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Metalorganic Chemistry in the Gas Phase: Insight into Catalysis

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Modern Mass Spectrometry

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 225))

Abstract

Applications of electrospray mass spectrometry (ESMS) to the study of reactions mediated by transition-metal complexes are reviewed. ESMS has become increasingly popular as an analytical tool in inorganic and organometallic chemistry, in particular with regard to the identification of short-lived intermediates of catalytic cycles. Going one step further, the coupling of electrospray ionization to ion-molecule techniques in the gas phase yields detailed information about single reaction steps of catalytic cycles. This method allows the study of transient intermediates that have previously not been within reach of condensed-phase techniques on both a qualitative and quantitative level.

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6 References

  1. Cole RB (ed) (1997) Electrospray ionization mass spectrometry. Wiley, New York

    Google Scholar 

  2. Snyder AP (ed) (1995) Biochemical and biotechnological applications of electrospray ionization mass spectrometry. Acs Symp Ser, vol 619

    Google Scholar 

  3. Przybylski M, Glocker MO (1996) Angew Chem Int Ed Engl 35:806

    Article  CAS  Google Scholar 

  4. Bailey AG (1988) Electrostatic spraying of liquids. Research Studies Press, Taunton, UK

    Google Scholar 

  5. Zeleny J (1914) Phys Rev 3:69

    Article  Google Scholar 

  6. Zeleny J (1917) Phys Rev 10:1

    Article  Google Scholar 

  7. Zeleny J (1920) Phys Rev 16:102

    Article  Google Scholar 

  8. Zeleny J (1915) Proc Cambridge Phil Soc 18:71

    Google Scholar 

  9. Drozin VG (1955) J Colloid Sci 10:158

    Article  CAS  Google Scholar 

  10. Dole M, Hines RL, Mack LL, Mobley RC, Ferguson LD, Alice MB (1968) Macromolecules 1:96

    Article  CAS  Google Scholar 

  11. Dole M, Mack LL, Hines RL, Mobley RC, Ferguson LD, Alice MB (1968) J Chem Phys 49:2240

    Article  CAS  Google Scholar 

  12. Mack LL, Kralik P, Rheude A, Dole M (1970) J Chem Phys 52:4977

    Article  CAS  Google Scholar 

  13. Clegg GA, Dole M (1971) Biopolymers 10:821

    Article  CAS  Google Scholar 

  14. For a very personal account on the route to electrospray mass spectrometry see: Fenn JB (1997) Foreword. In: Cole RB (1997) (ed) Electrospray ionization mass spectrometry. Wiley, New York, p ix

    Google Scholar 

  15. Yamashita M, Fenn JB (1984) J Phys Chem 88:4451

    Article  CAS  Google Scholar 

  16. Yamashita M, Fenn JB (1984) J Phys Chem 88:4671

    Article  CAS  Google Scholar 

  17. Aleksandrov ML, Gall LN, Krasnov VN, Nikolaev VI, Pavlenko VA, Shkurov VA (1984) Dokl Akad Nauk SSSR 277:379

    CAS  Google Scholar 

  18. Whitehouse CM, Dreyer RN, Yamashita M, Fenn JB (1985) Anal Chem 57:675

    Article  CAS  Google Scholar 

  19. Taylor GI (1964) Proc R Soc London A280:383

    Article  Google Scholar 

  20. Taflin DC, Ward TL, Davis EJ (1989) Langmuir 5:376

    Article  CAS  Google Scholar 

  21. Davis EJ (1987) ISA Trans 26:1

    CAS  Google Scholar 

  22. Gomez A, Tang K (1994) Phys Fluids 6:404

    Article  CAS  Google Scholar 

  23. Lord Rayleigh (1882) Philos Mag 14:184

    Article  Google Scholar 

  24. Fernández de la Mora J, Loscertales IG (1994) J Fluid Mech 260:155

    Article  Google Scholar 

  25. Schmelzeisen-Redeker G, Röllgen FW, Wirtz H, Vögtle F (1985) Org Mass Spectrom 20:752

    Article  CAS  Google Scholar 

  26. Schmelzeisen-Redeker G, Bütfering L, Röllgen FW (1989) Int J Mass Spectrom Ion Processes 90:139

    Article  CAS  Google Scholar 

  27. Iribarne JV, Thomson BA (1976) J Chem Phys 64:2287

    Article  CAS  Google Scholar 

  28. Thomson BA, Iribarne JV (1979) J Chem Phys 71:4451

    Article  CAS  Google Scholar 

  29. Fenn JB, Rosell J, Nohmi T, Shen S, Banks FJ Jr (1995) Electrospray ion formation: desorption versus desertion. In: Snyder AP (1995) (ed) Biochemical and biotechnological applications of electrospray ionization mass spectrometry. Acs Symp Ser, vol 619, p 60

