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Miniemulsions for Nanoparticle Synthesis

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Colloid Chemistry II

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 227))

Abstract

Miniemulsions are specially formulated heterophase systems consisting of stable nanodroplets in a continuous phase. The narrowly size distributed nanodroplets of 50 to 500 nm can be prepared by shearing a system containing oil, water, a surfactant, and an osmotic pressure agent which is insoluble in the continuous phase. Since each of the nanodroplets can be regarded as a batch reactor, a whole variety of reactions can be carried out starting from miniemulsions clearly extending the profile of classical emulsion polymerization. This articles gives an overview about the mechanism of formation of and polymerizations in miniemulsions and reviews the current standing of the field for both the synthesis of new polymers and of dispersed hybrid systems.

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References

  1. Blackley DC (1997) Polymer lattices, 2nd edn. Chapman & Hill, London

    Google Scholar 

  2. Chou YJ, El-Aasser MS, Vanderhoff JW (1980) J Dispers Sci Technol 1:129–150

    Article  CAS  Google Scholar 

  3. Ostwald WZ (1901) Phys Chem 37:385

    Google Scholar 

  4. Higuchi WI, Misra J (1962) J Pharm Sci 459–466

    Google Scholar 

  5. Webster AJ, Cates ME (1998) Langmuir 14:2068–2079

    Article  CAS  Google Scholar 

  6. Postel M, Riess JG, Weers JG (1994) Artif Cells Blood Substit Immob Biotechnol 22:991–1005

    Article  CAS  Google Scholar 

  7. Lowe KC (2000) Artif Cells Blood Substit Immob Biotechnol 28:25–38

    CAS  Google Scholar 

  8. Abismail B, Canselier JP, Wilhelm AM, Delmas H, Gourdon C (1999) Ultrasonics Sonochem 6:75–83

    Article  CAS  Google Scholar 

  9. Wood RW, Loomis AL (1927) Phil Mag 4:417

    CAS  Google Scholar 

  10. Sorokin VI (1957) Soviet Phys Acoust 3:281–291

    Google Scholar 

  11. Li MK, Fogler HS (1978) J Fluid Mech 88:499–511

    Article  CAS  Google Scholar 

  12. Li MK, Fogler HS (1978) J Fluid Mech 88:513–528

    Article  CAS  Google Scholar 

  13. Bondy C, Söllner K (1935) Trans Faraday Soc 31:835–842

    Article  CAS  Google Scholar 

  14. Mason TJ (1992) Ultrasonics Sonochem 30:192–196

    CAS  Google Scholar 

  15. Lauterborn W (1997) Ultrasonics Sonochem 4:65–75

    Article  CAS  Google Scholar 

  16. Brösel S, Schubert H (1999) Chem Eng Process 38:533–540

    Article  Google Scholar 

  17. Fontenot KJJ, Schork FJ (1992) In: Reichert KH, Moritz H (eds) Fourth International Workshop on Polymer Reaction Engineering. Dechema Monographs, Weinheim, Germany, vol 127, pp 429–439

