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Coupled Plasmonic Plasmon/Photonic Resonance Effects in SERS

  • Chapter
Surface-Enhanced Raman Scattering

Part of the book series: Topics in Applied Physics ((TAP,volume 103))

5 Conclusion

The present studies show that array structures can be used to produce local field enhancements that are considerably larger than is found for isolated particles or dimers. These enhancements are large enough, in fact, that singlemolecule SERS measurements may be possible. The largest enhancements were obtained using a structure of two one-dimensional arrays, one parallel to the wavevector direction and one perpendicular to it. The particle at the crossing point of the two arrays is replaced by a dimer of particles, so that the local field between the particles is enhanced both by short-range near-field behavior of the dimer and also by long-range photonic interactions associated with resonances in the two arrays. This structure produced a field enhancement of 3.9 × 105 for a dimer of spheres, which is twice what we have been able to generate for a dimer in a single chain. Computational limitations make it impossible for us to study a dimer of nonspherical particles for this array structure, but similar studies for an isolated dimer of truncated tetrahedrons produced an extra factor of over 102 in the enhancement over the equivalent sphere result, suggesting that ∥E∥2 values of over 107 are possible for the “+” structure with a truncated tetrahedron dimer at the center. Furthermore, the resonance structures in this case are broad enough that significant enhancements at both the incoming and outgoing wavelengths is possible. Thus we conclude that this structure holds promise for single-molecule SERS measurements.

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References

  1. M. G. Albrecht, J. A. Greghton: J. Am. Chem. Soc. 99, 5215 (1977)

    Article  Google Scholar 

  2. D. L. Jeanmaire, R. P. Van Duyne: J. Electroanal. Chem. 84, 1 (1977)

    Article  Google Scholar 

  3. R. K. Chang, T. Furtak: in Surface-Enhanced Raman Scattering (Plenum, New York 1981)

    Google Scholar 

  4. S. G. Schultz, M. Janik-Czachor, R. P. Van Duyne: Surf. Sci. 104, 419 (1981)

    Article  ADS  Google Scholar 

  5. U. Laor, G. C. Schatz: J. Chem. Phys. 76, 2889 (1982)

    Article  ADS  Google Scholar 

  6. I. Pockrand: J. Electron. Spectrosc. Relat. Phenom. 29, 257 (1983)

    Google Scholar 

  7. G. W. Robinson: Chem. Phys. Lett. 80, 404 (1981)

    Article  ADS  Google Scholar 

  8. S. Nie, S. R. Emory: Science 275, 1102 (1997)

    Article  Google Scholar 

  9. J. Grand, M. L. de la Chapelle, J. L. Bijeon, P. M. Adam, A. Vial, P. Royer: Phys. Rev. B 72, 33407 (2005)

    Article  ADS  Google Scholar 

  10. D. A. Genov, A. K. Sarychev, V. M. Shalaev, A. Wei: Nano Lett. 4, 153 (2004)

    Article  ADS  Google Scholar 

  11. A. J. Haes, C. L. Haynes, A. D. McFarland, G. C. Schatz, R. P. Van Duyne, S. Zou: MRS Bull. 30, 368 (2005)

    Google Scholar 

  12. A. D. McFarland, M. A. Young, J. A. Dieringer, R. P. Van Duyne: J. Phys. Chem. B 109, 11279 (2005)

    Article  Google Scholar 

  13. L. A. Dick, A. D. McFarland, C. L. Haynes, R. P. Van Duyne: J. Phys. Chem. B 106, 853 (2002)

    Article  Google Scholar 

  14. E. M. Hicks, S. Zou, G. C. Schatz, K. G. Spears, R. P. Van Duyne, L. Gunnarsson, T. Rindzevicius, B. Kasemo, M. Kall: Nano Lett. 5, 1065 (2005)

    Article  ADS  Google Scholar 

  15. E. J. Zeman, G. C. Schatz: J. Phys. Chem. 91, 634 (1987)

    Article  Google Scholar 

  16. S. Zou, N. Janel, G. C. Schatz: J. Chem. Phys. 120, 10871 (2004)

    Article  ADS  Google Scholar 

  17. S. Zou, G. C. Schatz: Chem. Phys. Lett. 403, 62 (2004)

    Article  ADS  Google Scholar 

  18. S. Zou, G. C. Schatz: SPIE Proc. 5513, 22 (2004)

    Article  ADS  Google Scholar 

  19. S. Zou, G. C. Schatz: J. Chem. Phys. 121, 12606 (2004)

    Article  ADS  Google Scholar 

  20. S. Zou, L. Zhao, G. C. Schatz: Proc. SPIE 5221, 174 (2003)

    Article  ADS  Google Scholar 

  21. D. S. Citrin: Nano Lett. 5, 985 (2005)

    Article  ADS  Google Scholar 

  22. H. D. Ladouceur, D. E. Tevault, R. R. Smardzewski: J. Chem. Phys. 78, 980 (1983)

    Article  ADS  Google Scholar 

  23. G. Niaura, A. K. Gaigalas, V. L. Vilker: J. Phys. Chem. B 101, 9250 (1997)

    Article  Google Scholar 

  24. C. A. Jennings, G. J. Kovacs, R. Aroca: Langmuir 9, 2151 (1993)

    Article  Google Scholar 

  25. K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Etzkan, R. R. Dasari, M. S. Feld: Phys. Rev. Lett. 78, 1667 (1977)

