. J. Chem. Phys. 1986, 84 ,4651.

    CAS  Google Scholar 

  18. Whetten, R.L.; Cox, D.M.; Trevor, D.J.; Kaldor, A. Phys. Rev. Lett. 1985, 54 ,1494.

    CAS  Google Scholar 

  19. Whetten, R.L., Zakin, M.R., Cox, D.M., Trevor, D.J.; Kaldor, A. J. Chem. Phys. 1987, 85,1697.

    Google Scholar 

  20. Geusic, M.E.; Morse, M.D.; Smalley, R.E. J. Chem. Phys. 1985, 82 ,590.

    CAS  Google Scholar 

  21. Zhang, Q.L.; O’Brien, S.C.; Heath, J.R.; Liu, Y.; Curl, R.F.; Kroto, H.W., Smalley, R.E. J. Phvs. Chem. 1986, 90 ,525.

    CAS  Google Scholar 

  22. Cox, D.M., Trevor, D.J.; Whetten, R.L.; Kaldor, A. J. Phys. Chem. 1988, 92 ,421.

    CAS  Google Scholar 

  23. Kubo, R.; Kawabata, A.; Kobayashi, S. Annu. Rev. Mater. Sci. 1984, 14 ,49

    CAS  Google Scholar 

  24. Halperin, W. P. Rev. Mod. Phys. 1986, 58 ,533.

    CAS  Google Scholar 

  25. Abraham, D.W.; Sattler, K.; Ganz, E.; Mamin, H.J., Thomson, R.E.; Clarke, J. Appl. Phys. Lett. 1986, 49 ,853.

    CAS  Google Scholar 

  26. Binder, K.; Stauffer, D. In Topics in Current Physics 7 ,“Monte Carlo Methods in Statistical Physics”, Binder, K. Ed.; Springer-Verlag: New York, 1979.

    Google Scholar 

  27. Koutecký, J.; Fantucci, P. Chem. Rev. 1986, 86 ,539.

    Google Scholar 

  28. Car, R., Parinello, M. Phys. Rev. Lett. 1985, 55 ,2471.

    CAS  Google Scholar 

  29. Car, R.; Parinello, M.; Andreoni, W. Microclusters; Sugano, S.; Nishina, Y., Ohnishi, S., Eds.; Springer-Verlag: New York, 1987