    Google Scholar 

  18. Fontenot K, Schork FJ (1993) Ind Eng Chem Res 32:373–385

    Article  CAS  Google Scholar 

  19. Landfester K, Bechthold N, Tiarks F, Antonietti M (1999) Macromolecules 32:5222–5228

    Article  CAS  Google Scholar 

  20. Landfester K (2000) Macromol Symp 150:171–178

    Article  CAS  Google Scholar 

  21. Guo JS, El-Aasser M, Vanderhoff J (1989) J Polym Sci Polym Chem Ed 24:861–874

    Google Scholar 

  22. Fontenot K, Schork FJ (1993) J Appl Polym Sci 49:633–655

    Article  CAS  Google Scholar 

  23. Landfester K, Bechthold N, Förster S, Antonietti M (1999) Macromol Rapid Commun 20:81–84

    Article  CAS  Google Scholar 

  24. Ugelstad J, Mork PC, Kaggerud KH, Ellingsen T, Berge A (1980) Adv Colloid Interface Sci 13:101–140

    Article  CAS  Google Scholar 

  25. Chern CS, Chen TJ, Liou YC (1998) Polymer 39:3767–3777

    Article  CAS  Google Scholar 

  26. Reimers J, Schork FJ (1996) Polym React Eng 4:135–152

    CAS  Google Scholar 

  27. Chern CS, Chen TJ (1998) Colloids Surf A Physicochem Eng Aspects 138:65–74

    Article  CAS  Google Scholar 

  28. Mouran D, Reimers J, Schork J (1996) J Polym Sci Polym Chem Ed 34:1073–1081

    Article  CAS  Google Scholar 

  29. Wang S, Poehlein GW, Schork FJ (1997) J Polym Sci Polym Chem Ed 35:595–603

    Article  CAS  Google Scholar 

  30. Alduncin JA, Forcada J, Asua JM (1994) Macromolecules 27:2256–2261

    Article  CAS  Google Scholar 

  31. Reimers JL, Schork FJ (1997) Ind Eng Chem Res 36:1085–1087

    Article  CAS  Google Scholar 

  32. Ugelstad J, El-Aasser MS, Vanderhoff JW (1973) J Polym Sci Polym Lett Ed 11:503–513

    Article  CAS  Google Scholar 

  33. Ugelstad J, Hansen FK, Lange S (1974) Makromol Chem 175:507–521

    Article  CAS  Google Scholar 

  34. Delgado J, El-Aasser MS, Vanderhoff JW (1986) J Polym Sci Polym Chem Ed 24:861–874

    Article  CAS  Google Scholar 

  35. Chern CS, Chen TJ (1997) Colloid Polym Sci 275:546–554

    Article  CAS  Google Scholar 

  36. Delgado J, EL-Aasser MS, Silibi CA, Vanderhoff JW (1990) J Polym Sci Polym Chem Ed 28:777–794

    Article  CAS  Google Scholar 

  37. Reimers JL, Schork FJ (1996) J Appl Polym Sci 60:251–262

    Article  CAS  Google Scholar 

  38. Reimers JL, Schork FJ (1996) J Appl Polym Sci 59:1833–1841

    Article  CAS  Google Scholar 

  39. Azad ARM, Ugelstad J, Fitch RM, Hansen FK (1976) In: Piirma I, Gardon JL (eds) Emulsion polymerization. ACS, Washington, D.C., vol 24, pp 1–23

    Google Scholar 

  40. Goetz RJ, El-Aasser MS (1990) Langmuir 6:132–136

    Article  CAS  Google Scholar 

  41. Miller CM, Venkatesan J, Silibi CA, Sudol ED, El-Aasser MS (1994) J Colloid Interface Sci 162:11–18

    Article  CAS  Google Scholar 

  42. Wang ST, Schork FJ, Poehlein GW, Gooch JW (1996) J Appl Polym Sci 60:2069–2076

    Article  CAS  Google Scholar 

  43. Chang H-C, Lin Y-Y, Chern C-S, Lin S-Y (1998) Langmuir 14:6632–6638

    Article  CAS  Google Scholar 

  44. Erdem B, Sully Y, Sudol ED, Dimonie VL, El-Aasser MS (2000) Langmuir 16:4890–4895

    Article  CAS  Google Scholar 

  45. Landfester K, Willert M, Antonietti M (2000) Macromolecules 33:2370–2376

    Article  CAS  Google Scholar 

  46. Willert M (2001) PhD thesis, Universität Potsdam

    Google Scholar 

  47. Candau F (1992) In: Paleos EC (ed) Polymerization in organized media. Gordon and Breach Science Publisher, Philadelphia, pp 215–282

    Google Scholar 

  48. Candau F (1995) Macromol Symp 92:169–178

    CAS  Google Scholar 

  49. Hunkeler DJ, Hernandez-Barajas J (1996) In: Salamone JC (ed) Polymeric materials encyclopedia. CRC Press, New York, vol 9, pp 3322–3333