    Google Scholar 

  30. Fenn JB, Mann M, Meng CK, Wong SF, Whitehouse CM (1989) Science 246:64

    Article  CAS  Google Scholar 

  31. Snyder AP (1995) Electrospray: a popular ionization technique for mass spectrometry. In: Snyder AP (1995) (ed) Biochemical and biotechnological applications of electrospray ionization mass spectrometry. Acs Symp Ser, vol 619, p 1

    Google Scholar 

  32. Colton R, D’Agostino A, Traeger JC (1995) Mass Spectrom Rev 14:79

    Article  CAS  Google Scholar 

  33. Henderson W, Nicholson BK, McCaffrey LJ (1998) Polyhedron 17:4291

    Article  CAS  Google Scholar 

  34. Zass E, Plattner DA, Beck AK, Neuburger M (2002) Helv Chim Acta 85:4012

    Article  CAS  Google Scholar 

  35. Raffaelli A, Bruins AP (1991) Rapid Commun Mass Spectrom 5:269

    Article  CAS  Google Scholar 

  36. Katta V, Chowdhury SK, Chait BT (1990) J Am Chem Soc 112:5348

    Article  CAS  Google Scholar 

  37. Wilson SR, Yasmin A, Wu Y (1992) J Org Chem 57:6941

    Article  CAS  Google Scholar 

  38. Gatlin CL, Turecek F, Vaisar T (1994) Anal Chem 66:3950

    Article  CAS  Google Scholar 

  39. Colton R, James BD, Potter ID, Traeger JC (1993) Inorg Chem 32:2626

    Article  CAS  Google Scholar 

  40. Tuoi JLQ, Muller E (1994) Rapid Commun Mass Spectrom 8:692

    Article  CAS  Google Scholar 

  41. Deery MJ, Howarth OW, Jenings KR (1997) J Chem Soc Dalton Trans 4783

    Google Scholar 

  42. Walanda DK, Burns RC, Lawrance GA, von Nagy-Felsobuki EI (2000) Inorg Chim Acta 305:118

    Article  CAS  Google Scholar 

  43. Walanda DK, Burns RC, Lawrance GA, von Nagy-Felsobuki EI (1999) J Chem Soc Dalton Trans 311

    Google Scholar 

  44. Arakawa R, Mimura S, Matsubayashi G, Matsuo T (1996) Inorg Chem 35:5725

    Article  CAS  Google Scholar 

  45. Wilson SR, Wu YH (1993) Organometallics 12:1478

    Article  CAS  Google Scholar 

  46. Aliprantis AO, Canary JW (1994) J Am Chem Soc 116:6985

    Article  CAS  Google Scholar 

  47. Ripa L, Hallberg A (1996) J Org Chem 61:7147

    Article  CAS  Google Scholar 

  48. Brown JM, Hii KK (1996) Angew Chem Int Ed Engl 35:657

    Article  CAS  Google Scholar 

  49. Farrington EJ, Brown JM, Barnard CFJ, Rowsell E (2002) Angew Chem Int Ed 41:169

    Article  CAS  Google Scholar 

  50. Lipshutz BH, Stevens KL, James B, Pavlovich JG, Snyder JP (1996) J Am Chem Soc 118:6796

    Article  CAS  Google Scholar 

  51. Gilman H, Jones RG, Woods LA (1952) J Org Chem 17:1630

    Article  CAS  Google Scholar 

  52. Lipshutz BH, Keith J, Buzard DJ (1999) Organometallics 18:1571

    Article  CAS  Google Scholar 

  53. Yeo JSL, Vittal JJ, Henderson W, Hor TSA (2002) J Chem Soc Dalton Trans 328

    Google Scholar 

  54. Fong SWA, Yap WT, Vittal JJ, Hor TSA, Henderson W, Oliver AG, Rickard CEF (2001) J Chem Soc Dalton Trans 1986

    Google Scholar 

  55. Fong SWA, Vittal JJ, Henderson W, Hor TSA, Oliver AG, Rickard CEF (2001) Chem Commun 421

    Google Scholar 

  56. Bartók M, Balázsik K, Szöllölsi G, Bartók T (2002) J Catal 205:168

    Article  CAS  Google Scholar 

  57. Náray-Szabó G (1998) Electrostatic catalysis. In: Schleyer PR (ed) Encyclopedia of computational chemistry, vol 2. Wiley, New York, p 905