    Google Scholar 

  30. Farges, J.; DeFeraudy, M.F.; Raoult, B.; Torchet, G. J. Chem. Phys. 1983, 78 ,5067

    CAS  Google Scholar 

  31. Fu, C.L.; Freeman, A.J.; Oguchi, T. Phys. Rev. Lett. 1985, 54 ,2700, and references therein.

    CAS  Google Scholar 

  32. Brown, W.L.; Freeman, R.R.; Raghavachari, K.; Schlüter M. Science 1987, 235 ,860.

    CAS  Google Scholar 

  33. Bernholc, J.; Phillips, J.C. J. Chem. Phys. 1986, 85 ,3258.

    CAS  Google Scholar 

  34. Bauer, S.H.; Frurip, D.J. J. Phys. Chem. 1977, 81 ,1015, and references therein.

    CAS  Google Scholar 

  35. Dietz, T.G.; Duncan, M.A.; Powers, D.E.; Smalley, R.E. J. Chem. Phys. 1981, 74 ,6511

    CAS  Google Scholar 

  36. Soler, J.M.; Garcia, N.; Echt, O.; Sattler, K.; Recknagel, E. Phys. Rev. Lett. 1982, 49 ,1857.

    CAS  Google Scholar 

  37. Ryali, S.B.; Fenn, J.B. Ber. Bunsenges. Phys. Chem. 1984, 88 ,245.

    CAS  Google Scholar 

  38. LaiHing, K.; Wheeler, R.G.; Wilson, W.L., Duncan, M.A. J. Chem. Phys. 1987, 87 ,3401.

    CAS  Google Scholar 

  39. Whetten, R.L.; Cox, D.M.; Trevor, D.J.; Kaldor, A. J. Phys. Chem. 1985, 89 ,566.

    CAS  Google Scholar 

  40. Geusic, M.E.; Morse, M.D.; O’Brien, S.C.; Smalley, R.E. Rev. Sci. Instrum ,1985, 56 ,2123.

    CAS  Google Scholar 

  41. See Chapter 9 in this volume.

    Google Scholar 

  42. Loh, S.K., Hales, D.A.; Armentrout, P.B. Chem. Phys. Lett. 1986, 129 ,527.

    CAS  Google Scholar 

  43. Herrman, A.; Schumacher, E.; Wöste, L. J. Chem. Phys. 1978, 68 ,2327.

    Google Scholar 

  44. Bahat, D., Cheshnovsky, O.; Even, U.; Lavie, N; Magen, Y. J. Phys. Chem. 1987, 91 ,2460, and references therein.

    CAS  Google Scholar 

  45. Doll, J.D., Freeman, D.L. Science 1986, 234 ,1356.

    CAS  Google Scholar 

  46. Clemenger, K. Ph.D. thesis, University of California, Berkeley, 1984, (unpublished). See Reference 12 also.

    Google Scholar 

  47. Kappes, M.M., Schär, M., Radi, P.; Schumacher, E. J. Chem. Phys. 1986, 84 ,1863.

    CAS  Google Scholar 

  48. Walstedt, R.E., Bell, R.F. J. Chem. Phys. 1987, 87 ,1423.

    CAS  Google Scholar 

  49. Ramsey, N.F. Molecular Beams; Oxford University Press: Oxford, 1956.

    Google Scholar 

  50. Morse, M.D., Hopkins, J.B., Langridge-Smith, P.R.R., Smalley, R.E. J. Chem. Phys. 1983 79 ,5316.

    CAS  Google Scholar 

  51. Delacrétaz, G., Wöste, L. Surf. Sci. 1985, 156 ,770

    Google Scholar 

  52. Broyer, M., Delacrétaz, G., Labastie, P. Whetten, R.L., Wolf, J.P., Wöste, L. Z Phys. D 1986, 3 ,131.

    CAS  Google Scholar 

  53. Alexander, M.L., Johnson, M.A., Levinger, N.E.; Lineberger, W.C. Phys. Rev. Lett. 1986 57 ,976.

    CAS  Google Scholar 

  54. deHeer, W.A., Selby, K., Kresin, V.; Masui, S., Vollmer, M.; Châtelain, A.; Knight, W.D Phys. Rev. Lett. 1987, 59 ,1805.

    CAS  Google Scholar 

  55. Leopold, D.G., Murray, K.K., Miller, A.E.S., Lineberger, W.C. J. Chem. Phys. 1985, 85 4849

    Google Scholar 

  56. Cheshnovsky, O., Yang, S.H., Pettiette, C.L., Craycraft, M.J., Liu, Y.; Smalley, R.E. Chem Phys. Lett. 1987, 138 ,119

    Google Scholar 

  57. Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H. J. Chem. Phys 1986, 84 ,618.

