Abstract
Once the existence of polymer chains as covalent structures became established a half century ago, the understanding of the molecular basis of the high elasticity characteristic of rubber-like substances presented itself as a foremost challenge. The first attempts1, 2 to explain this remarkable property may be said to date from the beginning of molecular theory as applied to polymers. Although the subject today is old, it is of continuing interest and one in which much remains to be done before an acceptable state of completion will have been attained.
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References
K. H. Meyer, G. vonSusich and E. Valkó, Kolloid Z., 59, 208 (1932).
E. Guth and H. Mark, Monatsh. Chem., 65, 93 (1934).
See for example, J. P. Cotton et al., Macromolecules, 7, 863-872 (1974)
R. G. Kirste, W. A. Kruse, and K. Ibel, Polymer, 16, 120–124 (1975)
J. Schelten, G. D. Wignall and D. G. H. Ballard, Polymer, 15, 682 (1974); Eur. Polymer J., 10, 861 (1974)
E. W. Fischer, G. Leiser and K. Ibel, Polymer Lett., 13, 39 (1975).
P. J. Flory, “Principles of Polymer Chemistry,” Cornell Univ. Press, Ithaca, N. Y., 1953.
P. J. Flory, J. Macromol. Sci., Phys. Ed., B12, 1–11 (1976).
P. J. Floiy, Pure & Appl. Chem., Macromolecularehem., 1–15 (1972); or. Rubber Chem. and Tech. 48, No. 3, 513–525 (1975).
P. J. Flory and D. Y. Yoon, J. Chem. Phys., 61,5358–5365 (1974).
P. J. Flory and V. W. C. Chang, Macromolecules, 9, 33–40 (1976).
M. V. Volkenstein and O. B. Ptitsyn, Zh. Tekh. Fiz., 15, 662 (1955).
M. V. Volkenstein, “Configurational Statistics of Polymeric Chains” (translated from the Russian edition by S. N. Timasheff and M. J. Timasheff), Interscience. New York, 1963, pp. 501–7.
E. Guthand, H. M. James, Ind. Eng. Chem., 33, 624 (1941).
H. M. James and E. Guth, J. Chem. Phys., 11, 455 (1943).
F. T. Wall, J. Chem. Phys., 11, 527 (1943).
L. R. G. Treloar, Trans. Faraday Soc., 3, 36, 241 (1943).
P. J. Flory and J. Rehner, Jr., J. Chem. Phys., 11, 512 (1943).
W. Kuhn, J. Polymer Sci., 1, 380 (1946).
L. R. G. Treloar, “The Physics of Rubber Elasticity,” 3rd ed., sssOxford Univ. Press, 1975.
P. J. Flory, Trans. Faraday Soc., 78, 829 (1961); J. Am. Chem. Soc., 78, 5222 (1956).
H. M. James, J. Chem. Phys., 15, 651 (1947).
H. M. James and E. Guth, ibid., 15, 669 (1947).
P. J. Flory, Proc. Roy Soc., in press. Presented at the Meeting for Discussion of Rubber Elasticity held by the Royal Society in London, 20 Nov., 1975.
B. E. Eichinger, Macromolecules, 5, 496 (1972).
W. W. Graessley, Macromolecules, 8, 865 (1975).
J. A. Duiser and J. A. Staverman, Physics of Non-Crystalline Solids, J. A. Prins, Ed., North Holland Publishing Co., Amsterdam (1965), pp. 376–387.
M. Mooney, J. Appl. Phys., 11 582 (1940.).
R. S. Rivlin, Phil. Trans. Roy. Soc. (London), A241, 379 (1948).
S. M. Gumbrell, L. Mullins and R. S. Rivlin, Trans. Faraday Soc., 49, 1495 (1953).
G. Allen, M. J. Kirkham, J. Padget and C. Price, Trans. Faraday Soc., 67, 1278–1292 (1971).
J. E. Mark, Rubber Chem. Technol., 48, 495 (1975).
D. S. Chlu and J. E. Mark, Colloid and Polymer Science, in press.
P. J. Flory and Y. Tatara, J. Polymer Sci.: Polymer Phys. Ed., 13 683–702 (1975).
L. R. G. Treloar, Rep. Prog. Physics, 36., 755 (1973).
R. Y. S. Chen, C. U. Yu and J. E. Mark, Macromolecules, 6, 746 (1973).
C. U. Yu and J. E. Mark, Polymer J., 7, 101 (1975).
H. Neidlinger and P. J. Flory, unpublished.
D. J. Walsh, G. Allen and G. Ballard, Polymer, J, 366 (1974).
G. Allen, P. A. Holmes and D. J. Walsh, Faraday Disc. Chem. Soc., 57, 19 (1974).
G. Allen, P. L. Egerton and D.J. Walsh, Polymer, 17, 65 (1976).
J. E. Mark, J. Chem. Phys., in press.
G. Allen, C. Price and N. Yoshimura, J. Chem. Soc., Faraday Trans. I, 71 748 (1975).
J. E. Mark, Rubber Chem. Technol., 46, 593 (1973).
A. Ciferri, C. A. J. Hoeve and P. J. Flory, J. Amer. Chem. Soc., 83, 1015 (1961).
P. J. Flory, A. Ciferri, and R. Chiang, J. Amer. Chem. Soc.,13, 1023 (1961).
R. Chiang, J. Phys. Chem., 70, 2348 (1966).
G. Ronca and G. Allegra, J. Chem. Phys., 63, 4990 (1975).
P. J. Flory, to be published.
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Flory, P.J. (1977). The Molecular Theory of Rubber Elasticity. In: Pearce, E.M., Schaefgen, J.R. (eds) Contemporary Topics in Polymer Science. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-6737-0_1
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DOI: https://doi.org/10.1007/978-1-4615-6737-0_1
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