    Google Scholar 

  58. Ding W, Johnson KA, Amster J, Kutal C (2001) Inorg Chem 40:6865

    Article  CAS  Google Scholar 

  59. Dakin LA, Ong PC, Panek JS, Staples RJ, Stavropoulos P (2000) Organometallics 19:2896

    Article  CAS  Google Scholar 

  60. Bonchio M, Licini G, Modena G, Moro S, Bortolini O, Traldi P, Nugent WA (1997) Chem Commun 869

    Google Scholar 

  61. Bonchio M, Licini G, Modena G, Bortolini O, Moro S, Nugent WA (1999) J Am Chem Soc 121:6258

    Article  CAS  Google Scholar 

  62. Hinderling C, Chen P (1999) Angew Chem Int Ed 38:2253

    Article  CAS  Google Scholar 

  63. Freiser BS (ed) (1996) Organometallic ion chemistry. Kluwer, Dordrecht

    Google Scholar 

  64. Canty AJ, Traill PR, Colton R, Thomas IM (1993) Inorg Chim Acta 210:91

    Article  CAS  Google Scholar 

  65. Dalgaard P, McKenzie CJ (1999) J Mass Spectrom 34:1033

    Article  CAS  Google Scholar 

  66. Styles ML, O’Hair RAJ, McFadyen WD, Tannous L, Holmes RJ, Gable RW (2000) J Chem Soc Dalton Trans 93

    Google Scholar 

  67. Jiang C, Hor TSA, Yan YK, Henderson W, McCaffrey LJ (2000) J Chem Soc Dalton Trans 3197

    Google Scholar 

  68. Spence TG, Burns TD, Posey LA (1997) J Phys Chem A 101:139

    Article  CAS  Google Scholar 

  69. Spence TG, Burns TD, Guckenberger GB, Posey LA (1997) J Phys Chem A 101:1081

    Article  CAS  Google Scholar 

  70. Spence TG, Trotter BT, Burns TD, Posey LA (1998) J Phys Chem A 102:6101

    Article  CAS  Google Scholar 

  71. Molina-Svendsen H, Bojesen G, McKenzie CJ (1998) Inorg Chem 37:1981

    Article  CAS  Google Scholar 

  72. Arndtsen BA, Bergman RG, Mobley TA, Petersen TH (1995) Acc Chem Res 28:154

    Article  CAS  Google Scholar 

  73. Janowicz AH, Bergman RG (1982) J Am Chem Soc 104:352

    Article  CAS  Google Scholar 

  74. Jones WD, Feher FJ (1984) J Am Chem Soc 106:1650

    Article  CAS  Google Scholar 

  75. Hoyano JK, McMaster AD, Graham WAG (1983) J Am Chem Soc 105:7190

    Article  CAS  Google Scholar 

  76. Burger P, Bergman RG (1993) J Am Chem Soc 115:10,462

    Article  CAS  Google Scholar 

  77. Arndtsen BA, Bergman RG (1995) Science 270:1970

    Article  CAS  Google Scholar 

  78. Veltheer JE, Burger P, Bergman RG (1995) J Am Chem Soc 117:12,478

    Article  CAS  Google Scholar 

  79. Holtcamp MW, Labinger JA, Bercaw JE (1997) J Am Chem Soc 119:848

    Article  CAS  Google Scholar 

  80. Hinderling C, Plattner DA, Chen P (1997) Angew Chem Int Ed Engl 36:243

    Article  CAS  Google Scholar 

  81. Hinderling C, Feichtinger D, Plattner DA, Chen P (1997) J Am Chem Soc 119:10,793

    Article  CAS  Google Scholar 

  82. Luecke HF, Bergman RG (1997) J Am Chem Soc 119:11,538

    Article  CAS  Google Scholar 

  83. Fink G, Mülhaupt R, Brintzinger HH (eds) (1995) Ziegler catalysts. Springer, Berlin Heidelberg New York

    Google Scholar 

  84. Jordan RF, Dasher WE, Echols SF (1986) J Am Chem Soc 108:1718

    Article  CAS  Google Scholar 

  85. Jordan RF, Bajgur CS, Willett R, Scott B (1986) J Am Chem Soc 108:7410

    Article  CAS  Google Scholar 

  86. Brintzinger HH, Fischer D, Mülhaupt R, Rieger B, Waymouth R (1995) Angew Chem Int Ed Engl 34:1143

    Article  CAS  Google Scholar 

  87. Christ CS, Eyler JR, Richardson DE (1988) J Am Chem Soc 110:4038

    Article  CAS  Google Scholar 

  88. Christ CS, Eyler JR, Richardson DE (1990) J Am Chem Soc 112:596

    Article  CAS  Google Scholar 

  89. Richardson DE, Alameddin NG, Ryan MF, Hayes T, Eyler JR, Siedle AR (1996) J Am Chem Soc 118:11,244

    Article  CAS  Google Scholar 

