skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Borylenes: An Emerging Class of Compounds

Abstract

Free borylenes (R–B:) have only been spectroscopically characterized in the gas phase or in matrices at very low temperatures. However, in recent years, a few mono- and bis(Lewis base)-stabilized borylenes have been isolated. In both of these compounds the boron atom is in the formal oxidation state +I which contrasts with classical organoboron derivatives wherein the element is in the +III oxidation state. Mono(Lewis base)-stabilized borylenes are isoelectronic with singlet carbenes, and their reactivity mimics to some extent that of transition metals. Further, they can activate small molecules, such as H2, and coordinate an additional ligand; in other words, they are boron metallomimics. Bis(Lewis base)borylene adducts are isoelectronic with amines and phosphines. In contrast to boranes, which act as electron acceptors and thus Lewis acids, they are electron-rich and act as ligands for transition metals.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Univ. of California, San Diego, La Jolla, CA (United States)
Publication Date:
Research Org.:
Univ. of California, San Diego, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC); National Science Foundation (NSF); SOLVAY Inc.
OSTI Identifier:
1533113
Alternate Identifier(s):
OSTI ID: 1375473
Grant/Contract Number:  
SC0009376
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Volume: 56; Journal Issue: 35; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; chemistry; boron; carbenoids

Citation Formats

Soleilhavoup, Michele, and Bertrand, Guy. Borylenes: An Emerging Class of Compounds. United States: N. p., 2017. Web. doi:10.1002/anie.201705153.
Soleilhavoup, Michele, & Bertrand, Guy. Borylenes: An Emerging Class of Compounds. United States. https://doi.org/10.1002/anie.201705153
Soleilhavoup, Michele, and Bertrand, Guy. 2017. "Borylenes: An Emerging Class of Compounds". United States. https://doi.org/10.1002/anie.201705153. https://www.osti.gov/servlets/purl/1533113.
@article{osti_1533113,
title = {Borylenes: An Emerging Class of Compounds},
author = {Soleilhavoup, Michele and Bertrand, Guy},
abstractNote = {Free borylenes (R–B:) have only been spectroscopically characterized in the gas phase or in matrices at very low temperatures. However, in recent years, a few mono- and bis(Lewis base)-stabilized borylenes have been isolated. In both of these compounds the boron atom is in the formal oxidation state +I which contrasts with classical organoboron derivatives wherein the element is in the +III oxidation state. Mono(Lewis base)-stabilized borylenes are isoelectronic with singlet carbenes, and their reactivity mimics to some extent that of transition metals. Further, they can activate small molecules, such as H2, and coordinate an additional ligand; in other words, they are boron metallomimics. Bis(Lewis base)borylene adducts are isoelectronic with amines and phosphines. In contrast to boranes, which act as electron acceptors and thus Lewis acids, they are electron-rich and act as ligands for transition metals.},
doi = {10.1002/anie.201705153},
url = {https://www.osti.gov/biblio/1533113}, journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 35,
volume = 56,
place = {United States},
year = {Sat Jun 03 00:00:00 EDT 2017},
month = {Sat Jun 03 00:00:00 EDT 2017}
}

Works referenced in this record:

Coordination of non-stabilized germylenes, stannylenes, and plumbylenes to transition metals
journal, January 2014


A Stable Neutral Diborene Containing a BB Double Bond
journal, October 2007


On the Existence of a Tungsten Carbonyl Carbene Complex
journal, August 1964


Peculiar boron startles again
journal, June 2015


Synthesis and structure of novel polycyclic species from toluene and m-xylene and the dehalogenation product of difluoro(diisopropylamino)borane
journal, October 1989


Dibora[2]ferrocenophane: A Carbene-Stabilized Diborene in a Strained cis -Configuration
journal, December 2016


31 P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes
journal, February 2013


Durch N-heterocyclische Carbene stabilisierte Borylradikale
journal, December 2016


The Parent Borylene: Betwixt and Between
journal, January 2012


Formation of a borylene by photolysis of an overcrowded bis(methylseleno)borane
journal, July 1999


