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Advances in Catalysts and Processes for Methanol Synthesis from CO2

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Book cover CO2: A Valuable Source of Carbon

Part of the book series: Green Energy and Technology ((GREEN))

Abstract

Methanol plays a key role in a CO2 economy scenario. This contribution analyzes recent developments in this area from the catalyst and process perspectives, in terms of both current industrial production of methanol from fossil fuels via syngas, and changes need to progressively go to CO2-rich feedstock and finally to use pure CO2 and renewable H2 as raw materials. Aspects discussed regard the methanol industrial production, the catalysts for methanol synthesis (especially regarding recent advances), the reaction mechanism, and role of CO2, and the catalyst needs for methanol synthesis directly from CO2.

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References

  1. G.A. Olah, A. Goeppert, G.K. Surya Prakash, Beyond Oil and Gas: The Methanol Economy, 2nd edn. (Wiley-VCH, Weinheim, 2009)

    Book  Google Scholar 

  2. G.A. Olah, A. Goeppert, G.K. Prakash Surya, J. Org. Chem. 74, 487 (2009)

    Article  Google Scholar 

  3. Methanol Institute web site 2012 http://www.methanol.org. Accessed 7 Dec 2012

  4. K. Weissermel, H-J. Arpe, Industrial Organic Chemistry, 4th edn. (Wiley-VCH, Weinheim 2003)

    Google Scholar 

  5. J.B. Hansen, P.E.H. Nielsen, Methanol synthesis. In Handbook of Heterogenous Catalysis, eds. by G. Ertl, H. Knözinger, F. Schüth, J. Weitkamp (Wiley-VCH, Weinheim 2008)

    Google Scholar 

  6. Carbon Recycling International, Making renewable fuel by carbon recycling presentation (2012), http://newenergy.is/gogn/Radstefnur/3mai2010/carbon_recycling_international__cri____overview.pdf. Accessed 9 Dec 2012

  7. K. Aasberg-Petersen, T.S. Christensen, I. Dybkjaer, J. Sehested, M. Østberg, R.M. Coertzen, M.J. Keyser, A.P. Steynberg, Stud. Surf. Sci. Cat 152, 258 (2004)

    Article  Google Scholar 

  8. K. Aasberg-Petersen, C. Stub Nielsen, I. Dybkjær, J. Perregaard, Large scale methanol production from natural gas 2012 http://www.topsoe.com/business_areas/methanol/~/media/PDF%20files/Methanol/Topsoe_large_scale_methanol_prod_paper.ashx. Accessed 9 Dec 2012

  9. J. Skrzypek, M. Lachowska, M. Grzesik, J. Sloczynski, P. Nowak, Chem. Eng. J. 58, 101 (1995)

    Google Scholar 

  10. J.A. Moulijn, M. Makkee, A. Van Diepen, Chemical Process Technology (Wiley, Chichester, 2001)

    Google Scholar 

  11. X.-M. Liu, G.Q. Lu, Z.-F. Yan, J. Beltramini, Ind. Eng. Chem. Res. 42, 6518 (2003)

    Article  Google Scholar 

  12. H.H. Kung, Catal. Today 11, 443 (1992)

    Article  Google Scholar 

  13. M. Behrens, F. Studt, I. Kasatkin, S. Kühl, M. Hävecker, F. Abild-Pedersen, S. Zander, F. Girgsdies, P. Kurr, B.-L. Kniep, M. Tovar, R.W. Fischer, J.K. Nørskov, R. Schlögl, Science 336, 893 (2012)

    Article  Google Scholar 

  14. E. Kleymenov, J. Sa, J. Abu-Dahrieh, D. Rooney, J.A. van Bokhoven, E. Troussard, J. Szlachetko, O.V. Safonova, M. Nachtegaal, Catal. Sci. Technol. 2, 373 (2012)

    Article  Google Scholar 

  15. D. Grandjean, V. Pelipenko, E.D. Batyrev, J.C. van den Heuvel, A.A. Khassin, T.M. Yurieva, B.M. Weckhuysen, J. Phys. Chem. C 115, 20175 (2011)

    Article  Google Scholar 

  16. M.W.E. Berg, S. Polarz, O.P. Tkachenko, K. Kaehler, M. Muhler, W. Gruenert, Catal. Lett. 128, 49 (2009)

    Article  Google Scholar 

  17. I. Kasatkin, P. Kurr, B. Kniep, A. Trunschke, R. Schlögl, Angew. Chem. Int. Ed. 46, 7324 (2007)

    Google Scholar 

  18. O. Hinrichsen, T. Genger, M. Muhler, Chem. Eng. Technol. 23, 956 (2000)

    Article  Google Scholar 

  19. M. Behrens, S. Kissner, F. Girsgdies, I. Kasatkin, F. Hermerschmidt, K. Mette, H. Ruland, M. Muhler, R. Schlögl, Chem. Commun. 47, 1701 (2011)