  90. Guo BC, Castleman AW Jr (1992) J Am Chem Soc 114:6152

    Article  CAS  Google Scholar 

  91. Daly GM, El-Shall MS (1994) J Phys Chem 98:696

    Article  CAS  Google Scholar 

  92. Daly GM, El-Shall MS (1995) J Phys Chem 99:5283

    Article  CAS  Google Scholar 

  93. Bjarnason A, Ridge DP (1996) J Phys Chem 100:15,118

    Article  CAS  Google Scholar 

  94. Feichtinger D, Plattner DA, Chen P (1998) J Am Chem Soc 120:7125

    Article  CAS  Google Scholar 

  95. Chien JCW, Wang BP (1990) J Polym Sci Part A 28:15

    Article  CAS  Google Scholar 

  96. Ortiz de Montellano PR (ed) (1995) Cytochrome P-450, structure, mechanism and biochemistry. Plenum Press, New York

    Google Scholar 

  97. Sheldon RA (ed) (1994) Metalloporphyrins in catalytic oxidations. Dekker, New York

    Google Scholar 

  98. Montanari F, Casella L (eds) (1994) Metalloporphyrin catalyzed oxidations. Kluwer, Dordrecht

    Google Scholar 

  99. Siddall TL, Miyaura N, Huffman JC, Kochi JK (1983) J Chem Soc Chem Commun 1185

    Google Scholar 

  100. Samsel EG, Srinivasan K, Kochi JK (1985) J Am Chem Soc 107:7606

    Article  CAS  Google Scholar 

  101. Srinivasan K, Kochi JK (1985) Inorg Chem 24:4671

    Article  CAS  Google Scholar 

  102. Srinivasan K, Michaud P, Kochi JK (1986) J Am Chem Soc 108:2309

    Article  CAS  Google Scholar 

  103. Srinivasan K, Perrier S, Kochi JK (1986) J Mol Catal 36:297

    Article  CAS  Google Scholar 

  104. Zhang W, Loebach JL, Wilson SR, Jacobsen EN (1990) J Am Chem Soc 112:2801

    Article  CAS  Google Scholar 

  105. Irie R, Noda K, Ito Y, Matsumoto N, Katsuki T (1990) Tetrahedron Lett 31:7345

    Article  CAS  Google Scholar 

  106. Dalton CT, Ryan KM, Wall VM, Bousquet C, Gilheany DG (1998) Top Catal 5:75

    Article  CAS  Google Scholar 

  107. Groves JT, Kruper WJ (1979) J Am Chem Soc 101:7613

    Article  CAS  Google Scholar 

  108. Groves JT, Stern MK (1987) J Am Chem Soc 109:3812

    Article  CAS  Google Scholar 

  109. Groves JT, Stern MK (1988) J Am Chem Soc 110:8628

    Article  CAS  Google Scholar 

  110. Groves JT, Lee J, Marla SS (1997) J Am Chem Soc 119:6269

    Article  CAS  Google Scholar 

  111. Plattner DA, Feichtinger D, El-Bahraoui J, Wiest O (2000) Int J Mass Spectrom 195/196:351

    Article  CAS  Google Scholar 

  112. Calligaris M, Randaccio L (1987) In: Wilkinson G, Gillard RD, McCleverty JA (eds) Comprehensive coordination chemistry, vol 2. Pergamon, Oxford, p 715

    Google Scholar 

  113. Oki AR, Hodgson DJ (1990) Inorg Chim Acta 170:65

    Article  CAS  Google Scholar 

  114. Feichtinger D, Plattner DA (1997) Angew Chem Int Ed Engl 36:1718

    Article  CAS  Google Scholar 

  115. Gilbert BC, Kamp NWJ, Lindsay Smith JR, Oakes J (1998) J Chem Soc Perkin Trans 2 1841

    Article  Google Scholar 

  116. Feichtinger D, Plattner DA (2000) J Chem Soc Perkin Trans 2 1023

    Article  Google Scholar 

  117. Nugent WA, Mayer JM (1988) Metal-ligand multiple bonds. Wiley, New York

    Google Scholar 

  118. Feichtinger D, Plattner DA (2001) Chem Eur J 7:591

    Article  CAS  Google Scholar 

  119. Brown HC, Okamoto Y (1958) J Am Chem Soc 80:4979

    Article  CAS  Google Scholar 

  120. Jacobsen EN, Zhang W, Güler ML (1991) J Am Chem Soc 113:6703

    Article  CAS  Google Scholar 

  121. Palucki M, Finney NS, Pospisil PJ, Güler ML, Ishida T, Jacobsen EN (1998) J Am Chem Soc 120:948

    Article  CAS  Google Scholar 

  122. Finney NS, Pospisil PJ, Chang S, Palucki M, Konsler RG, Hansen KB, Jacobsen EN (1997) Angew Chem Int Ed Engl 36:1720