    Google Scholar 

  50. Chou YJ, El-Aasser MS (1980) In: Fitch RM (ed) Polymer colloids II. Plenum Press, New York London, pp 599–618

    Google Scholar 

  51. Landfester K, Bechthold N, Tiarks F, Antonietti M (1999) Macromolecules 32:2679–2683

    Article  CAS  Google Scholar 

  52. Putlitz BZ, Hentze H-P, Landfester K, Antonietti M (2000) Langmuir 16:3214–3220

    Article  CAS  Google Scholar 

  53. Chern CS, Liou Y-C (1999) Polymer 40:3763–3772

    Article  CAS  Google Scholar 

  54. Capek I (1999) Adv Polym Sci 145:1–55

    Article  CAS  Google Scholar 

  55. Lim M-S, Chen J (2000) J Polym Sci Polym Chem Ed 38:1818–1827

    Article  CAS  Google Scholar 

  56. Wang S, Schork FJ (1994) J Appl Polym Sci 54:2157–2164

    Article  CAS  Google Scholar 

  57. Baskar G, Landfester K, Antonietti M (2000) Macromolecules 33:9228–9232

    Article  CAS  Google Scholar 

  58. Bechthold N, Tiarks F, Willert M, Landfester K, Antonietti M (2000) Macromol Symp 151:549–555

    Article  CAS  Google Scholar 

  59. Harkins WD (1945) J Chem Phys 13:381–382

    Article  CAS  Google Scholar 

  60. Harkins WD (1947) J Am Chem Soc 69:1428–1444

    Article  CAS  Google Scholar 

  61. Harkins WD (1950) J Polym Sci 5:217–251

    Article  CAS  Google Scholar 

  62. Tauer K, Mueller H, Schellenberg C, Rosengarten L (1999) Colloid Surf A Phys Chem Eng Aspects 153:143–151

    Article  CAS  Google Scholar 

  63. Gilbert R (1995) Emulsion polymerization. Academic Press, San Diego

    Google Scholar 

  64. Tang PL, Sudol ED, Adams ME, Silibi CA, El-Aasser MS (1992) ACS Symp Ser 492:72–98

    Article  CAS  Google Scholar 

  65. Tang PL, Sudol ED, Silebi CA, El-Aasser MS (1991) J Appl Polym Sci 43:1059–1066

    Article  CAS  Google Scholar 

  66. Bechthold N, Landfester K (2000) Macromolecules 33:4682–4689

    Article  CAS  Google Scholar 

  67. Saethre B, Moerk PC, Ugelstad J (1995) J Polym Sci Polym Chem Ed 33:2951–2959

    Article  CAS  Google Scholar 

  68. Huang H, Zhang H, Li J, Cheng S, Hu F, Tan B (1998) J Appl Polym Sci 68:2029–2039

    Article  CAS  Google Scholar 

  69. Wang CC, Yu NS, Chen CY, Kuo JF (1996) J Appl Polym Sci 60:493–501

    Article  CAS  Google Scholar 

  70. Wang CC, Yu NS, Chen CY, Kuo JF (1996) Polymer 37:2509–2516

    Article  CAS  Google Scholar 

  71. Landfester K (2001) Macromol Rapid Comm 22:896–936

    Article  Google Scholar 

  72. Landfester K, Rothe R, Antonietti M (2002) Macromolecules 35:1658–1662

    Article  CAS  Google Scholar 

  73. Wu XQ, Schork FJ (2000) Ind Eng Chem Res 39:2855–2865

    Article  CAS  Google Scholar 

  74. Dewald RC, Hart LH, Carroll WF Jr (1984) J Polym Sci Polym Chem Ed 22:2923–2930

    Article  CAS  Google Scholar 

  75. Reichert K-H, Baade W (1984) Angew Makromol Chem 123/124:381–386

    Google Scholar 

  76. Baade W, Reichert K-H (1986) Makromol Chem Rapid Commun 7:235–241

    Article  CAS  Google Scholar 

  77. Landfester K, Antonietti M (2000) Macromol Chem Rapid Comm 21:820–824

    Article  CAS  Google Scholar 

  78. Rodriguez VS, El-Aasser MS, Asua JM, Silibi CA (1989) J Polym Sci Polym Chem Ed 27:3659–3671

    Article  CAS  Google Scholar 

  79. Asua JM, Rodriguez VS, Silebi CA, El-Aasser MS (1990) Makromol Chem Macromol Symp 35/35:59–85

    Google Scholar 