    CAS  Google Scholar 

  58. Richtsmeier, S.C.; Parks, E.K.; Liu, K.; Pobo, L.G.; Riley, S.J. J. Chem. Phys. 1985, 82 ,3659

    CAS  Google Scholar 

  59. Upton, T.H.; Phys. Rev. Lett. 1986, 56 ,2168

    CAS  Google Scholar 

  60. Clemenger, K. Phys. Rev. B 1985, 32 ,1359.

    CAS  Google Scholar 

  61. See, for example, Phillips, J.C. Chem. Rev. 1986, 86 ,619.

    CAS  Google Scholar 

  62. Saunders, W.A. Ph.D. thesis, University of California, Berkeley, 1986, (unpublished).

    Google Scholar 

  63. Knight, W.D.; deHeer, W.A.; Saunders, W.A. Z. Phys. D 1986, 3 ,109.

    CAS  Google Scholar 

  64. Saunders, W.A.; Clemenger, K.; deHeer, W.A.; Knight, W.D. Phys. Rev. B 1985, 32 ,1366

    CAS  Google Scholar 

  65. Schriver, K.E., Persson, J.L., Honea, E.C.; Whetten, R.L. To be submitted.

    Google Scholar 

  66. Fuke, K.; Nonose, Sh., Kikuchi, N.; Kaya, K. Chem. Phys. Lett. 1988, 147 ,479.

    CAS  Google Scholar 

  67. Bowen, K.H.; Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; Hugh, K.M.; Eaton, J.; Lee, G In preparation.

    Google Scholar 

  68. Begemann, W.; Dreihöfer, S.; Ganteför, G.; Siekmann, H.R.; Meiwes-Broer, K.-H.; Lutz, H.O. In Elemental and Molecular Clusters; Martin, T.P., Ed.; Springer-Verlag: New York, 1987.

    Google Scholar 

  69. Martins, J.L.; Buttet, J.; Car, R. Phys. Rev. B 1985, 31 ,1804.

    CAS  Google Scholar 

  70. Knight, W.D.; Clemenger, K.; deHeer, W.A.; Saunders, W.A. Phys. Rev. B 1985, 31 ,2539.

    CAS  Google Scholar 

  71. Schriver, K.E.; Whetten, R.L. In preparation.

    Google Scholar 

  72. Knight, W.D.; Monot, R.; Dietz, E.R.; George, A.R. Phys. Rev. Lett. 1978, 40 ,1324

    CAS  Google Scholar 

  73. Broyer, M.; Delacrétaz, G.; Labastie, P.; Wolf, J.P.; Wöste, L. Phys. Rev. Lett. 1986, 57 ,1851

    CAS  Google Scholar 

  74. Fu, Z.; Lemire, G.W.; Hamrick, Y.M.; Taylor, S.; Shui, J.-C.; Morse, M.D. J. Chem. Phys ,1988, 88 ,3524.

    CAS  Google Scholar 

  75. Bréchignac, C.; Cahouzac, Ph. Z Phys. D 1986, 3 ,121

    Google Scholar 

  76. Bréchignac, C.; Cahouzac, Ph.; Roux, J. Ph. J. Chem. Phys. 1987, 87 ,229.

    Google Scholar 

  77. Jarrold, M.F.; Bower, J.E. J. Chem. Phys. 1986, 85 ,5373

    CAS  Google Scholar 

  78. Jarrold, M.F.; Bower, J.E. J. Am. Chem. Soc. 1988, 110 ,70.

    CAS  Google Scholar 

  79. Hanley, L.; Anderson, S.L. Chem. Phys. Lett. 1986, 129 ,429

    CAS  Google Scholar 

  80. Ruatta, S.A.; Hanley, L.; Anderson, S.L. ibid. 1987, 137, 5.

    CAS  Google Scholar 

  81. Hanley, L.; Ruatta, S.A.; Anderson, S.L. J. Chem. Phys. 1987, 87 ,260.

    CAS  Google Scholar 

  82. Jarrold, M.F.; Bower, J.E.; Kraus, J.S. J. Chem. Phys. 1987, 86 ,3876

    CAS  Google Scholar 

  83. Jarrold, M.F.; Bower, J.E. J. Chem. Phys. 1987, 87 ,1610.

    CAS  Google Scholar 

  84. Hanley, L.; Anderson, S.L. J. Phys. Chem. 1987, 91 ,5161.

    CAS  Google Scholar 

  85. Katakuse, I.; Ichihara, T.; Fujita, Y.; Matsuo, T.; Sakurai, T.; Matsuda, H. Int. J. Masi Spectrom. Ion Proc. 1985, 67 ,229