The synthesis and structure of a carbene-stabilized iminocarboranyl-boron( i ) compound
journal, January 2015


Synthesis and Structure of the First Terminal Borylene Complexes
journal, December 1998


Electronically Excited States of Borylenes
journal, August 2016


“Umpolung” at Boron by Reduction of [B(CN)4]− and Formation of the Dianion [B(CN)3]2−
journal, October 2011


The Medicinal Applications of Imidazolium Carbene−Metal Complexes
journal, August 2009


Deprotonation of a Borohydride: Synthesis of a Carbene-Stabilized Boryl Anion
journal, June 2013


Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes
journal, September 2014


Die Synthese von B 2 (SIDip) 2 und seine Reaktivität zwischen denen von Diboracumulenen und Diborinen
journal, October 2015


N-heterocyclic carbene metal complexes: photoluminescence and applications
journal, January 2014


A Singlet Phosphinidene Stable at Room Temperature
journal, July 2016


Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles
journal, May 2016


9-Fluorenylidene-2,2,6,6-tetramethylpiperidinoborane: an Allene Isoester with Two-Coordinated Boron and BC Double Bond
journal, May 1985


Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square
journal, October 2016


Isolation and Reduction of Sterically Encumbered Arylboron Dihalides:  Novel Boranediyl Insertion into C−C σ-Bonds
journal, January 1996


First structural characterization of a boron-centered radical: x-ray crystal structure of [Li(12-crown-4)2]+ [BMes3]-.bul.
journal, July 1986


A 9-Borylated Acridinyl Radical
journal, February 2007


Einfach substituierte Boraethene
journal, December 1985


Carbenes Introduction
journal, August 2009


Stable singlet carbenes as mimics for transition metal centers
journal, January 2011


Synthese und Struktur eines Carben-stabilisierten π-Boryl-Anions
journal, February 2010


Simply Substituted Boraethenes
journal, December 1985


A facile and selective route to remarkably inert monocyclic NHC-stabilized boriranes
journal, January 2015


Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion
journal, February 2010


Deprotonierung eines Hydridoborat-Anions
journal, January 2017


Ring Enlargement of Three-Membered Boron Heterocycles upon Reaction with Organic π Systems: Implications for the Trapping of Borylenes
journal, June 2016


Synthesis and Structural Characterization of a Stable Dimeric Boron(II) Dication
journal, December 2007


The generation and some reactions of methylborylene
journal, December 1976


N , N ′-Diamidocarbenes: Isolable Divalent Carbons with Bona Fide Carbene Reactivity
journal, July 2016


Experimental Assessment of the Strengths of B–B Triple Bonds
journal, January 2015


Ligand versus Complex: C−F and C−H Bond Activation of Polyfluoroaromatics at a Cyclic (Alkyl)(Amino)Carbene
journal, March 2017


“Umpolung” von Bor im [B(CN)4]− Anion durch Reduktion zum Dianion [B(CN)3]2− 
journal, October 2011


A stable crystalline carbene
journal, January 1991


Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile
journal, June 2014


25 years of N-heterocyclic carbenes: activation of both main-group element–element bonds and NHCs themselves
journal, January 2016


CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap
journal, May 2006


Photochemical Generation of Triphenylsilylboranediyl (C6H5)3SiB: from Organosilylboranes
journal, June 1984


Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene
journal, September 1988


Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)
journal, April 2007


A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom-Transfer Agent
journal, September 2012


Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
journal, September 2005


The Parent Borylene: Betwixt and Between
journal, January 2012


The Lightest Element Phosphoranylidene: NHC-Supported Cyclic Borylidene-Phosphorane with Significant B=P Character
journal, March 2017


An N , N ′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry
journal, November 2009


Main-group elements as transition metals
journal, January 2010


[Bis(diisopropylamino)phosphino]trimethylsilyl-carben: Ein stabiles nucleophiles Carben
journal, May 1989


Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene
journal, January 2017


Intramolecular “Hydroiminiumation and -amidiniumation” of Alkenes:  A Convenient, Flexible, and Scalable Route to Cyclic Iminium and Imidazolinium Salts
journal, April 2007


Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes
journal, September 2014


Reactions of Persistent Carbenes with Hydrogen-Terminated Silicon Surfaces
journal, June 2016


Carbene Ligands in Surface Chemistry: From Stabilization of Discrete Elemental Allotropes to Modification of Nanoscale and Bulk Substrates
journal, September 2015


Planar, Twisted, and Trans-Bent:  Conformational Flexibility of Neutral Diborenes
journal, March 2008


Stable Carbenes: From ‘Laboratory Curiosities' to Catalysis Mainstays
journal, June 2013


The Lightest Element Phosphoranylidene: NHC-Supported Cyclic Borylidene-Phosphorane with Significant B=P Character
journal, March 2017


Comparative Reactivity of Different Types of Stable Cyclic and Acyclic Mono- and Diamino Carbenes with Simple Organic Substrates
journal, March 2014


Formation and Reactivity of Electron-Precise B−B Single and Multiple Bonds
journal, December 2016


Insertion of Cyclic Alkyl(amino) Carbene into the Si–H Bonds of Hydrochlorosilanes
journal, February 2016


Radical-Type Reactivity of the 1,3-Dibora-2,4-Diphosphoniocyclobutane-1,3-diyl
journal, February 2004


N-heterocyclic silylenes as powerful steering ligands in catalysis
journal, February 2017


Phenylborylene:  Direct Spectroscopic Characterization in Inert Gas Matrices
journal, March 2006


Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs)
journal, April 2007


Adduct Formation, B−H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs
journal, August 2016


Isolation of a Diborane(6) Dication: Formation and Cleavage of an Electron-Precise B(sp 3 )–B(sp 3 ) Bond
journal, June 2016


CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap
journal, May 2006


Carbene Stabilization of Highly Reactive Main-Group Molecules
journal, December 2011


Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile
journal, June 2014


Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene
journal, December 2016


Transition metal borylene complexes
journal, January 2013


Deprotonation of a Hydridoborate Anion
journal, January 2017


Selektive Generierung und Abfangreaktion eines NHC-stabilisierten B-H-Borylens
journal, April 2011


Synthese und strukturelle Charakterisierung eines stabilen dimeren Bor(II)-Dikations
journal, December 2007


Diborabutatrien: ein elektronenarmes Cumulen
journal, May 2014


Determining the Ligand Properties of N-Heterocyclic Carbenes from 77 Se NMR Parameters : Ligand Properties of N-Heterocyclic Carbenes
journal, April 2015


A 9-Borylated Acridinyl Radical
journal, February 2007


Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion
journal, October 2006


Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature
journal, February 2016


Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical
journal, December 2012


Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate ­Ligands: Intramolecularly Stabilized Tetrylenes
journal, October 2015


[Bis(trimethylsilyl)methylen](diisopropylamino)boran: ein Allen-homologes NBC-System
journal, June 1987


Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron
journal, July 2016


Isolierung eines neutralen, Bor‐haltigen Radikals, stabilisiert durch ein cyclisches (Alkyl)(amino)carben
journal, June 2014


Electron-Precise Coordination Modes of Boron-Centered Ligands
journal, July 2010


Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2
journal, March 2012


Synthese und Reaktivität von Verbindungen mit elektronenpräzisen B-B-Einfach- und B-B-Mehrfachbindungen
journal, December 2016


Infrared Spectra of Boron-Ammonia Reaction Products in Solid Argon
journal, September 1995


NHC-Stabilized 1-Hydro-1 H -borole and Its Nondegenerate Sigmatropic Isomers
journal, May 2011


Synthese und Struktur der ersten terminalen Borylenkomplexe
journal, November 1998


Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene
journal, January 2017


The Synthesis of B 2 (SIDip) 2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes
journal, October 2015


Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond
journal, June 2012


Chemistry of boron and silicon subhalides
journal, April 1973


Erzeugung zweifach koordinierter Bor(I)-Einheiten durch Fragmentierung eines molekularen Tetra-Bor(I)-Quadrats
journal, October 2016


Multiple complexation of CO and related ligands to a main-group element
journal, June 2015