  80. Rodriguez VS, Delgado J, Silibi CA, El-Aasser MS (1989) Ind Eng Chem Res 28:65–74

    Article  CAS  Google Scholar 

  81. Huang H, Zhang HT, Hu F, Ai ZQ, Tan B, Cheng SY, Li LZ (1999) J Appl Polym Sci 73:315–322

    Article  CAS  Google Scholar 

  82. Inaba Y, Daniels ES, El-Aasser MS (1994) J Coatings Technol 66:63–74

    CAS  Google Scholar 

  83. Rajatapiti P, Dimonie VL, El-Aasser MS (1995) J Macromol Sci Pure Appl Chem A32(8/9):1445–1460

    CAS  Google Scholar 

  84. Rajatapiti P, Dimonie VL, El-Aasser MS, Vratsanos MS (1997) J Appl Polym Sci 63:205–219

    Article  CAS  Google Scholar 

  85. Landfester K, Dimonie VL, El-Aasser MS (1998) DECHEMA Monographs, vol 134. Wiley-VCH Weinheim, pp 469–477

    CAS  Google Scholar 

  86. Chern CS, Sheu JC (2001) Polymer 42:2349–2357

    Article  CAS  Google Scholar 

  87. Chern CS, Sheu JC (2000) J Polym Sci A Polym Chem 38:3188–3199

    Article  CAS  Google Scholar 

  88. Willert M, Landfester K (2002) Macromol Chem Phys 203:825–836

    Article  CAS  Google Scholar 

  89. Kukulj D, Davis TP, Gilbert RG (1997) Macromolecules 30:7661–7666

    Article  CAS  Google Scholar 

  90. Matyjaszewski K, Gaynor SG (2000) In: Craver CD, Carraher CE (eds) Applied polymer science: 21st century. Elsevier Science, Oxford, pp 929–978

    Chapter  Google Scholar 

  91. Lansalot M, Farcet C, Charleux B, Vairon J-P (1999) Macromolecules 32:7354–7360

    Article  CAS  Google Scholar 

  92. Butte A, Storti G, Morbidelli M (2000) Macromolecules 33:3485–3487

    Article  CAS  Google Scholar 

  93. Farcet C, Lansalot M, Pirri R, Vairon JP, Charleux B (2000) Macromol Chem Rapid Commun 21:921–926

    Article  CAS  Google Scholar 

  94. MacLeod PJ, Barber R, Odell PG, Keoshkerian B, Georges MK (2000) Macromol Symp 155:31–38

    Article  CAS  Google Scholar 

  95. Prodpran T, Dimonie VL, Sudol ED, El-Aasser MS (2000) Macromol Symp 155:1–14

    Article  CAS  Google Scholar 

  96. Pan G, Sudol ED, Dimonie VL, El-Aasser MS (2001) Macromolecules 34:481–488

    Article  CAS  Google Scholar 

  97. Farcet C, Lansalot M, Charleux B, Pirri R, Vairon JP (2000) Macromolecules 33:8559–8570

    Article  CAS  Google Scholar 

  98. de Brouwer H, Tsavalas JG, Schork FJ, Monteiro MJ (2000) Macromolecules 33:9239–9246

    Article  CAS  Google Scholar 

  99. Matyaszewski K, Qiu J, Tsarevsky NV, Charleux B (2000) J Polym Sci Polym Chem Ed 38:4724–4734

    Article  Google Scholar 

  100. Qiu J, Pintauer T, Gaynor SG, Matyjaszewski K, Charleux B, Vairon JP (2000) Macromolecules 33:7310–7320

    Article  CAS  Google Scholar 

  101. Wu XQ, Schork FJ, Gooch JW (1999) J Polym Sci Polym Chem Ed 37:4159–4168

    Article  CAS  Google Scholar 

  102. Tsavalas JG, Gooch JW, Schork FJ (2000) J Appl Polym Sci 75:916–927

    Article  CAS  Google Scholar 

  103. Gooch JW, Dong H, Schork FJ (2000) J Appl Polym Sci 76:105–114

    Article  CAS  Google Scholar 

  104. van Hamersveld EMS, van Es J, Cuperus FP (1999) Colloid Surf A Physicochem Eng Aspects 153:285–296

    Article  Google Scholar 

  105. Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) J Polym Sci Polym Chem Ed 38:4419–4430

    Article  CAS  Google Scholar 

  106. Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) J Polym Sci Polym Chem Ed 38:4431–4440