    Article  ADS  Google Scholar 

  26. H. Xu, E. J. Bjerneld, M. Kall, L. Borjesson: Phys. Rev. Lett. 83, 4357 (1999)

    Article  ADS  Google Scholar 

  27. R. Dornhaus, M. B. Long, R. E. Benner, R. K. Chang: Surf. Sci. 93, 240 (1980)

    Article  ADS  Google Scholar 

  28. M. Kerker, D. S. Wang, H. Chew: Appl. Opt. 19, 3373 (1980)

    Article  ADS  Google Scholar 

  29. G. C. Schatz: Acc. Chem. Res. 17, 370 (1984)

    Article  Google Scholar 

  30. H. Metiu, P. Das: Annu. Rev. Phys. Chem. 35, 507 (1984)

    Article  ADS  Google Scholar 

  31. H. Xu, J. Aizpurua, M. Kall, P. Apell: Phys. Rev. E 62, 4318 (2000)

    Article  ADS  Google Scholar 

  32. G. C. Schatz, R. P. Van Duyne: Handbook of Vibrational Spectroscopy, vol. 1 (Wiley, New York 2002) p. 759

    Google Scholar 

  33. K. L. Kelly, E. Coronado, L. Zhao, G. C. Schatz: J. Phys. Chem. B 107, 668 (2003)

    Article  Google Scholar 

  34. F. J. Adrian: J. Chem. Phys. 77, 5302 (1982)

    Article  ADS  Google Scholar 

  35. H. Yamada, H. Nagata, K. Toba, Y. Nakao: Surf. Sci. 182, 269 (1987)

    Article  ADS  Google Scholar 

  36. K. K. Caswell, C. M. Bender, C. J. Murphy: Nano Lett. 3, 667 (2003)

    Article  ADS  Google Scholar 

  37. N. R. Jana, L. Gearheart, C. J. Murphy: Chem. Commun. 7, 617 (2001)

    Article  Google Scholar 

  38. R. C. Jin, Y. W. Cao, C. A. Mirkin, K. L. Kelly, G. C. Schatz, J. G. Zheng: Science 294, 1901 (2001)

    Article  ADS  Google Scholar 

  39. E. Hao, K. L. Kelly, J. T. Hupp, G. C. Schatz: J. Am. Chem. Soc. 124, 15182 (2002)

    Article  Google Scholar 

  40. E. Hao, R. C. Bailey, G. C. Schatz, J. T. Hupp, S. Li: Nano Lett. 4, 327 (2004)

    Article  ADS  Google Scholar 

  41. C. L. Haynes, R. P. Van Duyne: J. Phys. Chem. B 105, 5599 (2001)

    Article  Google Scholar 

  42. M. Kahl, E. Voges, S. Kostrewa, C. Viets, W. Hill: Sens. Actuators B 51, 285 (1998)

    Article  Google Scholar 

  43. R. P. Van Duyne, J. C. Hulteen, D. A. Treichel: J. Chem. Phys. 99, 2101 (1993)

    Article  ADS  Google Scholar 

  44. C. L. Haynes, A. D. McFarland, L. Zhao, R. P. Van Duyne, G. C. Schatz, L. Gunnarsson, J. Prikulis, B. Kasemo, M. Kall: J. Phys. Chem. B 107, 7337 (2003)

    Article  Google Scholar 

  45. A. Haes, E. Voges, R. P. Van Duyne: J. Am. Chem. Soc. 124, 10596 (2002)

    Article  Google Scholar 

  46. A. Haes, S. Zou, G. C. Schatz, R. P. Van Duyne: J. Phys. Chem. B 108, 109 (2004)

    Article  Google Scholar 

  47. A. Haes, S. Zou, G. C. Schatz, R. P. Van Duyne: J. Phys. Chem. B 108, 6961 (2004)

    Article  Google Scholar 

  48. L. Gunnarsson, T. Rindzevicius, J. Prikulis, B. Kasemo, M. Kall, S. Zou, G. C. Schatz: J. Phys. Chem. B 109, 1079 (2005)

    Article  Google Scholar 

  49. P. C. Waterman: Phys. Rev. D 3, 825 (1971)

    Article  ADS  Google Scholar 

  50. M. I. Mishchenko, D. W. Mackowski, L. D. Travis: Appl. Opt. 34, 4589 (1995)

    Article  ADS  Google Scholar 

  51. M. I. Mishchenko, L. D. Travis: Opt. Commun. 109, 16 (1994)

    Article  ADS  Google Scholar 

  52. M. I. Mishchenko, L. D. Travis, D.W. Mackowski: J. Quant. Spectrosc. Radiat. Transfer 55, 535 (1996)

    Article  ADS  Google Scholar 

  53. D. W. Mackowski, M. I. Mishchenko: J. Opt. Soc. Am. A 13, 2266 (1996)

    Article  ADS  Google Scholar 

  54. D. W. Mackowski: J. Quant. Spectrosc. Radiat. Transfer. 70, 441 (2001)

    Article  ADS  Google Scholar 

  55. D. W. Mackowski: J. Opt. Soc. Am. A 11, 2851 (1994)

    Article  ADS  Google Scholar 

  56. G. Mie: Ann. Phys. 25, 377 (1908)

    Article  MATH  Google Scholar 

  57. C. F. Bohren, D. R. Huffman: Absorption and Scattering of Light by Small Particles (Wiley, New York 1983)

    Google Scholar 

  58. B. T. Draine, P. J. Flatau: User Guide for the Discrete Dipole Approximation Code DDSCAT.6.0 (2003) URL http://arxiv.org/ags.astro-ph/0309069

