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Techniques of Measuring Contact Angles

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Surface and Colloid Science

Abstract

The previous chapter was largely theoretical, in that it dealt with the interpretation of contact angle results in terms of solid surface energies. It also delved into the question of how the structure of a solid surface affects the contact angle that a liquid forms on the solid. The level of structure considered there included features that are not macroscopically observed, such as microheterogeneities, or minute peaks, pits, hills, and grooves in various geometries. Their existence may be inferred from certain observations, such as contact angle hysteresis, and sometimes they can be observed directly, e.g., with the optical or electron microscope.

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References

  1. H. W. Fox and W. A. Zisman, J. Colloid Sci. 5, 520 (1950).

    Google Scholar 

  2. W. A. Zisman, Advan. Chem. Ser. 43, (1964).

    Google Scholar 

  3. R. H. Ottewill, quoted by A. W. Adamson, The Physical Chemistry of Surfaces (3rd ed.), p. 343, Wiley Interscience, New York (1976).

    Google Scholar 

  4. R. J. Good, J. Colloid Interface Sci. 52, 308 (1975).

    Google Scholar 

  5. J. J. Bikerman, Surface Chemistry (2nd ed.), p. 343, Academic Press, New York (1958); Ind. Eng. Chem. Anal. Ed. 13, 443 (1941).

    Google Scholar 

  6. J. F. Padday, in Surface and Colloid Science (E. Matijevic, ed.), Vol. 1, p. 151, Wiley Interscience, New York (1969).

    Google Scholar 

  7. R. E. Baier, personal communication.

    Google Scholar 

  8. F. Neumann, Vorlesungen über die Theorie der Capillarität, B. G. Teubner, Leipzig (1893).

    Google Scholar 

  9. A. W. Neumann and R. J. Good, J. Colloid Interface Sci. 38, 341 (1972).

    CAS  Google Scholar 

  10. L. Boruvka and A. W. Neumann, J. Colloid Interface Sci. 65, 315 (1978).

    Google Scholar 

  11. G. McDougall and C. Ockrent, Proc. Roy. Soc. London A180, 151 (1942).

    Google Scholar 

  12. V. R. Gray, For. Prod. J. 12, 425 (1962); Chem. Ind. 969 (1965).

    Google Scholar 

  13. G. W. Longman and R. P. Palmer, J. Colloid Interface Sci. 29, 185 (1967).

    Google Scholar 

  14. G. J. Jameson and M. C. G. Del Cerro J. Chem. Soc. Faraday Trans. 172, 833 (1976).

    Google Scholar 

  15. P. S. de Laplace, Mechanique Celeste, Supplement to Book 10, J. B. M. Duprat, Paris (1806).

    Google Scholar 

  16. F. Bashforth and J. C. Adams, An Attempt to Test the Theory of Capillary Action, Cambridge University Press, Cambridge, England (1892).

    Google Scholar 

  17. C. A. Smolders, Ph.D. Thesis, Rijksuniversiteit, Utrecht (1961).

    Google Scholar 

  18. C. A. Smolders and J. Th. G. Overbeek, Rec. Tray. Chim. 80, 635 (1961).

    CAS  Google Scholar 

  19. R. Ehrlich, J. Colloid Interface Sci. 28, 5 (1968).

    Google Scholar 

  20. D. N. Staicopolus, J. Colloid Sci. 17, 439 (1962); 18, 793 (1963); 23, 453 (1967).

    Google Scholar 

  21. K. G. Parvatikar, J. Colloid Interface Sci. 23, 274 (1967).

    Google Scholar 

  22. E. Lefebre du Prey, Rev. Inst. Français Petrole, 701 (1969).

    Google Scholar 

  23. C. Maze and G. Burnet, Surface Sci. 13, 451 (1969).

    Google Scholar 

  24. J. F. Padday, Proc. Roy. Soc. London A330, 561 (1972).

    Google Scholar 

  25. J. F. Padday, J. Colloid Interface Sci. 48, 170 (1974).

    Google Scholar 

  26. R. S. Burdon, Surface Tension and the Spreading of Liquids, p. 15. Cambridge University Press, Cambridge, England (1949).