Boron as an Electron-Pair Donor for B⋅⋅⋅Cl Halogen Bonds
journal, August 2016


Dibora[2]ferrocenophan: ein carbenstabilisiertes Diboren in einer gespannten cis -Konfiguration
journal, December 2016


Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C–H Bond
journal, November 2011


Klassische und nichtklassische Methylenborane
journal, July 1993


Boron-Fluorine Chemistry. I. Boron Monofluoride and Some Derivatives
journal, March 1967


Singlet Diradicals: from Transition States to Crystalline Compounds
journal, March 2002


Microwave spectroscopic study of the BBr molecule
journal, September 1997


Dative Wechselwirkungen einer Bor-zentrierten Lewis-Base mit Gruppe-13-Elementen
journal, November 2015


Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise
journal, December 2014


Alkene–Carbene Isomerization induced by Borane: Access to an Asymmetrical Diborene
journal, March 2017


Cyclische Alkylaminocarbene (CAACs): Neues von guten Bekannten
journal, June 2017


Group 1 and 2 cyclic (alkyl)(amino)carbene complexes
journal, January 2015


From an Electron-Rich Bis(boraketenimine) to an Electron-Poor Diborene
journal, February 2015


Trapping the Elusive Parent Borylene
journal, April 2011


Zur Borylierung von Benzol und Naphthalin durch Dehalogenierungsprodukte von Dichlor(diisopropylamino)boran
journal, June 1988


An overview of N-heterocyclic carbenes
journal, June 2014


Highly Energetic Tetraazidoborate Anion and Boron Triazide Adducts
journal, March 2001


31 P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes
journal, January 2013


Singlet (Phosphino)phosphinidenes are Electrophilic
journal, June 2016


N-Heterocyclic Carbene Stabilized Boryl Radicals
journal, December 2016


Classical and Nonclassical Methyleneboranes
journal, July 1993


An efficient synthetic route to stable bis(carbene)borylenes [(L 1 )(L 2 )BH]
journal, January 2014


Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene
journal, June 2014


σ-Bond Stretching: A Static Approach for a Dynamic Process
journal, January 2004


Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron
journal, January 2017


Deprotonierung eines Borhydrids und Synthese eines Carben- stabilisierten Borylanions
journal, June 2013


[Bis(diisopropylamino)phosphino]trimethylsilylcarbene: A Stable Nucleophilic Carbene
journal, May 1989


Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center
journal, October 2010


Convenient access to the tricyanoborate dianion B(CN) 3 2− and selected reactions as a boron-centred nucleophile
journal, January 2015


Reactivity of Borylenes toward Ethyne, Ethene, and Methane
journal, October 2012


Facile Splitting of Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center
journal, April 2007


Diborabutatriene: An Electron-Deficient Cumulene
journal, May 2014


Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base
journal, November 2015


Photochemische Erzeugung von Triphenylsilylborandiyl (C6H5)3SiB: aus Organosilylboranen
journal, June 1984


Von einem elektronenreichen Bis(boraketenimin) zu einem elektronenarmen Diboren
journal, February 2015


Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center
journal, October 2010


σ-Bond Stretching: A Static Approach for a Dynamic Process
journal, January 2004


Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines
journal, July 2011


Zur Frage eines Wolfram-Carbonyl-Carben-Komplexes
journal, July 1964


Works referencing / citing this record:

Metallfreie Stickstofffixierung an Bor
journal, May 2018


Einfacher Zugang zum ersten stabilen {BH 2 } Dihydroborylanion
journal, October 2018


Dreifach koordiniertes Bor als Superdonor und ‐akzeptor für quadrupolare Nahinfrarot‐Chromophore
journal, February 2019


Heterodiatomic Multiple Bonding in Group 13: A Complex with a Boron–Aluminum π Bond Reduces CO 2
journal, July 2019


Boranchemie aus einer neuen Perspektive: Nukleophilie der B-H-Bindungselektronen
journal, January 2019


The Thermal Rearrangement of an NHC‐Ligated 3‐Benzoborepin to an NHC‐Boranorcaradiene
journal, November 2019