    Google Scholar 

  59. B. T. Draine, P. J. Flatau: J. Opt. Soc. Am. A 11, 1491 (1994)

    Article  ADS  Google Scholar 

  60. A. Taflove: Advances in Computational Electrodynamics: The Finite-Difference Time-Domain Method (Artech House, Boston 1995) p. 599

    Google Scholar 

  61. R. X. Bian, R. C. Dunn, X. S. Xie, P. T. Leung: Phys. Rev. Lett. 75, 4772 (1995)

    Article  ADS  Google Scholar 

  62. L. Novotny, R. X. Bian, X. S. Xie: Phys. Rev. Lett. 79, 645 (1997)

    Article  ADS  Google Scholar 

  63. E. Moreno, D. Erni, C. Hafner, R. Vahldieck: J. Opt. Soc. Am. A 19, 101 (2002)

    Article  ADS  Google Scholar 

  64. L. Zhao, K. L. Kelly, G. C. Schatz: J. Phys. Chem. B 107, 7343 (2003)

    Article  Google Scholar 

  65. E. Hao, G. C. Schatz: J. Chem. Phys. 120, 357 (2004)

    Article  ADS  Google Scholar 

  66. S. Zou, G. C. Schatz: Nanotechnology (2006) in press

    Google Scholar 

  67. D. W. Lynch, W. R. Hunter: Optical constants of metals, in E. D. Palik (Ed.): Handbook of Optical Constants of Solids (Academic, New York 1985) pp. 350–356

    Google Scholar 

  68. H. Xu, M. Kall: Phys. Rev. Lett. 89, 246802 (2002)

    Article  ADS  Google Scholar 

  69. P. K. Aravind, H. Metiu: Surf. Sci. 124, 506 (1983)

    Article  ADS  Google Scholar 

  70. M. Micic, N. Klymyshyn, Y. D. Suh, H. P. Lu: J. Phys. Chem. 107, 1574 (2003)

    Google Scholar 

  71. P. T. Leung, W. S. Tse: Solid State Commun. 95, 39 (1995)

    Article  ADS  Google Scholar 

  72. J. C. Hulteen, R. P. Van Duyne: J. Vac. Sci. Technol. A 13, 1553 (1995)

    Article  ADS  Google Scholar 

  73. K. T. Carron, W. Fluhr, M. Meier, A. Wokaun, H. W. Lehmann: J. Opt. Soc. Am. B 3, 430 (1986)

    Article  ADS  Google Scholar 

  74. V. A. Markel: J. Mod. Opt. 40, 2281 (1993)

    Article  ADS  Google Scholar 

  75. S. Zou, G. C. Schatz: J. Chem. Phys. 12, 97102 (2005)

    Article  Google Scholar 

  76. W. D. Bragg, V. A. Markel, W. T. Kim, K. Banerjee, M. R. Young, J. G. Zhu, R. L. Armstrong, V. M. Shalaev, Z. C. Ying: J. Opt. Soc. Am. B 18, 698 (2001)

    Article  ADS  Google Scholar 

  77. K. Li, M. I. Stockman, D. J. Bergman: Phys. Rev. Lett. 91, 227402 (2003)

    Article  ADS  Google Scholar 

  78. W. L. Barnes, A. Dereux, T. W. Ebbesen: Nature 424, 824 (2003)

    Article  ADS  Google Scholar 

  79. J. A. Porto, F. J. Garca-Vidal, J. B. Pendry: Phys. Rev. Lett. 83, 2845 (1999)

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois, 60208-311

    Shengli Zou & George C. Schatz

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  1. Shengli Zou
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Editors and Affiliations

  1. Wellman Center for Photomedicine Harvard-M.I.T. Division of Health Sciences & Technology, Harvard University, Medical School, Boston, MA, 02114, USA

    Katrin Kneipp

  2. Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA, 93105, USA

    Martin Moskovits

  3. Wellman Center for Photomedicine, Harvard University, Medical School, Boston, MA, 02114, USA

    Harald Kneipp

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Zou, S., Schatz, G.C. (2006). Coupled Plasmonic Plasmon/Photonic Resonance Effects in SERS. In: Kneipp, K., Moskovits, M., Kneipp, H. (eds) Surface-Enhanced Raman Scattering. Topics in Applied Physics, vol 103. Springer, Berlin, Heidelberg . https://doi.org/10.1007/3-540-33567-6_4

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