    Google Scholar 

  27. L. Wilhelmy, Ann. Physik 119, 177 (1863).

    Google Scholar 

  28. A. W. Neumann, Ph.D. Thesis, University of Mainz (1962); Z. Physik. Chem. N. F. 41, 339 (1964); 43, 71 (1964).

    CAS  Google Scholar 

  29. D. D. Jordan and J. E. Lane, Austral. J. Chem. 17, 7 (1964).

    CAS  Google Scholar 

  30. H. M. Princen, Austral. J. Chem. 23, 1789 (1970); J. Colloid Interface Sci. 30, 69 (1969); 30, 359 (1969).

    Google Scholar 

  31. J. Guastalla, J. Chim. Phys. 51, 583 (1954); II Intern. Congr. Surface Activity (London), Vol. 3, p. 143 (1957).

    Google Scholar 

  32. R. E. Johnson, Jr., and R. H. Dettre, in Surface and Colloid Science (E. Matijevic and F. R. Eirich, eds.), Vol. 2, p. 85, Academic Press, New York (1969).

    Google Scholar 

  33. H. M. Princen, in Surface and Colloid Science (E. Matijevic and F. R. Eirich, eds.), Vol. 2, p. 1, Academic Press, New York (1969).

    Google Scholar 

  34. W. Funke, G. E. H. Hellwig, and A. W. Neumann, Angew. Macromolec. Chem. 8, 185 (1969).

    CAS  Google Scholar 

  35. G. E. H. Hellwig and A. W. Neumann, Kolloid-Z. Z. Polym. 229, 40 (1969).

    CAS  Google Scholar 

  36. G. E. H. Hellwig and A. W. Neumann, Vlntern. Congr. Surface Activity, Barcelona, 1968, Vol. 2, p. 687, Ediciones Unidas (1969).