Isolation of base stabilized fluoroborylene and its radical cation
journal, January 2019


CO 2 Binding and Splitting by Boron-Boron Multiple Bonds
journal, April 2018


Umpolung at Boron: Ancillary-Ligand-Induced Formation of Boron-Based Donor Ligands from Phosphine-Boranes
journal, March 2018


Push and pull: the potential role of boron in N 2 activation
journal, January 2018


Electronic structure of mono(Lewis base)-stabilized borylenes
journal, January 2019


Bindungsstärkende Rückbindung in Aminoborylen‐stabilisierten Aminoborylenen: an der Grenze zwischen Borylenen und Diborenen
journal, August 2019


Boron(II) Cations: Interplay between Lewis-Pair-Acceptor and Electron-Donor Properties
journal, July 2018


Heterodiatomare Mehrfachbindung zwischen Elementen der Gruppe 13: Ein Komplex mit B‐Al‐π‐Bindung reduziert CO 2
journal, June 2019


A New Perspective on Borane Chemistry: The Nucleophilicity of the B−H Bonding Pair Electrons
journal, January 2019


Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity
journal, January 2018


Crystalline Boragermenes
journal, January 2020


Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes
journal, September 2019


Bor(II)-Kationen: Ein Zusammenspiel zwischen Lewis-Paar-Akzeptor- und Elektronendonor-Eigenschaften
journal, July 2018


Bond‐Strengthening Backdonation in Aminoborylene‐Stabilized Aminoborylenes: At the Intersection of Borylenes and Diborenes
journal, August 2019


Boron carbonyl complexes analogous to hydrocarbons
journal, January 2018


Transition-metal-carbene-like intermolecular insertion of a borylene into C–H bonds
journal, January 2020


Triaminotriborane(3): A Homocatenated Boron Chain Connected by B−B Multiple Bonds
journal, November 2017


Facile Synthesis of a Stable Dihydroboryl {BH 2 } Anion
journal, November 2018


Metal-Free Nitrogen Fixation at Boron
journal, May 2018


A redox-active diborane platform performs C(sp 3 )–H activation and nucleophilic substitution reactions
journal, January 2018


Transition-Metal-Like Behavior of Monovalent Boron Compounds: Reduction, Migration, and Complete Cleavage of CO at a Boron Center
journal, April 2018


The Thermal Rearrangement of an NHC‐Ligated 3‐Benzoborepin to an NHC‐Boranorcaradiene
journal, November 2019


En Route to Bis-Carbene Analogues of the Heavier Group 13 Elements: Consideration of Bridging Group and Metal(I) Source
journal, June 2018


Near‐Infrared Quadrupolar Chromophores Combining Three‐Coordinate Boron‐Based Superdonor and Superacceptor Units
journal, May 2019


Nitrogen fixation and reduction at boron
journal, February 2018


Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
journal, January 2020


Release of Isonitrile- and NHC-Stabilized Borylenes from Group VI Terminal Borylene Complexes
journal, April 2018


CO 2 -Fixierung und Spaltung durch unpolare Mehrfachbindungen
journal, April 2018


Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes
journal, January 2019


Direct access to a cAAC-supported dihydrodiborene and its dianion
journal, January 2018


Unsymmetrical, Cyclic Diborenes and Thermal Rearrangement to a Borylborylene
journal, March 2018


Aluminum(I)/Boron(III) Redox Reactions
journal, February 2019


Redoxreaktionen zwischen Aluminium(I)- und Bor(III)-Verbindungen
journal, February 2019


Unsymmetrische, cyclische Diborene und thermische Umlagerung zu einem Borylborylen
journal, March 2018


Ring Expansion, Photoisomerization, and Retrocyclization of 1,4,2-Diazaboroles
journal, October 2017


Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone
journal, November 2017


Ring Expansion, Photoisomerization, and Retrocyclization of 1,4,2-Diazaboroles
journal, October 2017


Triaminotriborane(3): A Homocatenated Boron Chain Connected by B−B Multiple Bonds
journal, November 2017


Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone
journal, November 2017


Crystalline Boragermenes
journal, February 2020