    Article  CAS  Google Scholar 

  123. Ivin KJ, Mol JC (1997) Metathesis and metathesis polymerization. Academic Press, New York

    Google Scholar 

  124. Stevens AE, Beauchamp JL (1979) J Am Chem Soc 101:6449

    Article  CAS  Google Scholar 

  125. Jacobsen DB, Freiser BS (1985) J Am Chem Soc 107:67

    Article  Google Scholar 

  126. Jacobsen DB, Freiser BS (1985) J Am Chem Soc 107:2605

    Article  Google Scholar 

  127. Stöckigt D, Schwarz H (1992) Chem Ber 125:2817

    Article  Google Scholar 

  128. Mohr B, Lynn DM, Grubbs RH (1996) Organometallics 15:4317

    Article  CAS  Google Scholar 

  129. Hinderling C, Adlhart C, Chen P (1998) Angew Chem Int Ed 37:2685

    Article  CAS  Google Scholar 

  130. Adlhart C, Hinderling C, Baumann H, Chen P (2000) J Am Chem Soc 122:8204

    Article  CAS  Google Scholar 

  131. Schwab P, Grubbs RH, Ziller JW (1996) J Am Chem Soc 118:100

    Article  CAS  Google Scholar 

  132. Ulman M, Grubbs RH (1998) Organometallics 17:2484

    Article  CAS  Google Scholar 

  133. Patton PA, McCarthy TJ (1984) Macromolecules 17:2939

    Article  CAS  Google Scholar 

  134. Patton PA, McCarthy TJ (1985) Polym Prep 26:66

    CAS  Google Scholar 

  135. Patton PA, McCarthy TJ (1987) Macromolecules 20:778

    Article  CAS  Google Scholar 

  136. Martinho Simões JA, Beauchamp JL (1990) Chem Rev 90:629

    Article  Google Scholar 

  137. Armentrout PB (1992) Thermochemical measurements by guided ion beam mass spectrometry. In: Adams N, Babcock LM (eds) Advances in gas phase ion chemistry, vol 1. JAI Press, Greenwich, CT, p 83

    Google Scholar 

  138. Armentrout PB (1995) Acc Chem Res 28:430

    Article  CAS  Google Scholar 

  139. Dalleska NF, Honma K, Armentrout PB (1993) J Am Chem Soc 115:12,125

    Article  CAS  Google Scholar 

  140. Anderson SG, Blades AT, Klassen J, Kebarle P (1995) Int J Mass Spectrom Ion Proc 141:217

    Article  CAS  Google Scholar 

  141. Hinderling C, Plattner DA (unpublished)

    Google Scholar 

  142. Holbrook KA, Pilling MJ, Robertson SH (1996) Unimolecular reactions. Wiley, Chichester

    Google Scholar 

  143. Schultz RH, Crellin KC, Armentrout PB (1991) J Am Chem Soc 113:8590

    Article  CAS  Google Scholar 

  144. Khan FA, Clemmer DE, Schultz RH, Armentrout PB (1993) J Phys Chem 97:7978

    Article  CAS  Google Scholar 

  145. Sunderlin LS, Wang D, Squires RR (1993) J Am Chem Soc 115:12,060

    Article  CAS  Google Scholar 

  146. Kim YM, Chen P (2000) Int J Mass Spectrom 202:1

    Article  CAS  Google Scholar 

  147. Klassen JS, Anderson SG, Blades AT, Kebarle P (1996) J Phys Chem 100:14,218

    Article  CAS  Google Scholar 

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  1. Laboratorium für Organische Chemiem, Eidgenössische Technische Hochschule Zürich, ETH-Hönggerberg, HCI G203, Wolfgang-Pauli-Strasse 10, 8093, Zürich, Switzerland

    Dietmar A. Plattner

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  1. Kekulé-Institut für Organische Chemie und Biochemie, Universität Bonn, Gerhard-Domagk-Straße 1, 53121, Bonn, Germany

    Christoph A. Schalley

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Plattner, D.A. (2003). Metalorganic Chemistry in the Gas Phase: Insight into Catalysis. In: Schalley, C.A. (eds) Modern Mass Spectrometry. Topics in Current Chemistry, vol 225. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-36113-8_5

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