    Google Scholar 

  37. A. W. Neumann and D. Renzow, Z. Physik. Chem. N. F. 68, 11 (1969).

    Google Scholar 

  38. A. W. Neumann and W. Tanner, J. Colloid Interface Sci. 34, 1 (1970).

    CAS  Google Scholar 

  39. A. W. Neumann, Advan. Colloid Interface Sci. 4, 105 (1974).

    Google Scholar 

  40. A. C. Hardy and F. H. Perrin, The Principles of Optics, p. 130, McGraw-Hill, New York (1932).

    Google Scholar 

  41. G. L. Kehl, Principles of Metallographic Laboratory Practice, ( 3rd ed. ), McGraw-Hill, New York (1952).

    Google Scholar 

  42. A. J. T. Scarr, Metrology and Precision Engineering, Chapter 5, McGraw-Hill, New York (1967).

    Google Scholar 

  43. A. A. Michelson, J. Opt. Soc. Amer. Rev. Sci. Instr. 8 (1), 321 (1924).

    Google Scholar 

  44. A. A. Michelson, Studies in Optics, University of Chicago Press, Chicago (1927).

    Google Scholar 

  45. A. W. Neumann and W. Tanner, Tenside 4, 220 (1967).

    CAS  Google Scholar 

  46. J. Kloubek and A. W. Neumann, Tenside 6, 4 (1969).

    CAS  Google Scholar 

  47. N. K. Adam and G. Jessop. J. Chem. Soc. 1925, 1863 (1925).

    Google Scholar 

  48. N. K. Adam, The Physics and Chemistry of Surfaces ( 3rd ed. ), Oxford University Press, Oxford, England (1941).

    Google Scholar 

  49. F. M. Fowkes and W. D. Harkins, J. Amer. Chem. Soc. 62, 337 (1940).

    Google Scholar 

  50. A. L. Spreece, C. P. Rutkowski, and G. L. Gaines, Jr., Rev. Sci. Instr. 28, 636 (1957).

    Google Scholar 

  51. I. Langmuir and V. J. Schaeffer, J. Am. Chem. Soc. 59, 2400 (1937).

    CAS  Google Scholar 

  52. T. Fort, Jr., and H. T. Patterson, J. Colloid Sci. 18, 217 (1963).

    CAS  Google Scholar 

  53. R. J. Good and G. V. Ferry, Advan. Cryogen. Eng. 8, 306 (1963).

    CAS  Google Scholar 

  54. R. J. Good and J. K. Paschek, in Wetting, Spreading and Adhesion ( J. F. Padday, ed.), p. 147, Academic Press, New York (1978).

    Google Scholar 

  55. W. D. Harkins and A. E. Alexander, in Physical Methods of Organic Chemistry (A. Weissberger ed.) (3rd ed.), Vol I, part I, p. 757, Interscience, New York (1959).

    Google Scholar 

  56. F. E. Bartell and H. Y. Jennings, J. Phys. Chem. 38, 495 (1934).

    CAS  Google Scholar 

  57. E. W. Washburn, Phys. Rev. 17, 374 (1921).

    Google Scholar 

  58. R. J. Good, J. A. Kirkstad, and W. O. Bailey, J. Colloid Interface Sci. 35, 314 (1971).

    CAS  Google Scholar 

  59. C. Huh and L. E. Scriven, J. Colloid Interface Sci. 30, 323 (1969).

    Google Scholar 

  60. A. M. Schwartz and F. W. Minor, J. Colloid Sci. 14, 572 (1959).

    CAS  Google Scholar 

  61. A. M. Schwartz and C. A. Rader, IVth Intern. Congr. Surface Activity, Brussels, 1964, Vol. 2, p. 383, Gordon and Breach, New York (1964).

    Google Scholar 

  62. W. D. Bascom and J. B. Romans, Ind. Eng. Chem. Prod. Res. Develop. 7, 172 (1968).

    CAS  Google Scholar 

  63. R. J. Roe, J. Colloid Interface Sci. 50, 70 (1975).

    Google Scholar 

  64. B. J. Carroll, J. Colloid Interface Sci. 57, 488 (1976).

    Google Scholar 

  65. N. K. Adam and H. L. Schute, Symposium on Wetting and Detergency, 1937, p. 53, Chemical Publishing Company, New York (1937).

    Google Scholar 

  66. A. V. Rapacchietta, A. W. Neumann, and S. N. Omenyi, J. Colloid Interface Sci. 59, 541 (1977).

    Google Scholar 

  67. A. V. Rapacchietta and A. W. Neumann, J. Colloid Interface Sci. 59, 555 (1977).

    Google Scholar 

  68. A. W. Neumann and W. Tanner, Vth Internat. Conference on Surface Activity, Barcelona 1968, Vol. 2, p. 727, Ediciones Unidas, Barcelona (1969); A. W. Neumann, Chemie. Ing.-Tech. 42, 969 (1970).

    CAS  Google Scholar 

  69. W. C. Jones and M. C. Porter, J. Colloid Interface Sci. 24, 1 (1967).

    CAS  Google Scholar 

  70. E. Weber, Habilitationsschrift, University of Stuttgart (1968).

    Google Scholar 

  71. K. L. Wolf, Physik und Chemie der Grenzfíächen, Vol 2, p. 322, Springer, Heidelberg (1959).

    Google Scholar 

  72. T. Steudel, IVth International Congress Surface Activity, Brussels, 1969, Vol. 2, p. 1251, Gordon and Breach, New York (1964).

