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Calix[n]phyrins: Synthesis and Anion Recognition

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Anion Recognition in Supramolecular Chemistry

Part of the book series: Topics in Heterocyclic Chemistry ((TOPICS,volume 24))

Abstract

This chapter covers advances in calix[n]phyrin chemistry since 2001, focusing on their synthesis and properties as anion complexants. Over the last 8 years, the structural variety of calixphyrins has significantly increased, and several applications as anion complexants were reported.

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Abbreviations

DDQ:

4,5-Dichloro-3,6-dioxo-1,2-benzonitrile

NCP:

N-confused porphyrin

NMR:

Nuclear magnetic resonance

OEP:

β-Octaethylporphyrin

PTSA:

4-Methylphenylsulphonic acid

PVC:

Poly(vinyl chloride)

TBA:

Tetrabutylammonium

TFA:

Trifluoroacetic acid

TPP:

meso-Tetraphenylporphyrin

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Authors and Affiliations

  1. Department of Chemistry, University of Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium

    Wim Dehaen

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  1. Wim Dehaen
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Correspondence to Wim Dehaen .

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Editors and Affiliations

  1. School of Chemistry, University of Southampton, Southampton, SO17 1BJ, United Kingdom

    Philip A. Gale

  2. Dept. Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200 F, Leuven, 3001, Belgium

    Wim Dehaen

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Dehaen, W. (2010). Calix[n]phyrins: Synthesis and Anion Recognition. In: Gale, P., Dehaen, W. (eds) Anion Recognition in Supramolecular Chemistry. Topics in Heterocyclic Chemistry, vol 24. Springer, Berlin, Heidelberg. https://doi.org/10.1007/7081_2010_51

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