    Article  Google Scholar 

  20. S. Kaluza, M. Behrens, N. Schiefenhoevel, B. Kniep, R. Fischer, R. Schlögl, M. Muhler, ChemCatChem 3, 189 (2011)

    Article  Google Scholar 

  21. J. Strunk, K. Kaehler, X. Xia, M. Muhler, Surf. Sci. 603, 1776 (2009)

    Article  Google Scholar 

  22. M.A. Sliem, S. Turner, D. Heeskens, S.B. Kalidindi, G. Van Tendeloo, M. Muhler, R.A. Fischer, Phys. Chem. Chem. Phys. 14, 8170 (2012)

    Article  Google Scholar 

  23. X. Sun, R. Fan, G. Yang, J. Shamoto, Y. Zhang, N. Tsubaki, J. Jpn. Petrol Inst. 54, 344 (2011)

    Article  Google Scholar 

  24. G.C. Chinchen, M.S. Spencer, K.C. Waugh, D.A. Whan, J. Chem. Soc., Faraday Trans. I 83, 2193 (1987)

    Google Scholar 

  25. M. Reiser, K. Stoewe, W.F. Maier, ACS Comb. Sci. 14, 378 (2012)

    Article  Google Scholar 

  26. W. Shen, Y. Ichihashi, Y. Matsumura, Catal. Lett. 79, 12 (2002)

    Article  Google Scholar 

  27. Q.-L. Tang, Q.-J. Hong, Z.-P. Liu, J. Catal. 263, 114 (2009)

    Article  Google Scholar 

  28. Y.X. Chen, A. Miki, S. Ye, H. Sakai, M. Osawa, J. Am. Chem. Soc. 25, 3680 (2003)

    Article  Google Scholar 

  29. Y. Yang, C.A. Mims, R.S. Disselkamp, J.-H. Kwak, C.H.F. Peden, C.T. Campbell, J. Phys. Chem. C 114, 17205 (2010)

    Article  Google Scholar 

  30. Y.-F. Zhao, Y. Yang, C. Mims, C.H.F. Peden, J. Li, D. Mei, J. Catal. 281, 199 (2011)

    Article  Google Scholar 

  31. L.C. Grabow, M. Mavrikakis, ACS Catal. 1, 365 (2011)

    Article  Google Scholar 

  32. P. Liu, Y.M. Choi, Y. Yang, M.G. White, J. Phys. Chem. A 114, 3888 (2010)

    Article  Google Scholar 

  33. J.M. Christensen, P.A. Jensen, A.D. Jensen, Ind. Eng. Chem. Res. 50, 7949 (2011)

    Article  Google Scholar 

  34. D.L.S. Nieskens, D. Ferrari, Y. Liu, R., Jr. Kolonko, Catal. Commun. 14, 111 (2011)

    Google Scholar 

  35. V.R. Surisetty, A.K. Dalai, J. Kozinski, Appl. Catal. A 385, 153 (2010)

    Google Scholar 

  36. X.-L. Liang, X. Dong, G.-D. Lin, H.-B. Zhang, Appl. Catal. B 88, 315 (2009)

    Article  Google Scholar 

  37. Q. Zhang, Y.-Z. Zuo, M.-H. Han, J.-F. Wang, Y. Jin, F. Wei, Catal. Today 150, 55 (2010)

    Article  Google Scholar 

  38. M. Saito, Catal. Surv. Jpn. 2, 175 (1998)

    Article  Google Scholar 

  39. M. Sahibzada, I.S. Metcalfe, D. Chadwick, J. Catal. 174, 111 (1998)

    Article  Google Scholar 

  40. K.C. Waugh, Catal. Today 15, 51 (1992)

    Article  Google Scholar 

  41. F. Arena, K. Barbera, G. Italiano, G. Bonura, L. Spadaro, F. Frusteri, J. Catal. 249, 185 (2007)

    Article  Google Scholar 

  42. M. Saito, T. Fujitani, M. Takeuchi, T. Watanabe, Appl. Catal. A 138, 311 (1996)

    Article  Google Scholar 

  43. E. Kunkes, M. Behrens, Methanol Chemistry, in Chemical Energy Storage, R. Schlögl Ed., De Gruyter Pub.: Berlin, Germany. In press. 2013

    Google Scholar 

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Acknowledgments

The EU project NEXT-GTL (NMP-3-LA-2009-229183), in the frame of which part of this work was realized, is gratefully acknowledged.

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Correspondence to G. Centi .

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Centi, G., Perathoner, S. (2013). Advances in Catalysts and Processes for Methanol Synthesis from CO2 . In: Falco, M., Iaquaniello, G., Centi, G. (eds) CO2: A Valuable Source of Carbon. Green Energy and Technology. Springer, London. https://doi.org/10.1007/978-1-4471-5119-7_9

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  • DOI: https://doi.org/10.1007/978-1-4471-5119-7_9

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  • Publisher Name: Springer, London

  • Print ISBN: 978-1-4471-5118-0

  • Online ISBN: 978-1-4471-5119-7

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