    Google Scholar 

  73. G. E. H. Hellwig and A. W. Neumann, Farbe Lack 73, 823 (1967).

    CAS  Google Scholar 

  74. H. Freundlich, O. Schmidt, and G. Lindau, Kolloid-Beiheft 36, 43 (1932).

    CAS  Google Scholar 

  75. H. Freundlich, O. Enslin, and G. Lindau, Kolloid-Beiheft 37, 242 (1933).

    CAS  Google Scholar 

  76. E. Sauer and W. Gussmann, Kolloid Z. 82, 253 (1938).

    CAS  Google Scholar 

  77. M. von Stackelberg and K. H. Frangen, Forschungsbericht des Landes Nordrhein-Westfalen, no. 166 (1955).

    Google Scholar 

  78. F. Kindervater, Farbe Lack 69, 21 (1965).

    Google Scholar 

  79. R. Shuttleworth and G. L. J. Bailey, Discuss Faraday Soc. 1948 (3), 16, (1948).

    Google Scholar 

  80. A. W. Neumann, D. Renzow, H. Reumuth, and I.-E. Richter, Fortschr. Kolloide Polym. 55, 49 (1971).

    CAS  Google Scholar 

  81. N. W. F. Kossen and P. M. Heertjes, Chem. Eng. Sci. 20, 593 (1965).

    CAS  Google Scholar 

  82. F. E. Bartell and H. J. Osterhof, Ind. Eng. Chem. 19, 1277 (1927).

    CAS  Google Scholar 

  83. F. E. Bartell and H. J. Osterhof, J. Phys. Chem. 34, 544 (1930); J. Phys. Chem. 37, 543 (1933).

    CAS  Google Scholar 

  84. F. E. Bartell and C. E. Whitney, J. Phys. Chem. 36, 3115 (1933).

    Google Scholar 

  85. N. S. Davies and H. A. Curtis, Ind. Eng. Chem. 24, 1137 (1932).

    Google Scholar 

  86. H. L. Ritter and L. C. Drake, Ind. Eng. Chem., Anal. Ed. 17, 782 (1945).

    CAS  Google Scholar 

  87. L. C. Drake and H. L. Ritter, Ind. Eng. Chem., Anal. Ed. 17, 787 (1945).

    CAS  Google Scholar 

  88. L. C. Drake, Ind. Eng. Chem. 41, 780 (1949).

    Google Scholar 

  89. L. G. Joyner, E. P. Barrett, and R. Skold, J. Amer. Chem. Soc. 73, 3155 (1951).

    CAS  Google Scholar 

  90. C. Orr, Powder Technol. 3, 117 (1969–70).

    Google Scholar 

  91. C. Orr and J. M. Dalla Valle, Fine Particle Measurement, Macmillan, New York (1959).

    Google Scholar 

  92. S. Diamond, Cement Concrete Res. 1, 531 (1971).

    Google Scholar 

  93. H. M. Rootare and C. F. Prenzlow, J. Phys. Chem. 71, 2733 (1967).

    CAS  Google Scholar 

  94. H. M. Rootare, Aminco Laboratory News, Aminco Reprint, no. 439 (1968).

    Google Scholar 

  95. H. M. Rootare and J. Suencer, Powder Tech. 6, 17 (1972).

    Google Scholar 

  96. H. M. Rootare, personal communication.

    Google Scholar 

  97. S. Brunauer, The Adsorption of Gases and Vapors, Princeton University Press (1945).

    Google Scholar 

  98. R. J. Good and R. Sh. Mikhail, in preparation.

    Google Scholar 

  99. R. Sh. Mikhail and R. J. Good, in preparation.

    Google Scholar 

  100. A. B. D. Cassie and S. Baxter, Trans. Faraday Soc. 40, 546 (1944).

    CAS  Google Scholar 

  101. A. B. D. Cassie, Disc. Faraday Soc. 3, 11 (1948).

    Google Scholar 

  102. V. Ludviksson and E. N. Lightfoot, AIChE J. 14, 674 (1968).

    CAS  Google Scholar 

  103. D. D. Ely and D. C. Pepper, Trans. Faraday Soc. 42, 697.

    Google Scholar 

  104. R. J. Good and N. J. Lin, J. Colloid Interface Sci. 54, 52 (1976).

    CAS  Google Scholar 

  105. R. J. Good and N. J. Lin, in Proceedings of the 50th Colloid and Interface Science Symposium, Colloid and Interface Sci. (M. Kerker, ed.), Vol. 3, p. 277, Academic Press, New York (1976).