    CAS  Google Scholar 

  86. Katakuse, I. In Microclusters; Sugano, S.; Nishini, Y.; Ohnishi, S., Eds.; Springer-Verlag: New York, 1987.

    Google Scholar 

  87. Turkevich, L.A.; Cohen, M.H. Phys. Rev. Lett. 1984, 53 ,2323.

    CAS  Google Scholar 

  88. Rademann, K.; Kaiser, B., Even, U.; Hensel, F. Phys. Rev. Lett. 1987, 59 ,2319.

    CAS  Google Scholar 

  89. Powers, D.E.; Hansen, S.G., Geusic, M.E., Michalopoulos, D.L.; Smalley, R.E. J. Chem. Phys. 1983, 78 ,2866.

    CAS  Google Scholar 

  90. Zheng, L.-S.; Karner, CM.; Brucat, P.J.; Yang, S.H., Pettiette, C.L.; Craycraft, M.J.; Smalley, R.E. J. Chem. Phys. 1986, 85 ,1681.

    CAS  Google Scholar 

  91. Bréchignac, C., Broyer, M., Cahuzac, Ph.; Delacrétaz, G., Labastie, P.; Wöste, L. Chem. Phys. Lett. 1985, 120 ,559.

    Google Scholar 

  92. Bréchignac, C.; Broyer, M.; Cahuzac, Ph.; Delacrétaz, G.; Labastie, P.; Wolf, J.P.; Wöste, L. Phys. Rev. Lett. 1988, 60 ,275.

    Google Scholar 

  93. Leopold, D.G.; Ho, J.; Lineberger, W.C. J. Chem. Phys. 1987, 86 ,1715.

    CAS  Google Scholar 

  94. Pettiette, C.L.; Yang, S.H.; Craycraft, M.J.; Conceicao, J.; Laaksonen, R.T.; Cheshnovsky, O.; Smalley, R.E. J. Chem. Phys. 1988, 88 ,5377.

    CAS  Google Scholar 

  95. Cox, D.M.; Reichmann, K.C.; Trevor, D.J.; Kaldor, A. J. Chem. Phys. 1988, 88 ,111.

    CAS  Google Scholar 

  96. Kaldor, A.; Cox, D.M.; Zakin, M.R. Adv. Chem. Phys. (in press).

    Google Scholar 

  97. Whetten, R.L.; Cox, D.M., Trevor, D.J.; Kaldor, A. Surf. Sci. 1985, 156 ,8.

    CAS  Google Scholar 

  98. Morse, M.D. Chem. Rev. 1986, 86 ,1049.

    CAS  Google Scholar 

  99. Cox, D.M.; Whetten, R.L.; Zakin, M.R.; Trevor, DJ.; Reichmann, K.C.; Kaldor, A. In Advances in Laser Science-I ,Optical Science and Engineering Series ,6; Stwalley, W.C.; Lapp, M., Eds.; American Institute of Physics: New York, 1986.

    Google Scholar 

  100. Whetten, R.L.; Cox, D.M.; Zakin, M.R.; Trevor, D.J.; Kaldor, A. To be submitted.

    Google Scholar 

  101. Rohlfing, E.A.; Cox, D.M.; Kaldor, A.; Johnson, K.H. J. Chem. Phys. 1984, 81 ,3846.

    CAS  Google Scholar 

  102. Zakin, M.R.; Cox, D.M.; Whetten, R.L.; Trevor, D.J.; Kaldor, A. Chem. Phys. Lett. 1987, 135 ,223.

    CAS  Google Scholar 

  103. Lineberger, W.C. Private communication.

    Google Scholar 

  104. Morse, M.D.; Geusic, M.E.; Heath, J.R.; Smalley, R.E. J. Chem. Phys. 1985, 83 ,2293.

    CAS  Google Scholar 

  105. Brucat, P.J.; Pettiette, C.L.; Yang, S., Zheng, L.-S.; Craycraft, M.J.; Smalley, R.E. J. Chem. Phys. 1986, 85 ,4747.