    Article  CAS  Google Scholar 

  107. Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) Macromol Symp 155:181–198

    Article  CAS  Google Scholar 

  108. Erdem B, Sudol ED, Dimonie VL, El-Aasser MS (2000) J Polym Sci Polym Chem Ed 38:4441–4450

    Article  CAS  Google Scholar 

  109. Hoffmann D, Landfester K, Antonietti M (2001) Magnetohydrodynamics 37:217–221

    Google Scholar 

  110. Tiarks F, Landfester K, Antonietti M (2001) Macromol Chem Phys 202:51–60

    Article  CAS  Google Scholar 

  111. Rudin A (1995) Macromol Symp 92:53–70

    CAS  Google Scholar 

  112. Landfester K, Boeffel C, Lambla M, Spiess HW (1996) Macromolecules 29:5972–5980

    Article  CAS  Google Scholar 

  113. Landfester K, Spiess HW (1998) Acta Polym 49:451–464

    Article  CAS  Google Scholar 

  114. Tiarks F, Landfester K, Antonietti M (2001) Langmuir 17:908–917

    Article  CAS  Google Scholar 

  115. Putlitz BZ, Landfester K, Fischer H, Antonietti M (2001) Adv Mater 13:500–503

    Article  Google Scholar 

  116. Torza S, Mason SG (1970) J Colloid Interface Sci 33:6783

    Article  Google Scholar 

  117. Berg J, Sundberg D, Kronberg B (1989) J Microencapsulation 6:327–337

    Article  CAS  Google Scholar 

  118. Ramsden W (1903) Proc R Soc London 72:156–164

    Article  CAS  Google Scholar 

  119. Pickering SU (1907) J Chem Soc Commun 91:2001

    Google Scholar 

  120. Briggs TR (1921) Ind Eng Chem Prod Res Dev 13:1008

    CAS  Google Scholar 

  121. Tiarks F, Landfester K, Antonietti M (2001) Langmuir 17:5775–5780

    Article  CAS  Google Scholar 

  122. Barthet C, Hickey AJ, Cairns DB, Armes SP (1999) Adv Mater 11:408–410

    Article  CAS  Google Scholar 

  123. Percy MJ, Barthet C, Lobb JC, Khan MA, Lascelles SF, Vamvakaki M, Armes SP (2000) Langmuir 16:6913–6920

    Article  CAS  Google Scholar 

  124. Soler-Illia GJDA, Sanchez C (2000) New J Chem 24:493

    Article  CAS  Google Scholar 

  125. Landfester K, Tiarks F, Hentze H-P, Antonietti M (2000) Macromol Chem Phys 201:1–5

    Article  CAS  Google Scholar 

  126. Tiarks F, Landfester K, Antonietti M (2001) J Polym Sci Polym Chem Ed 39:2520–2524

    Article  CAS  Google Scholar 

  127. Marie E, Landfester K, Antonietti M (2002) Biomacromolecules (in press)

    Google Scholar 

  128. Maitre C, Ganachaud F, Ferreira O, Lutz JF, Paintoux Y, Hemery P (2000) Macromolecules 33:7730–7736

    Article  CAS  Google Scholar 

  129. Tomov A, Broyer JP, Spitz R (2000) Macromol Symp 150:53–58

    Article  CAS  Google Scholar 

  130. Willert M, Rothe R, Landfester K, Antonietti M (2001) Chem Mater 13:4681–4685

    Article  CAS  Google Scholar 

  131. Förster S, Antonietti M (1998) Adv Mater 10:195–217

    Article  Google Scholar 

  132. Antonietti M, Landfester K, Mastai Y (2001) Isr J Chem 41:1–5

    Article  CAS  Google Scholar 

  133. Antonietti M, Landfester K (2001) Chem Phys Chem 2:207–210

    CAS  Google Scholar 

  134. Stähler K, Selb J, Candau F (1999) Langmuir 15:7565

    Article  CAS  Google Scholar 

  135. Hartl FU (1996) Nature 381:571

    Article  CAS  Google Scholar 

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Landfester, K. (2003). Miniemulsions for Nanoparticle Synthesis. In: Antonietti, M. (eds) Colloid Chemistry II. Topics in Current Chemistry, vol 227. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-36412-9_4

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