Alkali-Metal-Intercalated Percolation Network Regulates Self-Assembled Electronic Aromatic Molecules
- Univ. at Buffalo, NY (United States). Dept. of Mechanical and Aerospace Engineering Research and Education in Energy Environment & Water (RENEW)
- Chinese Academy of Sciences (CAS), Shenzhen (China). Inst. of Advanced Technology
- Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
- Univ. at Buffalo, NY (United States). Dept. of Chemistry
Abstract In the continuously growing field of correlated electronic molecular crystals, there is significant interest in addressing alkali‐metal‐intercalated aromatic hydrocarbons, in which the possibility of high‐temperature superconductivity emerges. However, searching for superconducting aromatic molecular crystals remains elusive due to their small shielding fraction volume. To exploit this potential, a design principle for percolation networks of technologically important film geometry is indispensable. Here the effect of potassium‐intercalation is shown on the percolation network in self‐assembled aromatic molecular crystals. It is demonstrated that one‐dimensional (1D) dipole pairs, induced by dipole interaction, regulate the conductivity, as well as the electronic and optical transitions, in alkali‐metal‐intercalated molecular electronic crystals. A solid‐solution growth methodology of aromatic molecular films with a broad range of stability is developed to uncover electronic and optical transitions of technological importance. The light‐induced electron interactions enhance the charge‐carrier itinerancy, leading to a switchable metal‐to‐insulator transition. This discovery opens a route for the development of aromatic molecular electronic solids and long‐term modulation of electronic efficacy in nanotechnologically important thin films.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- US Army Research Office (ARO); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
- Grant/Contract Number:
- AC02-06CH11357; DE‐SC0018631; DE‐AC02‐06CH11357
- OSTI ID:
- 1558928
- Alternate ID(s):
- OSTI ID: 1492089
- Journal Information:
- Advanced Materials, Vol. 31, Issue 11; ISSN 0935-9648
- Publisher:
- WileyCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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