Semiconductor-Based, Solar-Driven Photochemical Cells for Fuel Generation from Carbon Dioxide in Aqueous Solutions

Yehezkeli, Omer; Bedford, Nicholas M.; Park, Eunsol; Ma, Ke; Cha, Jennifer N.

doi:10.1002/cssc.201601105

Title: Semiconductor-Based, Solar-Driven Photochemical Cells for Fuel Generation from Carbon Dioxide in Aqueous Solutions

Journal Article · Mon Oct 24 00:00:00 EDT 2016 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201601105· OSTI ID:1533150

Yehezkeli, Omer ^[1]; Bedford, Nicholas M. ^[2]; Park, Eunsol ^[1]; Ma, Ke ^[1]; Cha, Jennifer N. ^[1]

Univ. of Colorado, Boulder, CO (United States)
National Inst. of Standards and Technology (NIST), Boulder, CO (United States)

There has been active interest to identify new methods to reduce CO₂ into usable fuel sources. In this work, we demonstrate two types of photo-electrochemical cells (PECs) that photoreduce CO₂ directly to formate in aqueous solutions both in the presence and absence of external bias or additional electron sources. The photocathodes were either a CuFeO₂/CuO electrode or a bilayer of CdTe on NiO, whereas the photoanode was a bilayer of NiO_x on CdS. The PECs were characterized by using both electrochemistry and spectroscopy, and the products formed from CO₂ reduction were characterized and quantified by using ¹H NMR spectroscopy and ESI-MS. In addition, an organohydride catalyst was tested in conjunction with the PECs, which not only showed a significant gain of 85 times in CO₂ reduction (27 μm formate without the catalyst, 2.3 mm formate with it) compared to the NiO/CdTe photocathode system but could also generate methanol under an external bias (10 μm).

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Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0006398

OSTI ID:: 1533150

Journal Information:: ChemSusChem, Vol. 9, Issue 22; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 16 works

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