    Google Scholar 

  106. J. Szekely, A. W. Neumann, and Y. K. Chuang, J. Colloid Interface Sci. 35, 273 (1971).

    CAS  Google Scholar 

  107. E. Weber and A. W. Neumann, Giesserei 56, 628 (1969).

    CAS  Google Scholar 

  108. W. Rose and R. W. Heins, J. Colloid Sci. 17, 39 (1962).

    CAS  Google Scholar 

  109. R. J. Good, J. Colloid Interface Sci. 42, 473 (1973).

    Google Scholar 

  110. W. D. Harkins, The Physical Chemistry of Surface Films, Reinhold, New York (1952).

    Google Scholar 

  111. W. D. Harkins and G. Jura, J. Amer. Chem. Soc. 66, 1362 (1944).

    CAS  Google Scholar 

  112. R. J. Good and L. A. Girifalco, J. Phys. Chem. 62, 1418 (1958).

    CAS  Google Scholar 

  113. M. L. White, in Clean Surfaces ( G. Goldfinger ed.), p. 361, Marcel Dekker, New York (1969).

    Google Scholar 

  114. A. I. Bailey, DECHEMA Monogr. 51, 210 (1964).

    Google Scholar 

  115. A. I. Bailey, private communication.

    Google Scholar 

  116. F. P. Bowden and D. Tabor, The Friction and Lubrication of Solids, Vol. 1, Clarendon Press, Oxford (1958).

    Google Scholar 

  117. H. Schonhorn, J. Polymer Sci. 85, 919 (1967).

    Google Scholar 

  118. H. Schonhorn, Macromolecules 1, 145 (1968).

    CAS  Google Scholar 

  119. A. W. Neumann, G. Haage, and D. Renzow, J. Colloid Interface Sci. 35, 379 (1971).

    CAS  Google Scholar 

  120. W. J. Herzberg, J. E. Marian, and T. Vermeulen, J. Colloid Interface Sci. 33, 164 (1970).

    CAS  Google Scholar 

  121. W. C. Bigelow, D. L. Pickett, and W. A. Zisman, J. Colloid Sci. 1, 513 (1946).

    CAS  Google Scholar 

  122. W. C. Bigelow, E. Glass, and W. A. Zisman, J. Colloid Sci. 2, 563 (1947).

    CAS  Google Scholar 

  123. E. G. Shafrin and W. A. Zisman, J. Colloid Sci. 4, 571 (1949).

    CAS  Google Scholar 

  124. H. R. Baker, E. G. Shafrin, and W. A. Zisman, J. Phys. Chem. 56, 405 (1952).

    CAS  Google Scholar 

  125. E. G. Shafrin and W. A. Zisman, Hydrophobic monolayers and their adsorption from aqueous solution, in Monomolecular Layers, H. Sobotka (ed.), AAAS Symposium Publication, Washington, D.C. (1954).

    Google Scholar 

  126. O. Levine and W. A. Zisman, J. Phys. Chem. 61, 1068 (1957).

    CAS  Google Scholar 

  127. E. G. Shafrin and W. A. Zisman, J. Phys. Chem. 64, 519 (1960).

    CAS  Google Scholar 

  128. C. O. Timmons and W. A. Zisman, J. Phys. Chem. 69, 984 (1965).

    CAS  Google Scholar 

  129. R. J. Good and N. W. Han, unpublished work.

    Google Scholar 

  130. R. J. Good and E. D. Kotsidas, J. Adhesion (1978), in press; E. D. Kotsidas, M.S. Thesis, State University of New York at Buffalo (1977).

    Google Scholar 

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Neumann, A.W., Good, R.J. (1979). Techniques of Measuring Contact Angles. In: Good, R.J., Stromberg, R.R. (eds) Surface and Colloid Science. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7969-4_2

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