    CAS  Google Scholar 

  106. Zakin, M.R.; Brickman, R.O.; Cox, D.M., Kaldor, A. J. Chem. Phys. 1988, 88 ,3555; ibid. 1988, 88 ,6605.

    CAS  Google Scholar 

  107. Elkind, J.L.; Weiss, F.D.; Alford, J.M.; Laaksonen, R.T.; Smalley, R.E. J. Chem. PhysA9S8 ,88 ,5215.

    Google Scholar 

  108. Smalley, R.E.; Acc. Chem. Res. (in press).

    Google Scholar 

  109. Saito, Y.; Yamauchi, K., Mihama, K.; Noda, T. Jpn. J. Appl. Phys. 1982, 21 ,L396.

    Google Scholar 

  110. Yang, S.; Taylor, K.J.; Craycraft, M.J.; Conceicao, J.; Pettiette, C.L., Cheshnovsky, O., Smalley, R.E. Chem. Phys. Lett. 1988, 144 ,431.

    CAS  Google Scholar 

  111. Douglas, A.E. Nature 1977, 269 ,130.

    CAS  Google Scholar 

  112. Heath, J.R.; Curl, R.F.; Smalley, R.E., J. Chem. Phys. 1987, 87 ,4236.

    CAS  Google Scholar 

  113. Yang, S.; Pettiette, C.L.; Conceicao, J.; Cheshnovsky, O.; Smalley, R.E. Chem. Phys. Lett. 1987, 139 ,233.

    CAS  Google Scholar 

  114. McElvaney, S.W.; Creasy, W.R.; O’Keefe, A. J. Chem. Phys. 1986, 85 ,632

    Google Scholar 

  115. McElvaney, S.W.; Dunlap, B.I.; O’Keefe, A. J. Chem. Phys. 1986, 86 ,715.

    Google Scholar 

  116. See, for example, Reents, W.D., Mandich, M.L.; Bondybey, V.E. Chem. Phys. Lett. 1986, 131 ,1.

    CAS  Google Scholar 

  117. Reents, W.D.; Mujsce, A.M.; Bondybey, V.E.; Mandich, M.L. J. Chem. Phys. 1987, 86 ,5568.

    CAS  Google Scholar 

  118. Elkind, J.L.; Alford, J.M.; Weiss, F.D.; Laaksonen, R.T.; Smalley, R.E. J. Chem. Phys. 1987, 87 ,2397.

    CAS  Google Scholar 

  119. Harris, T.A.; Kidwell, R.S.; Northby, J.A. Phys. Rev. Lett. 1984, 53 ,2390.

    CAS  Google Scholar 

  120. Levinger, N.E.; Ray, D.; Murray, K.K.; Mullin, A.S.; Schulz, C.P., Lineberger, W.C. J. Chem. Phys. 1988, 89 ,71; idem. To be published.

    CAS  Google Scholar 

  121. Buck, U.; Meyer, H. J. Chem. Phys. 1986, 84 ,4854.

    CAS  Google Scholar 

  122. Märk, T.D.; Scheier, P.; Leiter, K., Ritter, W.; Stephen, K.; Stamotovic, A. Int. J. Mass Spectrom. Ion Proc. 1986, 74 ,281.

    Google Scholar 

  123. Kreisle, D.; Echt, O.; Knapp, M.; Recknagel, E. Phys. Rev. A 1986, 33 ,768.

    CAS  Google Scholar 

  124. Lee, J.W.; Stein, G.D. J. Phys. Chem. 1987, 91 ,2450.

    CAS  Google Scholar 

  125. Buck, U. J. Phys. Chem. 1988, 92 ,1023.

    CAS  Google Scholar 

  126. Echt, O.; Cook, M.C.; Castleman, A.W., Jr. Chem. Phys. Lett. 1987, 135 ,229.

    CAS  Google Scholar 

  127. Hahn, M.Y.; Whetten, R.W. Unpublished.

    Google Scholar 

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Whetten, R.L., Schriver, K.E. (1989). Atomic Clusters in the Gas Phase. In: Russell, D.H. (eds) Gas Phase Inorganic Chemistry. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5529-8_6

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